Citation: SUI Meng, LI Fa-she, WU Xue-hua, WANG Shuang, LI Ming. Preparation of anionic functionalized ionic liquid antioxidant[X] [C₆H₅COO] for biodiesel[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(1): 66-73. shu

Preparation of anionic functionalized ionic liquid antioxidant[X] [C₆H₅COO] for biodiesel

SUI Meng ^1,2 ,
LI Fa-she ^1,2,, ,
WU Xue-hua ^1,3 ,
WANG Shuang ² ,
LI Ming ⁴

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Engineering Research Center of Metallurgical Energy Conservation & Emission Reduction, Ministry of Education, Kunming 650093, China
3.
Kunming University of Science and Technology, Kunming 650093, China
4.
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510000, China

Corresponding author: LI Fa-she, asan97@qq.com
Received Date: 6 August 2018
Revised Date: 6 November 2018

Fund Project: Natural Science Foundation of Yunnan Province 2015FB128State Key Laboratory of Clean and Applied Utilization of Complex Nonferrous Metal Resources CNMRCUTS1704The project was supported by the National Natural Science Foundation of China(51766007), Natural Science Foundation of Yunnan Province(2015FB128, 2018FB092), NSFC-Yunnan Joint Fund Project(U1602272), State Key Laboratory of Clean and Applied Utilization of Complex Nonferrous Metal Resources(CNMRCUTS1704) and Yunnan Science and Technology Department Foundation Youth project (2016FD055)Yunnan Science and Technology Department Foundation Youth project 2016FD055Natural Science Foundation of Yunnan Province 2018FB092NSFC-Yunnan Joint Fund Project U1602272the National Natural Science Foundation of China 51766007

Figures(12)

Two ionic liquid antioxidants ([MI] [C₆H₅COO], [Ch] [C₆H₅COO]) were designed, and synthesized, and measured by nuclear magnetic resonance spectra and Fourier infrared spectra.The effects of two ionic liquid antioxidants on the oxidation resistance, copper corrosion and oil solubility of Jatropha biodiesel were studied.The results show that ionic liquid antioxidants can effectively improve the oxidative stability of biodiesel. When the addition amount of[MI] [C₆H₅COO] is 0.3‰, the induction period of Jatropha biodiesel increases by 238%, exceeding the national standard (6 h). However, when the addition amount of[Ch] [C₆H₅COO] is 0.3‰, the induction period of Jatropha biodiesel increases by 141%, which does not meet the national standard. The order of oil solubility from large to small is[MI] [C₆H₅COO] > [Ch] [C₆H₅COO] > GA (raw material for synthesizing ionic liquid antioxidants).Moreover, the experiments show that the synthetic properties of[MI] [C₆H₅COO] containing lipophilic cations in the two ionic liquid antioxidants are significantly better than those containing hydrophilic cations[Ch] [C₆H₅COO].
- ionic liquid,
- biodiesel,
- antioxidants,
- oil solubility,
- oxidative stability
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Preparation of anionic functionalized ionic liquid antioxidant[X] [C6H5COO] for biodiesel

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Preparation of anionic functionalized ionic liquid antioxidant[X] [C₆H₅COO] for biodiesel