Citation: Pan Yingying, Hu Xi, Lin Xiaoming, Xu Xuan, Luo Yifan. The Application of Core-Shell MOFs and Their Derivatives as Anode Materials in Lithium-Ion Batteries[J]. Chemistry, ;2020, 83(10): 883-890. shu

The Application of Core-Shell MOFs and Their Derivatives as Anode Materials in Lithium-Ion Batteries

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  • Metal-organic frameworks (MOFs) materials are widely used in the field of electrochemical energy conversion and storage, with the advantages of large specific surface area, adjustable pore size, easy preparation, structural and functional diversity. Among them, the unique core-shell materials often show more synergy between the core and shell due to the surface modification. This article introduces the development status of core-shell MOFs as anode materials for lithium-ion batteries, and focuses on the preparation methods of their derivatives (porous carbon, metal oxides, metal sulfur/selenide, metal/metal oxides) and their applications. MOFs can produce traditional inorganic electrode materials with adjustable structure and exhibit more excellent electrochemical performance by calcining at high temperature or changing the chemical reaction conditions. Finally, the problems and challenges of core-shell MOFs as anode materials for lithium-ion battery are summarized, and possible solutions and future application prospects are proposed.
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