Citation:
Xiu Yang LU, Qi JING, Zhun LI, Lei YUAN, Fei GAO, Xin LIU. Enhanced Acid/Base Catalysis in High Temperature Liquid Water[J]. Chinese Chemical Letters,
;2006, 17(6): 841-844.
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Two novel and environmentally benign solvent systems, organic acids-enriched high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
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