Citation: LI Yan-ge, LIU Yu-shun, SHEN Jian, SUN Yue. Alkylation of phenol with methanol over Mg-La-HY-SBA-15 zeolite[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(12): 1491-1497. shu

Alkylation of phenol with methanol over Mg-La-HY-SBA-15 zeolite

LI Yan-ge ¹ ,
LIU Yu-shun ² ,
SHEN Jian ¹ ,
SUN Yue ^1,,

1.
College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Sinopec Zhenhai Refining & Chemical Company, Ningbo 315200, China

Corresponding author: SUN Yue, sunyue19791980@126.com
Received Date: 20 June 2018
Revised Date: 10 September 2018

Figures(9)

Mg-La-HY-SBA-15 zeolite prepared by separate-step impregnation method was used to catalyze alkylation of phenol with methanol. The porous structure and acid property were characterized by SEM-EDS, Py-FTIR and others.The results found that Mg was successfully supported on La-HY-SBA-15 zeolite. Mg-La-HY-SBA-15 had micro-mesoporous structures. Compared with mono-mental modification, bimental modification reduced the amount of total acid and gained more total Lewis acid. At the same time, the selectivity and yield of o-cresol were increased.
- Mg-La-HY-SBA-15,
- micro-mesoporous,
- phenol,
- alkylation,
- o-cresol
1. [1]
  ZHAO Q, MAO Y, YAN L, LU L, JIANG T, YIN H. Stability of Y/MCM-48 composite molecular sieve with mesoporous and microporous structures[J]. J Asian Ceram Soc, 2014,2(4):347-356. doi: 10.1016/j.jascer.2014.07.003
2. [2]
  AUTTHANIT C, JONGSOMJIT B. Differences in characteristics of Zr/SBA-15 and bimetallic Zr-La/SBA-15 prepared by sol-gel and hydrothermal methods[J]. J Porous Mater, 2017,24(1):1-12. doi: 10.1007/s10934-016-0230-z
3. [3]
  LIU Peng, SHEN Jian. Preparation of ZSM-5-SBA-15 composite molecular sieves and its performance for toluene alkylation with methanol[J]. J Fuel Chem Technol, 2015,43(9):1147-1152. doi: 10.3969/j.issn.0253-2409.2015.09.019
4. [4]
  WU W, SHI C, BIAN X, BAI Y. Microwave radiation hydrothermal synthesis and characterization of micro-and mesoporous composite molecular sieve Y/SBA-15[J]. Arabian J Chem, 2013,13(2):123-126.
5. [5]
  DU J, SHI C, WU W, BIAN Y, CHEN P, CUI Q, CUI Z. Synthesis of core-shell structured FAU/SBA-15 composite molecular sieves and their performance in catalytic cracking of polystyrene[J]. Sci Technol Adv Mater, 2017,18(1)939. doi: 10.1080/14686996.2017.1396561
6. [6]
  LIU J, LIU Y, YANG W, GUO H, ZHANG H, TANG Z, FANG F. A novel and simple strategy for the direct synthesis bimetallic mesoporous materials Zr-La-SBA-15[J]. Mater Lett, 2014,128(10):15-18.
7. [7]
  SUBBARAMAIAH V, SRIVASTAVA V C, MALL I D. Optimization of reaction parameters and kinetic modeling of catalytic wet peroxidation of picoline by Cu/SBA-15[J]. Ind Eng Chem Res, 2013,52(26):9021-9029. doi: 10.1021/ie400124d
8. [8]
  ZHANG H, LI M, XIAO P, LIU D, ZOU C. Structure and catalytic performance of Mg-SBA-15-supported nickel catalysts for CO₂ reforming of methane to syngas[J]. Chem Eng Technol, 2013,36(10):1701-1707.
9. [9]
  WANG Jun-feng, SHEN Jian, LI Jian. Preparation of Mg/Ce-SBA-15 catalyst and its performance on phenol alkylation with methanol[J]. J Fuel Chem Technol, 2017,45(5):633-640. doi: 10.3969/j.issn.0253-2409.2017.05.015
10. [10]
  ZHAO D, FENG J, HUO Q, MELOSH N, FREDRICKSON G, CHMELKA B, STUCKY G. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. Science, 1998,279(5350):548-552. doi: 10.1126/science.279.5350.548
11. [11]
  ZHENG X D, DONG H J, WANG X, SHI L. Study on olefin alkylation of thiophenic sulfur in FCC gasoline using La₂O₃-modified HY zeolite[J]. Catal Lett, 2009,127(1/2):70-74.
12. [12]
  ZHANG Chuang, ZHANG Bo, YU Ming-quan. Adsorptive separation of 1, 1, 1, 2-tetrafluoroethane/1, 1-difluoro-2-chloroethylene over ion-exchanged Y zeolites[J]. J Chem Ind Eng, 2014,65(10):3946-3952. doi: 10.3969/j.issn.0438-1157.2014.10.027
13. [13]
  XU Xin-long, SHEN Jian. Preparation of β/SBA-15 composite molecular sieves and their catalytic performances of the synthesis of tert-Butyl phenol[J]. Petrochem Technol, 2014,43(7):767-773. doi: 10.3969/j.issn.1000-8144.2014.07.005
14. [14]
  LIU J, LIU Y, YANG W, GUO H, FANG F, TANG Z. Immobilization of phosphortungstic acid on amino-functionalized bimetallic Zr-La-SBA-15 and its highly catalytic performance for acetylation[J]. J Mol Catal A:Chem, 2014,393(18):1-7.
15. [15]
  KOSUGE K, SATO T, KIKUKAWA N, TAKEMORI M. Morphological control of rod-and fiberlike SBA-15 type mesoporous silica using water-soluble sodium silicate[J]. Chem Mater, 2004,16(5):899-905. doi: 10.1021/cm030622u
16. [16]
  CHEN L, DONG H, SHI L. Study on alkylation of toluene with tert-butanol over La₂O₃-modified HY zeolite[J]. Ind Eng Chem Res, 2010,49(16):7234-7238. doi: 10.1021/ie100695k
17. [17]
  GUI Jian-zhou, ZHANG Xiao-tong, HU Zhi-de, SUN Zhao-lin. A study of n-hexane aromatization on the ZnNi/HZSM-5 catalyst[J]. J Univ Lanzhou (Nat Sci), 2003,39(5):61-65.
18. [18]
  LI X, XIA Q, NGUYEN V C, PENG K, LIU X, ESSAYEM N, WANG Y. High yield production of HMF from carbohydrates over silica-alumina composite catalysts[J]. Catal Sci Technol, 2016,6(20):7586-7596. doi: 10.1039/C6CY01628F
19. [19]
  WANG Jun-feng, SHEN Jian, REN Tie-qiang. Preparation of Ce-SBA-15 catalyst and its performance on phenol alkylation with methanol[J]. J Mol Catal, 2016,30(6):523-531.
1. [1]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012
2. [2]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
5. [5]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
6. [6]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
7. [7]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
8. [8]
  Yufei Liu , Liang Xiong , Bingyang Gao , Qingyun Shi , Ying Wang , Zhiya Han , Zhenhua Zhang , Zhaowei Ma , Limin Wang , Yong Cheng . MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys. Chinese Chemical Letters, 2024, 35(12): 109932-. doi: 10.1016/j.cclet.2024.109932
9. [9]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
10. [10]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
11. [11]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
12. [12]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
13. [13]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
14. [14]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
15. [15]
  Hongsheng Tang , Yonghe Zhang , Dexiang Wang , Xiaohui Ning , Tianlong Zhang , Yan Li , Hua Li . A Wonderful Journey through the Kingdom of Hazardous Chemicals. University Chemistry, 2024, 39(9): 196-202. doi: 10.12461/PKU.DXHX202403098
16. [16]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
17. [17]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
18. [18]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
19. [19]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
20. [20]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(801)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142