Citation: Bai Qingqing, Wu Xiaoning, Wang Qian, Li Rong, Wang Xiaofei. Research Progress in Enlargement of pH in Fenton Reaction[J]. Chemistry, ;2018, 81(3): 217-222. shu

Research Progress in Enlargement of pH in Fenton Reaction

1.
School of Civil Engineering and Architecture, Xi'an University of Technology, Xi'an 710021
2.
School of Materials and Chemical Engineering, Xi'an University of Technology, Xi'an 710021
3.
School of Materials Science and Engineering, Shannxi University of Science and Technology, Xi'an 710021

Corresponding author: Wang Qian, xatutougao@163.com
Received Date: 26 October 2017
Accepted Date: 18 December 2017

Fenton technology is an effective method for the treatment of non-biodegradable organic pollutants. It can be carried out under mild conditions, but with the disadvantage of narrow pH range. In this paper, different methods of improving the catalyst and oxidant to expand the pH range were discussed, and the reaction mechanism of broadening the pH range was summarized. The catalyst modification includes the use of supported catalysts, iron and iron mineral catalysts, modified catalysts, non-ferrous metal active sites, etc. These catalysts can broaden the Fenton reaction pH range for their high catalytic activity over the wide pH range. Improvements to oxidants include the use of H₂O₂-containing solid oxidants such as percarbonates and persulfates, etc., using their own properties to achieve the purpose of broadening the pH range. Through the simultaneous improvement of the catalyst and the oxidant, the pH range of the Fenton reaction can be effectively broadened, and the formation of iron sludge can be avoided at the same time.
- Fenton oxidation technology,
- Catalyst,
- Oxidant,
- Broadening pH
1. [1]
  P K Malik, S K Saha. Sep. Purif. Technol., 2003, 31(3):241~250.
2. [2]
  J H Sun, S P Sun, G L Wang et al. Dyes Pigments, 2007, 74(3):647~652.
3. [3]
  L Zhou, Y Shao, J Liu et al. ACS. Appl. Mater. Interf., 2014, 6(10):7275~7285.
4. [4]
5. [5]
  D Nguyen, Z Zhang, W O S Doherty. J. Agr. Food Chem., 2015, 63(5):1582~1592.
6. [6]
  H J H Fenton. J. Chem. Soc., Transac., 1984, 65:899~910.
7. [7]
  N Masomboon, C Ratanatamskul, M C Lu. Environ. Sci. Technol., 2009, 43(22):8629~8634.
8. [8]
  G Zhang, Y Gao, Y Zhang et al. Environ. Sci. Technol., 2010, 44(16):6384~6389.
9. [9]
  S W Yin, M Rafatullah, A F M Alkarkhi et al. Desali. Water Treat., 2014, 52(22-24):4583~4591.
10. [10]
11. [11]
  F L Y Lam, X Hu. Ind. Eng. Chem. Res., 2013, 52(20):6639~6646.
12. [12]
  Y Yao, Y Mao, B Zheng et al. Ind. Eng. Chem. Res., 2014, 53(20):8376~8384.
13. [13]
  Z Xu, C Huang, L Wang et al. Ind. Eng. Chem. Res., 2015, 54(16):4593~4602.
14. [14]
  J Ma, Q Yang, Y Wen et al. Appl. Catal. B, 2017, 201:232~240.
15. [15]
16. [16]
  L Xu, J Wang. J. Hazard. Mater., 2011, 186(1):256~264.
17. [17]
  W Li, Y Wang, A Irini. Chem. Eng. J., 2014, 244(2):1~8.
18. [18]
19. [19]
  L Wei, Y Wang, Z Ai et al. ACS. Appl. Mater. Interf., 2015, 7(51):28534~28544.
20. [20]
  W Huang, M Brigante, F Wu et al. Environ. Sci. Technol., 2013, 47(4):1952~1959.
21. [21]
  Z H Diao, X R Xu, D Jiang et al. J. Hazard. Mater., 2017, 327:108~115.
22. [22]
  X Hou, X Huang F Jia et al. Environ. Sci. Technol., 2017, 51(9):5118~5126.
23. [23]
  Z Ma, L Ren, SXing et al. J. Phys. Chem. C, 2015, 119(40):23068~23074.
24. [24]
  T Xu, R Zhu, G Zhu et al. Appl. Catal. B, 2017, 212(5):50~58.
25. [25]
26. [26]
  S H Tian, Y T Tu, D S Chen et al. Chem. Eng. J., 2011, 169(1):31~37.
27. [27]
  L Lyu, L Zhang, Q Wang et al. Environ. Sci. Technol., 2015, 49(14):8639~8647.
28. [28]
  E J Kim, D Oh, C S Lee et al. Catal. Today, 2017, 282(1):71~76.
29. [29]
30. [30]
31. [31]
  H Gao, J Chen, Y Zhang et al. Chem. Eng. J., 2016, 306:522~530.
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
  K Nakashima, Y Ebi, M Kubo et al. Ultrason. Sono. Chem., 2016, 29:455~460.
37. [37]
  L Qi, G Zuo, Z Cheng et al. Chem. Eng. J., 2013, 229(4):197~205.
38. [38]
  A Long, L Yang, H Zhang. Ind. Eng. Chem. Res., 2014, 53(3):1033~1039.
39. [39]
  G Liu, X Li, B Han et al. J. Hazard. Mater., 2017, 322:461~468.
40. [40]
  J Zou, J Ma, L Chen et al. Environ. Sci. Technol., 2013, 47(20):11685~11691.
41. [41]
  X Zang, X Gu, S Lu et al. Environ. Sci. Technol., 2014, 35(7):791~798.
42. [42]
  Z Miao, X Gu, S Lu et al. Chemosphere, 2015, 119:1120~1125.
43. [43]
  Y Lei, C S Chen, Y J Tu et al. Environ. Sci. Technol., 2015, 49(11):6838~6845.
44. [44]
  X Li, Z Wang, B Zhang et al. Appl. Catal. B, 2016, 181:788~799.
45. [45]
  H Cui, X Gu, S Lu et al. Chem. Eng. J., 2017, 309(1):80~88.
46. [46]
  K Y A Lin, J T Lin, Y F Lin. J. Taiwan Inst. Chem. Eng., 2017, 19(36):1~6.
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
3. [3]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
4. [4]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
5. [5]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
6. [6]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
10. [10]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
11. [11]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
12. [12]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
13. [13]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
14. [14]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
17. [17]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(30)
Abstract views(2404)
HTML views(1026)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142