Citation: Xie Yanyan, Chai Yun, Zhang Puyu. Study on Dissolving Cellulose by Ionic Liquids[J]. Chemistry, ;2020, 83(12): 1104-1112. shu

Study on Dissolving Cellulose by Ionic Liquids

Figures(6)

  • Cellulose is a type of biodegradable natural polymer material, however, it is difficult to be dissolved in water and common organic solvents due to the strong inter- and intra-molecular hydrogen bonds. The traditional solvents have disadvantages such as poor stability, toxicity, and difficulty in recycling. Therefore, searching for a new green solvent has become a hot but difficult point in the development of cellulose. Ionic liquid is a new and efficient green solvent, which can dissolve cellulose, keratin and other biological macromolecules under certain conditions. The emergence of ionic liquids provides an environmentally friendly and biodegradable solvent system for the dissolution of cellulose, which has a broad application prospect. This review summarized the solubility of cellulose dissolved by different kinds of ionic liquid and several factors affecting the solubility, the mechanism of action between ionic liquid and cellulose and the recovery method of ionic liquids, which provides theoretical basis and industrial guidance for the processing and utilization of cellulose.
  • 加载中
    1. [1]

      Wang H, Gurau G, Rogers R D. Chem. Soc. Rev., 2012, 41(4): 1519~1537. 

    2. [2]

      Pinkert A, Marsh K N, Pang S S, et al. Chem. Rev., 2009, 109(12): 6712~6728. 

    3. [3]

       

    4. [4]

       

    5. [5]

      Cao Y, Zhang R, Cheng T, et al. Appl. Microbiol. Biot., 2016, 101(2): 521~532.

    6. [6]

    7. [7]

      Fink P W, Hans J Pur, Johannes G. Prog. Polym. Sci., 2001, 26(9): 1473~1524. 

    8. [8]

       

    9. [9]

       

    10. [10]

      Cai J, Zhang L N. Biomacromolecules, 2006, 7(1): 183~189. 

    11. [11]

      Wang Y, Liu L, Chen P, et al. Phys. Chem. Chem. Phys., 2018, 20(20): 14223~14233. 

    12. [12]

      Graenacher C. USP: 1943176, 1934.

    13. [13]

      Zhu S, Wu Y, Chen Q, et al. Green Chem., 2006, 8: 325~327. 

    14. [14]

      Swatloski R P, Spear S K, Holbrey J D, et al. J. Am. Chem. Soc., 2002, 124(18): 4974~4975. 

    15. [15]

       

    16. [16]

       

    17. [17]

      Hauru L K J, Hummel M, Koschella A, et al. Cellulose, 2014, 21(6): 4417~4481.

    18. [18]

       

    19. [19]

      Zhao D S, Li H, Zhang J, et al. Carbohydr. Polym., 2012, 87(2): 1490~1494. 

    20. [20]

      Hokayem A K, Hage E R, Svecova L, et al. Molecules, 2020, 25(7): 1629~1647. 

    21. [21]

      Nguyen N A, Kim K, Bowland C C, et al. Green Chem., 2019, 21(16): 4354~4367. 

    22. [22]

      Isik M, Sardon H, Mecerreyes D. Int. J. Mol. Sci., 2014, 15(7): 11922~11940. 

    23. [23]

      Olivierbourbigou H, Magna L, Morvan D. Appl. Catal. A-Gen., 2010, 373(1): 1~56. 

    24. [24]

      Lethesh K C, Evjen S, Venkatraman V, et al. Carbohydr. Polym., 2020, 229: 115594 

    25. [25]

      Grossereid I, Lethesh K C, Venkatraman V, et al. J. Mol. Liq., 2019, 292: 111353. 

    26. [26]

      Sixta H, Michud A, Hauru L K J, et al. Nord. Pulp. Pap. Res. J., 2015, 30(1): 43~57. 

    27. [27]

      Raut D G, Sundman O, Su W, et al. Carbohydr. Polym., 2015, 130: 18~25. 

    28. [28]

      King A W T, Asikkala J, Mutikainen I, et al. Angew. Chem. Int. Ed., 2011, 50(28): 6301~6305. 

    29. [29]

       

    30. [30]

      Heinze T, Dicke R, Koschella A, et al. Macromol. Chem. Phys., 2000, 201(201): 627~631.

    31. [31]

    32. [32]

      Ren H, Zong M H, Wu H, et al. Ind. Eng. Chem. Res., 2016, 55(6): 1788~1795. 

    33. [33]

    34. [34]

      Ohira K, Abe Y, Kawatsura M, et al. ChemSusChem, 2012, 5(2): 388~391. 

    35. [35]

      Abe M, Fukaya Y, Ohno H. Chem. Commun., 2012, 48(12): 1808~1810. 

    36. [36]

      Cheng G, Varanasi P, Arora R, et al. J. Phys. Chem. B, 2012, 116(33): 10049~10054. 

    37. [37]

      Yuan X, Yuan C P, Shi W T, et al. ChemistrySelect, 2017, 2(13): 3783~3787. 

    38. [38]

      Gale E, Wirawan R H, Silveira R L, et al. ACS Sustain. Chem. Eng., 2016, 4(11): 6200~6207. 

    39. [39]

       

    40. [40]

    41. [41]

      Xu A R, Cao L L, Wang B J. Carbohydr. Polym., 2015, (125): 249~254. 

    42. [42]

      Velioglu S, Yao X, Devemy J, et al. J. Phys. Chem. B, 2014, 118(51): 14860. 

    43. [43]

      Andanson J, Padua A A H, Gomes M F C. Chem. Commun., 2015, 51(21): 4485~4487. 

    44. [44]

      Andanson J, Bordes E, Devemy J, et al. Green Chem., 2014, 16(5): 2528~2538. 

    45. [45]

       

    46. [46]

       

    47. [47]

      Liu R, Zhang J, Sun S, et al. J. Eng. Fiber Fabr., 2019, 14: 1~7.

    48. [48]

      Li Y, Wang J J, Liu X M, et al. Chem. Sci., 2018, 9(17): 4027~4043. 

    49. [49]

      Li Y, Liu X M, Zhang S J, et al. Phys. Chem. Chem. Phys., 2015, 17(27): 17894~17905. 

    50. [50]

      Fukaya Y, Hayashi K, Wada M, et al. Green Chem., 2008, 10(1): 44~46. 

    51. [51]

      Lu B L, Xu A R, Wang J J. Green Chem., 2014, 16(3): 1326~1335. 

    52. [52]

      Li Y, Liu X M, Zhang Y Q, et al. ACS Sustain. Chem. Eng., 2017, 5(4): 3417~3428. 

    53. [53]

      Li X, Li H C, Ling Z, et al. Macromolecules, 2020, 53(9): 3284~3295. 

    54. [54]

      Lindman B, Karlstrom G, Stigsson L. J. Mol. Liq., 2010, 156(1): 76~81. 

    55. [55]

    56. [56]

       

    57. [57]

      Vitz J, Erdmenger T, Haensch C, et al. Green Chem., 2009, 11(3): 417~424. 

    58. [58]

      Mazza M, Catana D, Vacagarcia C, et al. Cellulose, 2009, 16(2): 207~215. 

    59. [59]

      Zhang J M, Wu J, Yu J, et al. Mater. Chem. Front., 2017, 1(7): 1273~1290. 

    60. [60]

      André Pinkert K N M, Pang S S. Ind. Eng. Chem. Res., 2010, 49(22): 11121~11130. 

    61. [61]

    62. [62]

    63. [63]

      Wang Y, Liu L, Chen P, et al. Phys. Chem. Chem. Phys., 2018, 20(20): 14223~14233. 

    64. [64]

       

    65. [65]

      Zhao Y L, Liu X M, Wang J J, et al. Carbohydr. Polym., 2013, 94(2): 723~730. 

    66. [66]

      Yuan X M, Cheng G. Phys. Chem. Chem. Phys., 2015, 17(47): 31592~31607. 

    67. [67]

       

    68. [68]

       

    69. [69]

      Huang J, Hou S N, Chen R Y. Bioresources, 2019, 14(4): 7805~7820.

    70. [70]

       

  • 加载中
    1. [1]

      Xiuqiong Zeng Jiqing Cai Chen Chen Yanping Ren Wan Li Yongxian Fan Faqiong Zhao Wenwei Zhang Mei Shi Min Hu Kai Hu Xiuyun Wang Weihong Li Yong Fan Xiaohang Qiu Juanjuan Song Dongcheng Liu Jianrong Zhang Shuyong Zhang . Suggestions on Dissolution, Crystallization and Crystal Cultivation. University Chemistry, 2026, 41(3): 191-199. doi: 10.12461/PKU.DXHX202507045

    2. [2]

      Yameen AhmedXiangxiang FengYuanji GaoYang DingCaoyu LongMustafa HaiderHengyue LiZhuan LiShicheng HuangMakhsud I. SaidaminovJunliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI3 Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057

    3. [3]

      Qiang ZhangYuanbiao HuangRong Cao . Imidazolium-Based Materials for CO2 Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040

    4. [4]

      Xiaoning TANGJunnan LIUXingfu YANGJie LEIQiuyang LUOShu XIAAn XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191

    5. [5]

      Yan'e LIUShengli JIAYifan JIANGQinghua ZHAOYi LIXinshu CHANG . MoO3/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054

    6. [6]

      Lisha LEIWei YONGYiting CHENGYibo WANGWenchao HUANGJunhuan ZHAOZhongjie ZHAIYangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202

    7. [7]

      Chao WUQingxiu SHITao XUZhengxi PENGZhongping XIONGYinglin ZHANGYujun SIChaozhong GUO . Enhancement of oxygen reduction reaction performance of iron-nitrogen doped carbon based catalysts by sodium carboxymethyl cellulose pre-deoxygenation. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 737-746. doi: 10.11862/CJIC.20250305

    8. [8]

      Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020

    9. [9]

      Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121

    10. [10]

      Yonghui Wang Weilin Chen Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102

    11. [11]

      Li'na ZHONGJingling CHENQinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280

    12. [12]

      Ling Li Guocheng Wang . 知识图谱与AI助教在无机化学混合式教学中的初步探索——以“沉淀溶解平衡”的教学为例. University Chemistry, 2025, 40(6): 1-8. doi: 10.12461/PKU.DXHX202407063

    13. [13]

      Shijie LiKe RongXiaoqin WangChuqi ShenFang YangQinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta3N5 S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005

    14. [14]

      Jun HuangPengfei NieYongchao LuJiayang LiYiwen WangJianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-0. doi: 10.1016/j.actphy.2025.100066

    15. [15]

      Ying LiYushen ZhaoKai ChenXu LiuTingfeng YiLi-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007

    16. [16]

      Yingran Liang Fei WangJiabao Sun Hongtao Zheng Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024

    17. [17]

      Mei Yan Rida Feng Yerdos·Tohtarkhan Biao Long Li Zhou Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103

    18. [18]

      Benhua Wang Chaoyi Yao Yiming Li Qing Liu Minhuan Lan Guipeng Yu Yiming Luo Xiangzhi Song . 一种基于香豆素氟离子荧光探针的合成、表征及性能测试——“科研反哺教学”在有机化学综合实验教学中的探索与实践. University Chemistry, 2025, 40(6): 201-209. doi: 10.12461/PKU.DXHX202408070

    19. [19]

      Kexin DongChuqi ShenRuyu YanYanping LiuChunqiang ZhuangShijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013

    20. [20]

      Cuiping Yang Huiping Ding Jinpeng Hou Kai Li Weiliang Tian . Reform and Exploration of “Comprehensive and Precise Process” Assessment in Chemical Engineering Principle Experimental Course. University Chemistry, 2024, 39(3): 178-190. doi: 10.3866/PKU.DXHX202309087

Metrics
  • PDF Downloads(159)
  • Abstract views(6905)
  • HTML views(2027)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return