Citation: JI Xue-wei, GE Qing-jie, SUN Jian. Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(4): 438-445. shu

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons

JI Xue-wei ^1,2 ,
GE Qing-jie ¹ ,
SUN Jian ^1,,

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: SUN Jian, sunj@dicp.ac.cn
Received Date: 13 November 2018
Revised Date: 16 February 2019

Fund Project: The project was supported by the National Natural Science Foundation of China (91745107)National Natural Science Foundation of China 91745107

Figures(6)

A series of fused iron (FI) catalysts promoted with biomass ash were prepared by physical mixing method and characterized by X-ray diffraction, transmission electron microscopy and Mossbauer spectroscopy. The catalytic performance of CO₂ hydrogenation to higher hydrocarbons was evaluated in a fixed bed reactor. The results show that compared with the catalyst without biomass ash (B-ash), the fused iron catalysts promoted with biomass ash have smaller particle size and narrower size distribution, and the four phases of Fe₃O₄, Fe₅C₂, Fe₃C as well as α-Fe coexist in synergy. Thus, the tandem reaction of reverse water gas shift (RWGS) and C-C coupling proceed efficiently, and the selectivity of higher hydrocarbons is significantly improved while methane formation is effectively suppressed. Among the products, C_4-18 hydrocarbons are dominant. The C_4-18 hydrocarbons' selectivity in all hydrocarbons reaches 73.9% at the conditions of 300℃, 1.0 MPa, 4800 h^-1, H₂/CO₂=3.0 as well as the additive amount of the promoter is 5% (mass ratio).
- CO₂ hydrogenation,
- high hydrocarbons,
- Fe-based catalyst,
- biomass,
- synergism
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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO2 to higher hydrocarbons

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通讯作者: 陈斌, bchen63@163.com

Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons