Citation: Bai Qingqing, Wu Xiaoning, Wang Qian, Li Rong, Wang Xiaofei. Research Progress in Enlargement of pH in Fenton Reaction[J]. Chemistry, ;2018, 81(3): 217-222. shu

Research Progress in Enlargement of pH in Fenton Reaction

1.
School of Civil Engineering and Architecture, Xi'an University of Technology, Xi'an 710021
2.
School of Materials and Chemical Engineering, Xi'an University of Technology, Xi'an 710021
3.
School of Materials Science and Engineering, Shannxi University of Science and Technology, Xi'an 710021

Corresponding author: Wang Qian, xatutougao@163.com
Received Date: 26 October 2017
Accepted Date: 18 December 2017

Fenton technology is an effective method for the treatment of non-biodegradable organic pollutants. It can be carried out under mild conditions, but with the disadvantage of narrow pH range. In this paper, different methods of improving the catalyst and oxidant to expand the pH range were discussed, and the reaction mechanism of broadening the pH range was summarized. The catalyst modification includes the use of supported catalysts, iron and iron mineral catalysts, modified catalysts, non-ferrous metal active sites, etc. These catalysts can broaden the Fenton reaction pH range for their high catalytic activity over the wide pH range. Improvements to oxidants include the use of H₂O₂-containing solid oxidants such as percarbonates and persulfates, etc., using their own properties to achieve the purpose of broadening the pH range. Through the simultaneous improvement of the catalyst and the oxidant, the pH range of the Fenton reaction can be effectively broadened, and the formation of iron sludge can be avoided at the same time.
- Fenton oxidation technology,
- Catalyst,
- Oxidant,
- Broadening pH
1. [1]
  P K Malik, S K Saha. Sep. Purif. Technol., 2003, 31(3):241~250.
2. [2]
  J H Sun, S P Sun, G L Wang et al. Dyes Pigments, 2007, 74(3):647~652.
3. [3]
  L Zhou, Y Shao, J Liu et al. ACS. Appl. Mater. Interf., 2014, 6(10):7275~7285.
4. [4]
5. [5]
  D Nguyen, Z Zhang, W O S Doherty. J. Agr. Food Chem., 2015, 63(5):1582~1592.
6. [6]
  H J H Fenton. J. Chem. Soc., Transac., 1984, 65:899~910.
7. [7]
  N Masomboon, C Ratanatamskul, M C Lu. Environ. Sci. Technol., 2009, 43(22):8629~8634.
8. [8]
  G Zhang, Y Gao, Y Zhang et al. Environ. Sci. Technol., 2010, 44(16):6384~6389.
9. [9]
  S W Yin, M Rafatullah, A F M Alkarkhi et al. Desali. Water Treat., 2014, 52(22-24):4583~4591.
10. [10]
11. [11]
  F L Y Lam, X Hu. Ind. Eng. Chem. Res., 2013, 52(20):6639~6646.
12. [12]
  Y Yao, Y Mao, B Zheng et al. Ind. Eng. Chem. Res., 2014, 53(20):8376~8384.
13. [13]
  Z Xu, C Huang, L Wang et al. Ind. Eng. Chem. Res., 2015, 54(16):4593~4602.
14. [14]
  J Ma, Q Yang, Y Wen et al. Appl. Catal. B, 2017, 201:232~240.
15. [15]
16. [16]
  L Xu, J Wang. J. Hazard. Mater., 2011, 186(1):256~264.
17. [17]
  W Li, Y Wang, A Irini. Chem. Eng. J., 2014, 244(2):1~8.
18. [18]
19. [19]
  L Wei, Y Wang, Z Ai et al. ACS. Appl. Mater. Interf., 2015, 7(51):28534~28544.
20. [20]
  W Huang, M Brigante, F Wu et al. Environ. Sci. Technol., 2013, 47(4):1952~1959.
21. [21]
  Z H Diao, X R Xu, D Jiang et al. J. Hazard. Mater., 2017, 327:108~115.
22. [22]
  X Hou, X Huang F Jia et al. Environ. Sci. Technol., 2017, 51(9):5118~5126.
23. [23]
  Z Ma, L Ren, SXing et al. J. Phys. Chem. C, 2015, 119(40):23068~23074.
24. [24]
  T Xu, R Zhu, G Zhu et al. Appl. Catal. B, 2017, 212(5):50~58.
25. [25]
26. [26]
  S H Tian, Y T Tu, D S Chen et al. Chem. Eng. J., 2011, 169(1):31~37.
27. [27]
  L Lyu, L Zhang, Q Wang et al. Environ. Sci. Technol., 2015, 49(14):8639~8647.
28. [28]
  E J Kim, D Oh, C S Lee et al. Catal. Today, 2017, 282(1):71~76.
29. [29]
30. [30]
31. [31]
  H Gao, J Chen, Y Zhang et al. Chem. Eng. J., 2016, 306:522~530.
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
  K Nakashima, Y Ebi, M Kubo et al. Ultrason. Sono. Chem., 2016, 29:455~460.
37. [37]
  L Qi, G Zuo, Z Cheng et al. Chem. Eng. J., 2013, 229(4):197~205.
38. [38]
  A Long, L Yang, H Zhang. Ind. Eng. Chem. Res., 2014, 53(3):1033~1039.
39. [39]
  G Liu, X Li, B Han et al. J. Hazard. Mater., 2017, 322:461~468.
40. [40]
  J Zou, J Ma, L Chen et al. Environ. Sci. Technol., 2013, 47(20):11685~11691.
41. [41]
  X Zang, X Gu, S Lu et al. Environ. Sci. Technol., 2014, 35(7):791~798.
42. [42]
  Z Miao, X Gu, S Lu et al. Chemosphere, 2015, 119:1120~1125.
43. [43]
  Y Lei, C S Chen, Y J Tu et al. Environ. Sci. Technol., 2015, 49(11):6838~6845.
44. [44]
  X Li, Z Wang, B Zhang et al. Appl. Catal. B, 2016, 181:788~799.
45. [45]
  H Cui, X Gu, S Lu et al. Chem. Eng. J., 2017, 309(1):80~88.
46. [46]
  K Y A Lin, J T Lin, Y F Lin. J. Taiwan Inst. Chem. Eng., 2017, 19(36):1~6.
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
5. [5]
  Chenyang WANG , Yiyan BAI , Wei ZHANG , Zhaorong LIU , Yuchun WANG . Performance of photo-assisted copper oxide catalyzed hydrolysis of ammonia borane to produce hydrogen. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 97-110. doi: 10.11862/CJIC.20250116
6. [6]
  Wenruo NI , Hongpeng LI , Yun ZHANG , Yiran TIAN , Jiehui RUI , Yingcheng TONG , Xiaolin PI , Zhenyan TANG . Research progress of ruthenium alloy catalysts in hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 23-44. doi: 10.11862/CJIC.20250188
7. [7]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
8. [8]
  Shuting KONG , Fengshi ZHANG , Zhiyi LU , Yanling LIU , Minglang YE , Zhengfang HU , Longsheng WANG , Bing HU , Haiying WANG . Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303
9. [9]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
10. [10]
  Mei-Xia Yang , Zhen-Hong He , Long-Rui Wang , You-Xing Yang . Route for Turning Waste CH₄ and CO₂ into Valuable Products: Reforming for Syngas. University Chemistry, 2026, 41(2): 197-207. doi: 10.12461/PKU.DXHX202503012
11. [11]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
12. [12]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
13. [13]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
14. [14]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
15. [15]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
16. [16]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
17. [17]
  Yuying JIANG , Jia LUO , Zhan GAO . Development status and prospects of solid oxide cell high entropy electrode catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1719-1730. doi: 10.11862/CJIC.20250124
18. [18]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
19. [19]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
20. [20]
  Haiqiang Lin , Weizheng Weng , Jingdong Lin , Mingshu Chen , Xueming Fang , Lefu Yang . Diverse Variables-Driven Catalytic Optimization: Experimental Enhancement and Instructional Design for Selective Methane Oxidation on Supported Nickel-based Catalysts. University Chemistry, 2025, 40(11): 327-336. doi: 10.12461/PKU.DXHX202505106

Get Citation

PDF

XML

Metrics

PDF Downloads(31)
Abstract views(3000)
HTML views(1127)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142