Citation: Zi Qiang LEI, Yun Pu WANG. OXIDATION OF ALKYLBENZENES CATALYZED BY IRON( Ⅱ,Ⅲ)-1,10-PHENANTHROLINE AND 2, 2'-BIPYRIDINE COMPLEXES[J]. Chinese Chemical Letters, ;1993, 4(1): 21-22. shu

OXIDATION OF ALKYLBENZENES CATALYZED BY IRON( Ⅱ,Ⅲ)-1,10-PHENANTHROLINE AND 2, 2'-BIPYRIDINE COMPLEXES

Department of Chemistry, Northwest Normal University, Lanzhou 730070

Received Date: 8 July 1992

Oxidation of alkybenzenes PhCH₂R(R=H, CH₃, C₂H₅ and n-C₃H₇ under 1 atm. of O₂ or air catalyzed by iron(Ⅱ, Ⅲ)-2,2'-bipyridine and 1,10-phenanthroline complexes, affords the aryl-substituted ketones and alcohols with the conversion of 15.00%~34.58% containing of 97.60%~99.80% ketones and alcohols. The turnover numbers of these catalysts are over 3500 mol-cat. -¹for 3.5 h.
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