Citation: Tian Qingqiang, Wang Huajun, Yuan Jianyong. Oxidation of Aromatic Aldehydes by Sodium Chlorite and Hydrogen Peroxide under Neutral Conditions[J]. Chemistry, ;2017, 80(12): 1143-1147. shu

Oxidation of Aromatic Aldehydes by Sodium Chlorite and Hydrogen Peroxide under Neutral Conditions

Pharmacy college, Chongqing medical university, Chongqing 400016

Corresponding author: Yuan Jianyong, enediyne90@163.com
Received Date: 11 May 2017
Accepted Date: 30 August 2017

Figures(3)

In this paper, the reaction conditions for the oxidation of aldehydes with sodium chlorite and hydrogen peroxide in neutral environment were optimized. The effects of solvent, amounts of sodium chlorite and hydrogen peroxide and reaction temperature on the yield of acids were investigated by orthogonal experimental design. The optimum conditions were as follows:ethanol as solvent, the molar ratio of sodium chlorite, hydrogen peroxide and aldehyde was 1.1:2:1. The adaptability of aldehydes was verified, and the industrial applicability was demonstrated by amplification experiments. It was proved that the method has the characteristics of high yield, simple post-processing, green by-products without pollution, etc.
- Sodium chlorite,
- Hydrogen peroxide,
- Neutral condition,
- Oxidation,
- Aldehyde
1. [1]
  E Dalcanale, F Montanari. J. Org. Chem., 1986, 51:567~569.
2. [2]
  B S Bal. W E Childers, H WPinnick. Tetrahedron, 1981, 37:2091~2096.
3. [3]
  J Sedelmeier, S V Ley, I R Baxendale et al. Org. Lett., 2010, 12:3618~3621.
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
  X A Wu, P Ying, J Y Liu. Synth. Commun., 2009, 39(19):3459~3470.
9. [9]
  H L Goering, A C Backus, C S Chang et al. J. Org. Chem., 1975, 40(11):1533~1535.
10. [10]
  P Marcé, J Lynch, A J Blacker et al. Chem. Commun., 2016, 52(5):1013~1016.
11. [11]
  X Y Wang, Z P Shang, G F Zha. Tetrahed. Lett., 2016, 57(50):5628~5631.
12. [12]
  R Zheng, Q Z Zhou, H N Gu. Tetrahed. Lett., 2014, 55(41):5671~5675.
13. [13]
  BBarati, M Moghadam, A Rahmati et al. Synlett, 2013, 24(1):90~96.
14. [14]
  S Battula, A Kumar, Q N Ahmed. Org. Biomol. Chem., 2015, 13(39):9953~9956.
15. [15]
  V VPatil, G S Shankarling. J. Org. Chem., 2015, 80(16):7876~7883.
16. [16]
  A H A Youssef, H M Abdel-Maksoud. J. Org. Chem., 1975, 40(22):3227~3229.
17. [17]
  X H Wei, S J Yang, N Liang et al. Molecules, 2013, 18(1):1325~1336.
18. [18]
  O Marvi, M Talakoubi. Orient. J. Chem., 2016, 32(1):359~365.
19. [19]
  A N Manin, A P Voronin, K V Drozd et al. Eur. J. Pharm. Sci., 2014, 65:56~64.
20. [20]
  A Correa, R Martin. J. Am. Chem. Soc., 2009, 131(44):15974~15975.
21. [21]
  F Tellier, R Sauvetre. Tetrahed. Lett., 1993, 34(34):5433~5436.
1. [1]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
6. [6]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
7. [7]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
8. [8]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
9. [9]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
10. [10]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
11. [11]
  Lisen Sun , Yongmei Hao , Zhen Huang , Yongmei Liu . Experimental Teaching Design for Viscosity Measurement Serves the Optimization of Operating Conditions for Kitchen Waste Treatment Equipment. University Chemistry, 2024, 39(2): 52-56. doi: 10.3866/PKU.DXHX202307063
12. [12]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
13. [13]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
14. [14]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
18. [18]
  Liu Lin , Zemin Sun , Huatian Chen , Lian Zhao , Mingyue Sun , Yitao Yang , Zhensheng Liao , Xinyu Wu , Xinxin Li , Cheng Tang . Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(4): 2305019-0. doi: 10.3866/PKU.WHXB202305019
19. [19]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
20. [20]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194

Get Citation

PDF

XML

Metrics

PDF Downloads(66)
Abstract views(7867)
HTML views(2689)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142