Citation: ZHENG Li, WU Cang-cang, XU Xiu-feng. Catalytic decomposition of N₂O over Mg-Co and Mg-Mn-Co composite oxides[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(12): 1494-1501. shu

Catalytic decomposition of N₂O over Mg-Co and Mg-Mn-Co composite oxides

School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China

Corresponding author: XU Xiu-feng, xxf@ytu.edu.cn
Received Date: 17 August 2016
Revised Date: 9 October 2016

Figures(14)

Mg-Co and Mg-Mn-Co composite oxides with different compositions were prepared by sol-gel method for N₂O catalytic decomposition in the presence of oxygen. Of Mg-Mn-Co catalysts, the one with higher activity was impregnated by K₂CO₃ solution to make K-modified catalyst. These catalysts were characterized by X-ray diffraction(XRD), nitrogen physisorption (BET), scanning electron microscopy(SEM), temperature-programmed reduction of hydrogen(H₂-TPR), and temperature-programmed desorption of oxygen(O₂-TPD). The effect of preparation parameters such as compositions and potassium loadings on their catalytic activity has been investigated. The results show that K-modified catalysts exhibit better activity and higher resistance towards water in contrast to un-modified catalyst due to the weakness of surface metal-oxygen bonds. Among these catalysts, 0.02K/MgMn_0.2Co_1.8O₄ is the most active, over which 97% and 60% conversions of N₂O can be reached at 400℃ after continuous running for 50 h under the atmosphere of oxygen-alone and oxygen-steam together, respectively. When the steam is switched off, the catalytic activity of 0.02K/MgMn_0.2Co_1.8O₄ can be restored to large extent, indicating the good water-resistance of K-modified catalyst.
- catalytic decomposition of N₂O,
- Mg-Co composite oxides,
- Mg-Mn-Co composite oxides,
- K-modified catalysts,
- catalytic performance
1. [1]
  PIETROGIACOMI D, CAMPA M C, CARBONE L R, TUTI S, OCCHIUZZI M. N₂O decomposition on CoO_x,CuO_x,FeO_x or MnO_x supported on ZrO₂:The effect of zirconia doping with sulfates or K⁺ on catalytic activity[J]. Appl Catal B:Environ, 2016,187:218-227. doi: 10.1016/j.apcatb.2016.01.018
2. [2]
  ASANO K, OHNISHI C, IWAMOTO S, SHIOYA Y, INOUE M. Potassium-doped Co₃O₄ catalyst for direct decomposition of N₂O[J]. Appl Catal B:Environ, 2008,78(3/4):242-249.
3. [3]
  XUE L, ZHANG C B, HE H, TERAOKA Y. Promotion effect of residual K on the decomposition of N₂O over cobalt-cerium mixed oxide catalyst[J]. Catal Today, 2007,126(3/4):449-455.
4. [4]
  HUSSAIN M, FINO D, RUSSO N. N₂O decomposition by mesoporous silica supported Rh catalysts[J]. J Hazard Mater, 2012,211-212:255-265. doi: 10.1016/j.jhazmat.2011.08.024
5. [5]
  KLYUSHINA, PACULTOVÁK, KREJČOVÁS, SLOWIK, JIRÁTOVÁK, KOVANDA, RYCZKOWSKI, OBALOVÁL. Advantages of stainless steel sieves as support for catalytic N₂O decomposition over K-doped Co₃O₄[J]. Catal Today, 2015,257(1):2-10.
6. [6]
  ZABILSKIY M, DJINOVĆ P, ERJAVEC B, DRAŽĆG , PINTAR A. Small CuO clusters on CeO₂ nanospheres as active species for catalytic N₂O decomposition[J]. Appl Catal B:Environ, 2015,163:113-122. doi: 10.1016/j.apcatb.2014.07.057
7. [7]
  AMROUSSE R, KATSUMI T. Substituted ferrite M_xFe_1-xFe₂O₄(M=Mn,Zn) catalysts for N₂O catalytic decomposition processes[J]. Catal Commun, 2012,26:194-198. doi: 10.1016/j.catcom.2012.05.024
8. [8]
  KUMAR S, VINU A, SUBBRT J, BAKARDJIEVA S, RAYALU S, TERAOKA Y, LABHSETWAR N. Catalytic N₂O decomposition on Pr_0.8Ba_0.2MnO₃ type perovskite catalyst for industrial emission control[J]. Catal Today, 2012,198(1):125-132. doi: 10.1016/j.cattod.2012.06.015
9. [9]
  XUE Z W, SHEN Y S, SHEN S B, LI C L, ZHU S M. Promotional effects of Ce⁴⁺,La³⁺ and Nd³⁺ incorporations on catalytic performance of Cu-Fe-O_x for decomposition of N₂O[J]. J Ind Eng Chem, 2015,30:98-105. doi: 10.1016/j.jiec.2015.05.008
10. [10]
  LIN Y, MENG T, MA Z. Catalytic decomposition of N₂O over RhO_x supported on metal phosphates[J]. J Ind Eng Chem, 2015,28:138-146. doi: 10.1016/j.jiec.2015.02.009
11. [11]
  DACQUIN J P, DUJARDIN C, GRANGER P. Surface reconstruction of supported Pd on LaCoO₃:Consequences on the catalytic properties in the decomposition of N₂O[J]. J Catal, 2008,253(1):37-49. doi: 10.1016/j.jcat.2007.10.023
12. [12]
  BEYER H, EMMERICH J, CHATZIAPOSTOLOU K, KÖHLER K. Decomposition of nitrous oxide by rhodium catalysts:Effect of rhodium particle size and metal oxide support[J]. Appl Catal A:Gen, 2011,391(1/2):411-416.
13. [13]
  PACHATOURIDOU E, PAPISTA E, DELIMITIS A, VASILIADES M A, EFSTATHIOU A M, AMIRIDIS M D, ALEXEEV O S, BLOOM D, MAMELLOS G E, KONSOLAKIS M, ILIOPOULOU E. N₂O decomposition over ceria-promoted Ir/Al₂O₃ catalysts:The role of ceria[J]. Appl Catal B:Environ, 2016,187:259-268. doi: 10.1016/j.apcatb.2016.01.049
14. [14]
  BERRIER E, OVSITSER O, KONDRATENKO E V, SCHWIDDER M, GRÜNERT W, BRÜCKNER A. Temperature-dependent N₂O decomposition over Fe-ZSM-5:Identification of sites with different activity[J]. J Catal, 2007,249(1):67-78. doi: 10.1016/j.jcat.2007.03.027
15. [15]
  CÜRDANELI P E, ÖZKAR S. Ruthenium (Ⅲ) ion-exchanged zeolite Y as highly active and reusable catalyst in decomposition of nitrous oxide to sole nitrogen and oxygen[J]. Microporous Mesoporous Mater, 2014,196:51-58. doi: 10.1016/j.micromeso.2014.04.052
16. [16]
  MENG T, REN N, MA Z. Silicalite-1@Cu-ZSM-5 core-shell catalyst for N₂O decomposition[J]. J Mol Catal A:Chem, 2015,404-405:233-239. doi: 10.1016/j.molcata.2015.05.006
17. [17]
  YAN L, REN T, WANG X L, GAO Q, JI D, SUO J S. Excellent catalytic performance of Zn_xCo_1-xCo₂O₄ spinel catalysts for the decomposition of nitrous oxide[J]. Catal Commun, 2003,4(10):505-509. doi: 10.1016/S1566-7367(03)00131-6
18. [18]
  YAN L, REN T, WANG X L, JI D, SUO J S. Catalytic decomposition of N₂O over M_xCo_1-xCo₂O₄(M=Ni,Mg) spinel oxides[J]. Appl Catal B:Environ, 2003,45(2):85-90. doi: 10.1016/S0926-3373(03)00174-7
19. [19]
  ABU-ZIED B M, SOLIMAN S A, ABDELLAH S E. Pure and Ni-substituted Co₃O₄ spinel catalysts for direct N₂O decomposition[J]. Chin J Catal, 2014,35(7):1105-1112. doi: 10.1016/S1872-2067(14)60058-9
20. [20]
  MANIAK G, STELMACHOWSKI P, STANEK J J, KOTARBA A, SOJKA Z. Catalytic properties in N₂O decomposition of mixed cobalt-iron spinels[J]. Catal Commun, 2011,15(1):127-131. doi: 10.1016/j.catcom.2011.08.027
21. [21]
  DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. J Fuel Chem Technol, 2014,42(2):238-245. doi: 10.1016/S1872-5813(14)60016-5
22. [22]
  WANG Jian, DOU Zhe, PAN Yan-fei, XU Xiu-feng. Mn_xCo_3-xO₄ composite oxide and modified catalyst catalytic decomposition of N₂O[J]. J Mol Catal (China), 2015,29(3):246-255.
23. [23]
  CHELLAM U, XU Z P, ZENG H C. Low-temperature synthesis of Mg_xCo_1-xCo₂O₄ spinel catalysts for N₂O decomposition[J]. Chem Mater, 2000,12:650-658. doi: 10.1021/cm990355l
24. [24]
  KUBOŇOVÁL , FRIDRICHOVÁD , WACH A, KUŚTROWSKR P, OBALOVÁL , COOL P. Catalytic activity of rhodium grafted on ordered mesoporous silicamaterials modified with aluminum in N₂O decomposition[J]. Catal Today, 2015,257:51-58. doi: 10.1016/j.cattod.2015.03.019
25. [25]
  PRRUTKO L V, CHERNYAVSKY V S, STAROKON E V, IVANOV A A, KHARITONOV A S, PANOV G. The role of a-sites in N₂O decomposition over FeZSM-5.Comparison with the oxidation of benzene to phenol[J]. Appl Catal B:Environ, 2009,91(1/2):174-179.
26. [26]
  WU Cang-cang, ZHANG Hai-jie, WANG Jian, ZHENG Li, XU Xiu-feng. The preparation parameters screening of Co-Al spinel oxides for N₂O catalytic decomposition[J]. J Mol Catal (China), 2016,30(1):62-71.
27. [27]
  AMROUSSE R, TSUTSUMI A, BACHAR A, LAHCENE D. N₂O catalytic decomposition over nano-sized particles of Co-substituted Fe₃O₄ substrates[J]. Appl Catal A:Gen, 2013,450:253-260. doi: 10.1016/j.apcata.2012.10.036
28. [28]
  FRANKEN T, PALKOVITS R. Investigation of potassium doped mixed spinels Cu_xCo_3-xO₄ as catalysts for an efficient N₂O decomposition in real reaction conditions[J]. Appl Catal B:Environ, 2015,176-177:298-305. doi: 10.1016/j.apcatb.2015.04.002
1. [1]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
2. [2]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
3. [3]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
4. [4]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
9. [9]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
12. [12]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
15. [15]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
16. [16]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
17. [17]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
20. [20]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(889)
HTML views(202)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic decomposition of N2O over Mg-Co and Mg-Mn-Co composite oxides

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic decomposition of N₂O over Mg-Co and Mg-Mn-Co composite oxides