Citation: Cen Shouyi, Zhang Zhipeng. The Differences between Dormant Period and Induction Period in Catalytic Reactions[J]. Chemistry, ;2020, 83(4): 369-376. shu

The Differences between Dormant Period and Induction Period in Catalytic Reactions

Cen Shouyi ,
Zhang Zhipeng ^,

School of Chemistry and Molecular Engineering, East China University of Science&Technology, Shanghai, 200237

Corresponding author: Zhang Zhipeng, zhipengzhang@ecust.edu.cn
Received Date: 26 November 2019
Accepted Date: 15 January 2020

Figures(14)

An initial slow phase which is nominated as induction period usually occurs in many chemical reactions such as some radical reactions, exothermic reactions and catalytic reactions. In contrast, a special phase during which the reaction rate is zero and after which the reaction starts spontaneously, has rarely been observed in a few catalytic reactions. The formation of these two kinds of periods is related to the mechanism of the reaction especially to the catalyst activation or deactivation. However, the two periods have been confused and their obvious distinctions have been neglected in the past. In this perspective, typical kinetic features of induction period and dormant period are demonstrated with selected catalytic reactions, and the differences between them are discussed. In-depth understanding of the pre-catalytic cycle and detailed mechanism of organic reactions are expected if more attentions would be paid to these hidden processes in front of the steady state catalytic cycle.
- Dormant period,
- Induction period,
- Catalysis,
- Catalyst activation,
- Catalyst deactivation
1. [1]
  Richey R S. Grignard Reagents, New York:John Wiley & Sons, 2000:185~275.
2. [2]
  Osborn J A, Wilkinson G. Inorg. Synth., 1967, 10:67~71.
3. [3]
  Halpern J. Inorg. Chim. Acta, 1981, 50:11~19.
4. [4]
  Tornøe C W, Christensen C, Meldal M. J. Org. Chem., 2002, 67:3057~3064.
5. [5]
  Rostovtsev V V, Green L G, Fokin V V, et al. Angew. Chem. Int. Ed., 2002, 41:2596~2599.
6. [6]
  Meldal M, Tornøe C W. Chem. Rev., 2008, 108:2952~3015.
7. [7]
  Hein J E, Fokin V V. Chem. Soc. Rev., 2010, 39:1302~1315.
8. [8]
  Himo F, Lovell T, Hilgraf R, et al., J. Am. Chem. Soc., 2005, 127:210~216.
9. [9]
  Rodionov V O, Fokin V V, Finn M G. Angew. Chem. Int. Ed., 2005, 44:2210~2215.
10. [10]
  Worrell B T, Malik J A, Fokin V V. Science, 2013, 340:457~460.
11. [11]
  McNaught A D, Wilkinson A. IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"), Oxford: Blackwell Scientific Publications, 1997.
12. [12]
  Zhang Z, Bae H Y, Guin J, et al. Nat. Commun., 2016, 7:12478.
13. [13]
  Held I, von den Hoff P, Stephenson D S, et al. Adv. Synth. Catal., 2008, 350:1891~1900.
14. [14]
  Brotherton W S, Michaels H A, Simmons J T, et al. Org. Lett., 2009, 11:4954~4957.
15. [15]
  Kuang G C, Guha P M, Brotherton W S, et al. J. Am. Chem. Soc., 2011, 133:13984~14001.
1. [1]
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