Citation:
CHEN KAN-TANG. ON THE PROGRAMMING OF THE ENGINEERING PROCESS OF IONIC SOLUTION POLYMERIZATION[J]. Acta Polymerica Sinica,
;1964, 6(3): 193-205.
-
The rate equation of the ionic solution polymerization may be expressed in.general by r=—dM—dθ=kMmCn where M and C denote the concentrations of the monomer and the catalyst in the solu-tion respectively.m and n are kinetic parameters characterizing the polymerization sys-tem.In order to control the polymerization process or to design an adequate reactor system,it is required to regulate the reaction rate to conform with the heat transfer capacity of the system.Various operating schemes were postulated and their rate behavior during the reaction obtained by integrating the fundamental rate equation for these schemes.The results obtained for batch polymerization under control at isothermal conditions are as follows.
-
-
-
-
[1]
Xie Yao , Li Shuangjun , Chen Chao , Fan Siyu , Tao Ying , Zhang Qitao . Ionic polarization engineering of polymeric carbon nitride toward efficient H2O2 photosynthesis. Acta Physico-Chimica Sinica, 2026, 42(5): 100183-. doi: 10.1016/j.actphy.2025.100183
-
[2]
Tiantian Dai , Xi Yang . Teaching Design and Reflection on the “Osmotic Pressure of Solutions” in Medical Chemistry. University Chemistry, 2025, 40(5): 268-275. doi: 10.12461/PKU.DXHX202411032
-
[3]
Cong Liu , Yuling Huang , Peng Zhen , Hualiu Li , Bingjia Xu , Suilian Luo , Guang Shi . A Comprehensive Design Experiment: Preparation and Property Characterization of Polymer Room-Temperature Phosphorescence Materials. University Chemistry, 2026, 41(4): 409-416. doi: 10.12461/PKU.DXHX202503092
-
[4]
Chunyuan Kang , Xiaoyu Li , Fan Yang , Bai Yang . Ionic-bond crosslinked carbonized polymer dots for tunable and enhanced room temperature phosphorescence. Acta Physico-Chimica Sinica, 2026, 42(1): 100156-0. doi: 10.1016/j.actphy.2025.100156
-
[5]
Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO2 conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
-
[6]
Yinuo Wu , Jiantao Ye , Xie Zhou , Yu Qian , Lei Guo . Teaching Design of Basic Chemistry Based on PBL Methodology for Medical Undergraduates: A Case Study on “Osmotic Pressure of Solution”. University Chemistry, 2024, 39(3): 149-157. doi: 10.3866/PKU.DXHX202309077
-
[7]
Manman Jin , Zhiguo Lv , Qingtao Niu . Teaching Reformation and Case Study for “Chemical Process Development and Design” Based on “Just-in-Time” Dynamic and Accurate Matching Industrial Needs. University Chemistry, 2024, 39(11): 108-116. doi: 10.12461/PKU.DXHX202403030
-
[8]
Jiahao Zeng , Hui Chao . 诱导程序性细胞死亡的金属抗肿瘤药物研究. University Chemistry, 2025, 40(6): 145-159. doi: 10.12461/PKU.DXHX202406019
-
[9]
Hui Xiong , Yan Wang , Rongxian Bai , Yongqi Wu , Chengmei Liu , Yuefa Gong , Jian Zhang . Development of a Compound Talent Training System Based on Virtual Technology: a Case Study of Chemical Unit and Process Simulation Practices. University Chemistry, 2024, 39(10): 314-317. doi: 10.12461/PKU.DXHX202405071
-
[10]
Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . Photomultiplication-Type All-Polymer Photodetectors and Their Applications in Photoplethysmography Sensor. Acta Physico-Chimica Sinica, 2025, 41(1): 100007-0. doi: 10.3866/PKU.WHXB202311021
-
[11]
Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
-
[12]
Jia Huo , Jia Li , Yongjun Li , Yuzhi Wang . Ideological and Political Design of Physical Chemistry Teaching: Chemical Potential of Any Component in an Ideal-Dilute Solution. University Chemistry, 2024, 39(2): 14-20. doi: 10.3866/PKU.DXHX202307075
-
[13]
Pingping Zhu , Qiang Zhou , Yu Huang , Haiyang Yang , Pingsheng He , Shiyan Xiao . Design and Practice of Ideological and Political Cases in the Course of Polymer Physics Experiments: Molecular Weight Determination of Polymers by Dilute Solution Viscosity Method as an Example. University Chemistry, 2025, 40(4): 94-99. doi: 10.12461/PKU.DXHX202405170
-
[14]
Shitong Wang , Yangyang He , Xihong Xiong , Wei Zhang , Meilin Xia , Fenglin Tang . 基于手机RGB图像-微信小程序的化学需氧量(COD)实时可视化快速分析. University Chemistry, 2026, 41(1): 394-405. doi: 10.12461/PKU.DXHX202506011
-
[15]
Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
-
[16]
Chunfang Zhang , Cuimiao Zhang , Shuai Liu , Yaduo Zheng , Lin Yang , Kehan Jiang , Mingtao Run . Refined Experiment for Magnetic Susceptibility Determination: A Digital Empowered Experiment Based on WeChat Mini Program and Animated Video. University Chemistry, 2026, 41(1): 244-252. doi: 10.12461/PKU.DXHX202505056
-
[17]
Rongrong Wang , Chen Li , Xiang Ren , Keliang Zhang , Yu Sun , Xianzhong Sun , Kai Wang , Xiong Zhang , Yanwei Ma . Recent advances and challenges of eco-friendly Ni-rich cathode slurry systems in lithium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(4): 100222-0. doi: 10.1016/j.actphy.2025.100222
-
[18]
Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
-
[19]
Haiqiang Lin , Weizheng Weng , Jingdong Lin , Mingshu Chen , Xueming Fang , Lefu Yang . Diverse Variables-Driven Catalytic Optimization: Experimental Enhancement and Instructional Design for Selective Methane Oxidation on Supported Nickel-based Catalysts. University Chemistry, 2025, 40(11): 327-336. doi: 10.12461/PKU.DXHX202505106
-
[20]
Yu Li , Lanlan Song , Hongxiu Zhang . Exploring the Innovation in Teaching Principles of Chemical Engineering: Emphasizing Foundational Knowledge and Practical Skills. University Chemistry, 2024, 39(8): 91-98. doi: 10.3866/PKU.DXHX202312087
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(356)
- HTML views(0)
Login In
DownLoad: