Citation: Qian CHENG, Yan Wen ZHANG, Xiang ZHANG, Takayuki ORITANI. An Expeditious Route for the Total Synthesis of Pondaplin Isolated from Annona glabra[J]. Chinese Chemical Letters, ;2003, 14(12): 1215-1218. shu

An Expeditious Route for the Total Synthesis of Pondaplin Isolated from Annona glabra

1.
Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku University, Sendai 981-8555, Japan;
2.
Laboratory of Medicinal Chemistry, College of Pharmacy, Tianjin Medical University, Tianjin 300203;
3.
Institute of Materia Medica, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 100050

Received Date: 19 November 2002

A novel cyclic prenylated phenylpropanoid, pondaplin 1, was first synthesized in 26% overall yields through an expeditious route (7 steps) that employed highly regio-and stereoselective phenyltellurenylation to arylacetylene and palladium (II) chloride-catalyzed carbonylation of hydroxy styryl phenyl telluride as key steps.
- Pondaplin,
- total synthesis,
- natural product
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