Citation: YANG Li-xia, LIU Dan, SHANG Ya-ning, ZHANG Peng, LIU Cheng-wei, GUI Jian-zhou. A simple and controllable preparation of double salt Na2MgCO3 as an efficient CO2 absorbent[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 886-890. shu

A simple and controllable preparation of double salt Na2MgCO3 as an efficient CO2 absorbent

  • Corresponding author: LIU Dan, ldan2000@163.com GUI Jian-zhou, jzgui@hotmail.com
  • Received Date: 2 April 2018
    Revised Date: 24 May 2018

    Fund Project: The project was supported by the National Nature Science Foundation of China (21576211), Key Scientific and Innovative Research Team in the University of Tianjin (TD13-5031) and 131 Innovation Team of Tianjin131 Innovation Team of Tianjin  the National Nature Science Foundation of China 21576211Key Scientific and Innovative Research Team in the University of Tianjin TD13-5031

Figures(7)

  • A series of sodium-magnesium double-salt as CO2 absorption materials with controllable morphologies were prepared by simple mixing method using sodium carboxymethyl cellulose as morphology-directing agent, and then characterized by XRD, SEM and TG. Finally, their CO2 absorption capability was evaluated by both saturation absorption tests at fixed temperature and dynamic absorption-desorption cyclic experiments. A uniform nanosheet-assembled absorbent, with 0.3 g sodium carboxymethyl cellulose added during preparation, can be obtained with a saturated absorption capacity of 22.8%. Meanwhile, good recycling capacity has been maintained at about 9.7% without apparent changes even after 20 cycles of dynamic absorption-desorption experiment.
  • 加载中
    1. [1]

      MIKKELSEN M, JØRGENSNM , KREBS F C. A review of fixation and transformation of carbon dioxide[J]. Energy Environ Sci, 2009,3(1):43-81.  

    2. [2]

      LU Jian-gang, ZHANG Hui, CHENG Min-dong, WANG Lian-jun. CO2 capture through membrane gas absorption with aqueous solution of inorganic salts-amino acid salts[J]. J Fuel Chem Technol, 2009,37(1):77-81.  

    3. [3]

      ROTH E A, AGARWAL S, GUPTA R K. Nanoclay-based solid sorbents for CO2capture[J]. Energy Fuels, 2013,27(8):4129-4136. doi: 10.1021/ef302017m

    4. [4]

      WANG J Y, HUANG L, YANG R Y, ZHANG Z, WU J W, GAO Y S, WANG Q, OHARE D, ZHONG Z Y. Recent advances in solid sorbents for CO2 capture and new development trends[J]. Energy Environ Sci, 2014,7(11):3478-3518. doi: 10.1039/C4EE01647E

    5. [5]

      SREENIVASULU B, SREEDHAR I, SURESH P, RAGHAVAN K V. Development trends in porous adsorbents for carbon capture[J]. Environ Sci Technol, 2015,49(21):12641-12661. doi: 10.1021/acs.est.5b03149

    6. [6]

      HARADA T, SIMEON F, HAMAD E Z, HATTON T A. Alkali metal nitrate-promoted high-capacity MgO adsorbents for regenerable CO2 capture at moderate temperatures[J]. Chem Mater, 2015,27(6):1943-1949. doi: 10.1021/cm503295g

    7. [7]

      HAN K K, ZHOU Y, LIN G, ZHU J H. One-pot synthesis of foam-like magnesia and its performance in CO2 adsorption[J]. Microporous Mesoporous Mater, 2013,169(6):112-119.  

    8. [8]

      LI P, LIU W, DENNIS J S, ZENG H C. Synthetic architecture of MgO/C nanocomposite from hierarchical-structured coordination polymer towards enhanced CO2 capture[J]. Acs Appl Mater Inter, 2017,9(11):9592-9602.  

    9. [9]

      YANG X F, ZHAO L F, LIU Y, SUN Z L, XIAO Y H. Carbonation performance of NaNO3 modified MgO sorbents[J]. Ind Eng Chem Res, 2017,56(1):342-350. doi: 10.1021/acs.iecr.6b03909

    10. [10]

      XIAO G K, SINGH R, CHAFFEE A, WEBLEY P. Advanced adsorbents based on MgO and K2CO3 for capture of CO2 at elevated temperatures[J]. Int J Greenh Gas Con, 2011,5(4):634-639. doi: 10.1016/j.ijggc.2011.04.002

    11. [11]

      ZHANG K L, LI X H S, DUAN Y H, KING D L, SINGH P, LI L Y. Roles of double salt formation and NaNO3 in Na2CO3-promoted MgOabsorbent for intermediate temperature CO2 removal[J]. Int J Greenh Gas Con, 2013,12(1):351-358.  

    12. [12]

      ZHANG K L, LI X H S, LI W Z, ROHATGI A, DUAN Y H, KING D L, SINGH P, LI L Y, KING D L. Phase transfer-catalyzed fast CO2 absorption by MgO-based absorbents with high cycling capacity[J]. Adv Mater Interfaces, 2014,1(3).  

    13. [13]

      ZUO Chen-sheng, ZHOU Si-yu, SUN Cheng-zhi, WANG Xing-zhi, LIU Dao-sheng, SEO Hwi-min, PARK Yong-Ki, GUI Jian-zhou, LIU Dan. Preparation and application of magnesium-based CO2 sorbent for temperature swing absorption(Ⅰ)Na/Mg mole ratio[J]. J Fuel ChemTechnol, 2014,42(7):884-889.  

    14. [14]

      LIU Dan, GUI Jian-zhou, YANG Li-xia, LI Yi, SUN Cheng-zhi. An intermediate temperature carbon dioxide adsorbent and its preparation method and application: CN, 104998600 A[P]. 2015-05-17.

    15. [15]

      YANG Li-xia, LIU Dan, LIU Dao-sheng, SUN Cheng-zhi, SEO Hwi-min, GUI Jian-zhou, PARK Yong-Ki. TiO2 modified magnesium-based adsorbents for intermediate-temperature CO2capture[J]. J Fuel Chem Technol, 2015,43(12):1498-1503. doi: 10.3969/j.issn.0253-2409.2015.12.014 

  • 加载中
    1. [1]

      Zhanglin Shi , Tao Xiu , Xinmeng Mao , Jianfeng Wu , Baoliang Zhang . Controllable construction and microwave absorption properties of TCF/Co@NC composite nanofibers. Acta Physico-Chimica Sinica, 2026, 42(11): 100306-0. doi: 10.1016/j.actphy.2026.100306

    2. [2]

      Xiuyun Wang ,  Jiashuo Cheng ,  Yiming Wang ,  Haoyu Wu ,  Yan Su ,  Yuzhuo Gao ,  Xiaoyu Liu ,  Mingyu Zhao ,  Chunyan Wang ,  Miao Cui ,  Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067

    3. [3]

      Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223

    4. [4]

      Lijuan Liu ,  Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060

    5. [5]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    6. [6]

      Laiying Zhang ,  Yinghuan Wu ,  Yazi Yu ,  Yecheng Xu ,  Haojie Zhang ,  Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126

    7. [7]

      Hongli CHEN , Ziling XU , Shiwen DU , Ting WANG , Liguang WU . Controlled preparation of HKUST-1 based on polyvinylpyrrolidone and CO2 separation performance of its doped mixed-matrix membranes. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 571-583. doi: 10.11862/CJIC.20250263

    8. [8]

      Baoshun Zhu , Xinyan Wang , Weipeng Mu , Xuanpeng Sun , Yubo Wang , Hongyu Wei , Pangyu Shi , Huilan Hao , Dashuang Wang , Guomin Li , Guizhen Wang . Recycling paper mill sludge to prepare low-cost Ni-modified carbon/silica composite for efficient microwave absorption. Acta Physico-Chimica Sinica, 2026, 42(11): 100417-0. doi: 10.1016/j.actphy.2026.100417

    9. [9]

      Qiang Wu ,  Wenhua Hou . Teaching Classical Contents Newly: Taking Temperature–Entropy Diagram as an Example. University Chemistry, 2025, 40(4): 399-407. doi: 10.12461/PKU.DXHX202407102

    10. [10]

      Chunguang Rong ,  Miaojun Xu ,  Xingde Xiang ,  Song Liu . 化学热力学熵变计算的教学探讨. University Chemistry, 2025, 40(8): 323-329. doi: 10.12461/PKU.DXHX202409146

    11. [11]

      Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065

    12. [12]

      Xiwen Xing ,  Muyi Guo ,  Zhuoran Hu ,  Shunchun Yao ,  Yao Sun . Context-Driven Teaching with Cue-Guided Reasoning: Taking X-Ray Teaching Practice as an Example. University Chemistry, 2025, 40(7): 141-147. doi: 10.12461/PKU.DXHX202409097

    13. [13]

      Jianquan Liu ,  Xiangshan Wang . Teaching Design and Practice of Naming Rules for Circular Isomer Configuration under the Guidance of Information Literacy. University Chemistry, 2025, 40(7): 352-358. doi: 10.12461/PKU.DXHX202409082

    14. [14]

      Yuyang Zhang ,  Yuqing Zhang ,  Quanxing Mao ,  Zixuan Chen ,  Ying Xiong . Application of Real-World Problem-Oriented Teaching Methods in Analytical Chemistry Course. University Chemistry, 2025, 40(10): 17-22. doi: 10.12461/PKU.DXHX202411072

    15. [15]

      Xin Dong ,  Ruimei Xu ,  Wenxia Zhao . Exploration of transmission electron microscope training model based on problem-based learning. University Chemistry, 2026, 41(7): 54-59. doi: 10.12461/PKU.DXHX202505034

    16. [16]

      Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn2S4 photocatalyst for H2O2 production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064

    17. [17]

      Xiyuan Su ,  Zhenlin Hu ,  Ye Fan ,  Xianyuan Liu ,  Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059

    18. [18]

      Lili Wang ,  Chunxia Chen ,  Lina Jia ,  Li Guo ,  Jingjing Cao . Exploration and Practice in Innovative and Interesting Scientific Research Skills Training for Wood Magnetization. University Chemistry, 2024, 39(6): 246-252. doi: 10.3866/PKU.DXHX202310088

    19. [19]

      Hong Zheng ,  Xin Peng ,  Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058

    20. [20]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

Metrics
  • PDF Downloads(14)
  • Abstract views(3044)
  • HTML views(323)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return