Citation: Sheng Lou DENG, Dong Zhi LIU, Ru Yu CHEN. Facile Synthesis of Five-membered Phosphoroheterocycles Bearing N-P-N and S-P-N Moieties[J]. Chinese Chemical Letters, ;2001, 12(12): 1065-1068. shu

Facile Synthesis of Five-membered Phosphoroheterocycles Bearing N-P-N and S-P-N Moieties

1.
School of Chemical Engineering, Tianjin University, Tianjin 300072;
2.
Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 20 April 2001

New reactions of Lawesson reagent (LR) with a-hydroxy (amino)nitriles have been studied. The experimental results showed that the five-membered phosphoroheterocycles 2 and 4 bearing N-P-N or S-P-N moiety could be readily prepared in high yields. Meanwhile, the possible mechanism of the reactions was also discussed.
- New reactions,
- Lawesson reagent,
- nitriles,
- phosphoroheterocycle,
- mechanism
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