Citation: Qing Lin MENG, Yue Lan LI, Yan HE, Ye Di GUAN. Thiazolidine Derivatives as Chiral Catalysts in the Enantioselective Addition of Diethylzinc to Benzaldehyde[J]. Chinese Chemical Letters, ;2000, 11(9): 761-764. shu

Thiazolidine Derivatives as Chiral Catalysts in the Enantioselective Addition of Diethylzinc to Benzaldehyde

Qing Lin MENG ^a,b ,
Yue Lan LI ^a,b ,
Yan HE ^a,b ,
Ye Di GUAN ^a,b

a Department of Chemistry, Peking University, Beijing 100871;
b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 20 March 2000

Four types of chiral thiazolidine derivatives were synthesized conveniently from natural L-cysteine and showed good enantioselectivity in up to 90% ee in the addition of diethylzinc to benzaldehyde.Their enantioselectivity was affected by the bulkiness of R and the thiazolidine ring systems in their molecules.
- Chiral catalysts,
- enantioselective addition,
- % ee(enantiomeric excess),
- thiazolidine derivatives
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