Citation: LIU Dian-bin, LI Wei, LI Shi-yuan, KONG Run-juan. Influences of ammonium sulfate additive on Cl and N co-transformation during biomass/semi-coke oxy-fuel co-combustion[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(1): 28-35. shu

Influences of ammonium sulfate additive on Cl and N co-transformation during biomass/semi-coke oxy-fuel co-combustion

  • Corresponding author: LI Shi-yuan, lishiyuan@iet.cn
  • Received Date: 26 August 2019
    Revised Date: 27 November 2019

    Fund Project: the National Natural Science Foundation of China 51706227The project was supported by the National Natural Science Foundation of China (51706227)

Figures(13)

  • To investigate the influences of ammonium sulfate(AS) on the K/S/Cl transformation and N2O/NO emission, the biomass and semi-coke were co-combusted in a 50 kW circulating fluidized bed under O2/CO2 atmosphere. The experimental results show that AS can reduce the Cl content in deposits obviously and decrease the NO concentration in flue gas significantly. Besides, AS can retain more K in bottom ash and circulating ash, thereby reducing the K content in deposits. In terms of reducing Cl in deposits, the top half of the riser is the optimal position to inject AS.
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    1. [1]

      LUO Zhong-yang, CHEN Chen, YU Chun-jiang. Review of deposition and high-temperature corrosion in biomass-fired boilers[J]. J Combust Sci Technol, 2014,20(3):189-198.  

    2. [2]

      GOUGH C, UPHAM P. Biomass energy with carbon capture and storage (BECCS or Bio-CCS)[J]. Greenhouse Gases:Sci Technol, 2011,1(4):324-334. doi: 10.1002/ghg.34

    3. [3]

      NIELSEN H P, FRANDSEN F J, DAM-JOHANSEN K, BAXTER L L. The implications of chlorine-associated corrosion on the operation of biomass-fired boilers[J]. Prog Energy Combust, 2000,26(3):283-298. doi: 10.1016/S0360-1285(00)00003-4

    4. [4]

      YU C, QIN J, NIE H, FANG M, LUO Z. Experimental research on agglomeration in straw-fired fluidized beds[J]. Appl Energy, 2011,88(12):4534-4543. doi: 10.1016/j.apenergy.2011.05.046

    5. [5]

      BIE Ru-shan, LI Bing-xi, LU Hui-lin, YANG Li-dan. Biomass-fired fluidized bed boilers[J]. J Eng Therm Energy Power, 2000,15(88):345-347.  

    6. [6]

      DAYTON D C, JENKINS B M, TURN S Q, BAKKER R R, WILLIAMS R B, BELLE-OUDRY D, HILL L M. Release of inorganic constituents from leached biomass during thermal conversion[J]. Energy Fuels, 1999,13(4):860-870. doi: 10.1021/ef980256e

    7. [7]

      DAVIDSSON K O, KORSGREN J G, PETTERSSON J B C, JALID U. The effects of fuel washing techniques on alkali release from biomass[J]. Fuel, 2002,81(2):137-142. doi: 10.1016/S0016-2361(01)00132-6

    8. [8]

      AHO M, VAINIKKA P, TAIPALE R, YRJAS P. Effective new chemicals to prevent corrosion due to chlorine in power plant superheaters[J]. Fuel, 2008,87(6):647-654. doi: 10.1016/j.fuel.2007.05.033

    9. [9]

      KASSMAN H, BAFVER L, ÅMAND L E. The importance of SO2 and SO3 for sulphation of gaseous KCl:An experimental investigation in a biomass fired CFB boiler[J]. Combust Flame, 2010,157(9):1649-1657. doi: 10.1016/j.combustflame.2010.05.012

    10. [10]

      KASSMAN H, PETTERSSON J, STEENARI B M, AMAND L E. Two strategies to reduce gaseous KCl and chlorine in deposits during biomass combustion-injection of ammonium sulphate and co-combustion with peat[J]. Fuel Process Technol, 2013,105:170-180. doi: 10.1016/j.fuproc.2011.06.025

    11. [11]

      KASSMAN H, BROSTROM M, BERG M, AMAND L E. Measures to reduce chlorine in deposits:Application in a large-scale circulating fluidized bed boiler firing biomass[J]. Fuel, 2011,90(4):1325-1334. doi: 10.1016/j.fuel.2010.12.005

    12. [12]

      NORLING R, NAFARI A, NYLUND A. Erosion-corrosion of Fe-and Ni-based tubes and coatings in a fluidized bed test rig during exposure to HCl- and SO2-containing atmospheres[J]. Wear, 2005,258(9):1379-1383. doi: 10.1016/j.wear.2004.05.028

    13. [13]

      MAYORAL M C, ANDRES J M, BELZUNCE J, HIGUERA V. Study of sulphidation and chlorination on oxidized SS310 and plasma-sprayed Ni-Cr coatings as simulation of hot corrosion in fouling and slagging in combustion[J]. Corros Sci, 2006,48(6):1319-1336. doi: 10.1016/j.corsci.2005.06.004

    14. [14]

      PHONGPHIPHAT A, RYU C, YANG Y B, FINNEY K N, LEYLAND A, SHARIFI V N, SWITHENBANK J. Investigation into high-temperature corrosion in a large-scale municipal waste-to-energy plant[J]. Corros Sci, 2010,52(12):3861-3874. doi: 10.1016/j.corsci.2010.07.032

    15. [15]

      HUANG Fang. Study on the deposit and corrosion problem on heating surface during straw combustion[D]. Hangzhou: Zhejiang Univeristy, 2013.

    16. [16]

      HE Xiao-ming, ZHAO Bin-tao. Emission and conversion characteristics of NO and SO2 from Co-firing of algae biomass and coal[J]. J Chin Soc Power Eng, 2019,39(6):474-477.  

    17. [17]

      JI X, BIE H, ZHANG Y, CHEN P, FANG W, BIE R. Release of K and Cl and emissions of NOx and SO2 during reed black liquor combustion in a fluidized bed[J]. Energy Fuels, 2017,31(2):1631-1637. doi: 10.1021/acs.energyfuels.6b02701

    18. [18]

      CHEN An-he. Investigation of chlorine, alkalis, NOx and N2O emissions during coal-biomass Co-firing[D]. Beijing: Institute of Process Engineering, Chinese Academy of Sciences, 2007.

    19. [19]

      XIE Jing-si, CHENG Shi-qing, ZHANG Hui-min, ZHANG Hai-rui, LIU Kun. Experimental study on no emission characteristic:of-firing of biomass and coal in O2/CO2 atmosphere[J]. Therm Power Gener, 2012,41(8):38-42.  

    20. [20]

      HANSEN L A, NIELSEN H P, FRANDSEN F J, DAM-JOHANSEN K, HORLYCK S, KARLSSON A. Influence of deposit formation on corrosion at a straw-fired boiler[J]. Fuel Process Technol, 2000,64(1):189-209.  

    21. [21]

      DAVIDSSON K O, AMAND L E, STEENARI B M, ELLED A L, ESKILSSON D, LECHNER B. Countermeasures against alkali-related problems during combustion of biomass in a circulating fluidized bed boiler[J]. Chem Eng Sci, 2008,63(21):5314-5329. doi: 10.1016/j.ces.2008.07.012

    22. [22]

      BROSTROM M, KASSMAN H, HELGESSON A, BERG M, ANDERSSON C, BACKMAN R, NORDIN A. Sulfation of corrosive alkali chlorides by ammonium sulfate in a biomass fired CFB boiler[J]. Fuel Process Technol, 2007,88(11/12):1171-1177.  

    23. [23]

      LIU D, LI W, LI S. Fundamental study of heterogeneous KCl sulfation under oxy-fuel combustion conditions[J]. Int J Energy Res, 2019,43(9):4093-4103. doi: 10.1002/er.4501

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