Citation: YU Jie, WANG Jing-yun, WANG Zhen, ZHOU Ming-dong, WANG Hai-yan. Synthesis of composite zeolites and their performance in hydrolysis of cellulose[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(4): 419-426. shu

Synthesis of composite zeolites and their performance in hydrolysis of cellulose

YU Jie ^1,2,3 ,
WANG Jing-yun ² ,
WANG Zhen ² ,
ZHOU Ming-dong ^2,, ,
WANG Hai-yan ^1,2,,

1.
College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China
2.
School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China
3.
Shenyang Paraffin Chemical Co Ltd, Shenyang 110141, China

Corresponding author: ZHOU Ming-dong, mingdong.zhou@lnpu.edu.cn WANG Hai-yan, haiyan.wang@lnpu.edu.cn
Received Date: 25 December 2017
Revised Date: 26 February 2018

Fund Project: Talent Scientific Research Fund of LSHU 2016XJJ-063Natural Science Foundation of Liaoning Province 2015020196the National Science Foundation of China 21101085Natural Science Foundation of Liaoning Province 20170540590The project was supported by the National Science Foundation of China (21101085), Natural Science Foundation of Liaoning Province (2015020196, 20170540590), the Fushun Science & Technology Program (FSKJHT 201423), the Liaoning Excellent Talents Program in University (LJQ2012031), Talent Scientific Research Fund of LSHU (2016XJJ-063)the Fushun Science & Technology Program FSKJHT 201423the Liaoning Excellent Talents Program in University LJQ2012031

Figures(7)

In this paper, core-shell composite zeolites (HUSY@MFI) were prepared by hydrothermal method. The composite zeolites were characterized by XRD, SEM, N₂-adsorption, NH₃-TPD and Py-FTIR. The results indicated that HUSY@MFI has both HUSY and MFI structure. Scanning Electron Microscope (SEM) reflects a core-shell morphology of HUSY@MFI. The particles displayed an elliptical sphere structure with scale-like surface. The growth of MFI shell results in a decrease of external acid density and the total acid sites. When the HUSY@MFI was used as catalyst instead of HUSY in hydrolysis of cellulose to glucose in 1-ethyl-3-methylimidazolium chloride ([Emim]Cl), the glucose yield could be significantly improved from 30.9% to 41.3%.
- HUSY@MFI,
- HUSY,
- cellulose,
- hydrolysis,
- glucose
1. [1]
  PEREGO C, BOSETTI A B. Biomass to fuels:The role of zeolite and mesoporous materials[J]. Microporous Mesoporous Mater, 2011,144:28-39. doi: 10.1016/j.micromeso.2010.11.034
2. [2]
  GOYAL H B, SEAL Diptendu, SAXENA R C. Bio-fuels from thermochemical conversion of renewable resources:A review[J]. Renewable Sustainable Energy Rev, 2008,12:504-517. doi: 10.1016/j.rser.2006.07.014
3. [3]
  GUO H X, LIAN Y F, YAN L L, QI X H, SMITH R. Cellulose-derived superparamagnetic carbonaceous solid acid catalyst for cellulose hydrolysis in an ionic liquid or aqueous reaction system[J]. Green Chem, 2013,15:2167-2174. doi: 10.1039/c3gc40433a
4. [4]
  CHUNDAWAT S P S, BECKHAM G T, HIMMEL M E, DALE B E. Deconstruction of lignocellulosic biomass to fuels and chemicals[J]. Annu Rev Chem Biomol Eng, 2011,2:121-145. doi: 10.1146/annurev-chembioeng-061010-114205
5. [5]
  GEBOERS J, VYVER S V, OOMS R, BEECK B, JACOBS P, SELS B F. Chemocatalytic conversion of cellulose:Opportunities, advances and pitfalls[J]. Catal Sci Technol, 2011,1:1714-1726.
6. [6]
  CHANDRAKANT P, BISARIA V S. Simultaneous bioconversion of cellulose and hemicellulose to ethanol[J]. Crit Rev Biotechnol, 1998,18(4):295-331. doi: 10.1080/0738-859891224185
7. [7]
  DENG W P, ZHANG Q H, WANG Y. Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural, levulinic acid, and lactic acid[J]. Sci China Chem, 2015,58(1):29-46. doi: 10.1007/s11426-014-5283-8
8. [8]
  TAN M X, ZHAO L, ZHANG Y G. Production of 5-hydroxymethyl furfural from cellulose in CrCl₂/Zeolite/BMIMCl system[J]. biomass and bioenergy, 2011,35:1367-1370. doi: 10.1016/j.biombioe.2010.12.006
9. [9]
  RINALDI R, SCHÜTH F. Acid hydrolysis of cellulose as the entry point into biorefinery schemes[J]. Chemsuschem, 2009,21:1096-1107.
10. [10]
  TORGET R W, KIM J, LEE Y Y. Fundamental aspects of dilute acid hydrolysis/fractionation kinetics of hardwood carbohydrates. 1. Cellulose hydrolysis[J]. Ind Eng Chem Res, 2000,39:2817-2825. doi: 10.1021/ie990915q
11. [11]
  ZHAO Bo, HU Shang-lian, GONG Dao-yong, LI Hui-ping. New advances on hydrolysis of cellulose to glucose by solid acid[J]. Chem Ind Eng Prog, 2017,36(2):555-567.
12. [12]
  SHEN Shu-guang, LI Huan-mei, WANG Tao, CAI Bei, QIN Hai-feng, WANG Chun-yan. Effect of coal rank on structure of coal-based solid acids and their catalytic performance in cellulose hydrolysis[J]. J Fuel Chem Technol, 2013,41(12):1466-1472.
13. [13]
  CAI H L, LI C Z, WANG A Q, XU G L, ZHANG T. Zeolite-promoted hydrolysis of cellulose in ionic liquid, insight into the mutual behavior of zeolite, cellulose and ionic liquid[J]. Appl Catal B:Environ, 2012,123/124:333-338. doi: 10.1016/j.apcatb.2012.04.041
14. [14]
  LAI D M, DENG L, GUO Q X, FU Y. Hydrolysis of biomass by magnetic solid acid[J]. Energy Environ Sci, 2011,4:3552-3557. doi: 10.1039/c1ee01526e
15. [15]
  RINALDI R, PALKOVITS R, SCHUTH F. Depolymerization of cellulose using solid catalysts in ionic liquids[J]. Angew Chem Int Ed, 2008,47:8047-8050. doi: 10.1002/anie.v47:42
16. [16]
  GUO H X, QI X H, LI L Y, SMITH R L. Hydrolysis of cellulose over functionalized glucose-derived carbon catalyst in ionic liquid[J]. Bioresour Technol, 2012,116:355-359. doi: 10.1016/j.biortech.2012.03.098
17. [17]
  SATOSHI S, MASAAKI K, DAIZO Y, KIYOTAKA N, HIDEKI K, SHIGENOBU H, MICHIKAZU H. Hydrolysis of cellulose by amorphous carbon bearing SO₃H, COOH, and OH groups[J]. J Am Chem Soc, 2008,130(38):12787-12793. doi: 10.1021/ja803983h
18. [18]
  ZHOU L P, LIU Z, SHI M T, DU S S, SUA Y L, YANG X M, XU J. Sulfonated hierarchical H-USY zeolite for efficient hydrolysis of hemicellulose/cellulose[J]. Carbohydrate Polymers, 2013,98:146-151. doi: 10.1016/j.carbpol.2013.05.074
19. [19]
  ONDA A, OCHI T, YANAGISAWA K. Selective hydrolysis of cellulose into glucose over solid acid catalysts[J]. Green Chem, 2008,10(10):1033-1037. doi: 10.1039/b808471h
20. [20]
  SWATLOSKI R P, SPEAR S K, HOLBREY J D, ROGERS R D. Dissolution of cellose with ionic liquids[J]. J Am Chem Soc, 2002,124(18):4974-4975. doi: 10.1021/ja025790m
21. [21]
  LOPES A M D C, JOÃO K G, RUBIK D F, BOGE-ŁUKASIK E, DUARTE L, ANDREAUS J, BOGEL-ŁUKASIK R. Pre-treatment of lignocellulosic biomass using ionic liquids:Wheat straw fractionation[J]. Bioresour Technol, 2013,142:198-208. doi: 10.1016/j.biortech.2013.05.032
22. [22]
  LOPES A M D C, BOGEL-ŁUKASIK R. Acidic ionic liquids as sustainable approach of cellulose and lignocellulosic biomass conversion without additional catalysts[J]. ChemSusChem, 2015,8:947-965. doi: 10.1002/cssc.v8.6
23. [23]
  TAO F R, SONG H L, CHOU L J. Hydrolysis of cellulose in SO₃H-functionalized ionic liquids[J]. Bioresour Technol, 2011,102:9000-9006. doi: 10.1016/j.biortech.2011.06.067
24. [24]
  WANG J Y, ZHOU M D, YUAN Y G, ZHANG Q, FANG X C, ZANG S L. Hydrolysis of cellulose catalyzed by quaternary ammonium perrhenates in 1-allyl-3-methylimidazolium chloride[J]. Bioresour Technol, 2015,197:42-47. doi: 10.1016/j.biortech.2015.07.110
25. [25]
  YUAN Y G, WANG J Y, FU N H, ZANG S L. Hydrolysis of cellulose in 1-allyl-3-methylimidazolium chloride catalyzed by methyltrioxorhenium[J]. Catal Commun, 2016,76:46-49. doi: 10.1016/j.catcom.2015.12.024
26. [26]
  ABOU-YOUSEF H, HASSAN E B. A novel approach to enhance the activity of H-form zeolite catalyst for production of hydroxymethylfurfural from cellulose[J]. J Ind Eng Chem, 2014,20:1952-1957. doi: 10.1016/j.jiec.2013.09.016
27. [27]
  ZHANG Z H, ZHAO Z B. Solid acid and microwave-assisted hydrolysis of cellulose in ionic liquid[J]. Carbohydrate Res, 2009,344:2069-2072. doi: 10.1016/j.carres.2009.07.011
28. [28]
  ZHOU L P, LIU Z, BAI Y Q, LU T L, YANG X M, XU J. Hydrolysis of cellobiose catalyzed by zeolites-the role of acidity and micropore structure[J]. J Energy Chem, 2016,25:141-145. doi: 10.1016/j.jechem.2015.11.010
29. [29]
  ZHENG J J, SUN X B. Structural features of core-shell zeolite-zeolite composite and its performance for methanol conversion into gasoline and diesel[J]. J Mater Res, 2016,31:2302-2316. doi: 10.1557/jmr.2016.208
30. [30]
  MILLER G L. Use of dinitrosaiicyiic acid reagent for determination of reducing sugar[J]. Anal Chem, 1959,31:426-428. doi: 10.1021/ac60147a030
31. [31]
  MAO R, RAMSARAN A, XIAO S Y, YAO J H, SEMMER V. PH of the sodium carbonate solution used for the desilication of zeolite materials[J]. J Materials Chem, 1995,5(3):533-535. doi: 10.1039/jm9950500533
32. [32]
  GROEN J C, MOULIJN J A, PÉREZ-RAMÍREZ J. Desilication:On the controlled generation of mesoporosity in MFI zeolites[J]. J Mater Chem, 2006,16(22):2121-2131. doi: 10.1039/B517510K
33. [33]
  GUO Da-lei, ZHENG Jia-jun, YI Yu-ming, ZHANG Qiu, PAN Meng, LI Rui-feng. Synthesis and characterization of FMZ bi-phases composite zeolites[J]. Acta Pet Sin(Pet Process Sect), 2013,29(4):591-596.
34. [34]
  QI X H, WATANABE M, AIDA T M, SMITH R L. Catalytic conversion of cellulose into 5-hydroxymethylfurfural in high yields via a two-step process[J]. Cellulose, 2011,18:1327-1333. doi: 10.1007/s10570-011-9568-1
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