Citation: Jin Shan LI, Jing, Kun ZANG. Synthesis and Moessbauer Spectra of Four-Coordinated TinCompounds Containing Tin-Copper Bonds[J]. Chinese Chemical Letters, ;1998, 9(5): 491-494. shu

Synthesis and Moessbauer Spectra of Four-Coordinated TinCompounds Containing Tin-Copper Bonds

1.
Institute of Elemento-Organic Chemistry, Nankai University, Tianin 300071;
2.
Central Laboratory, Nankai University, Tanjin 300071

Received Date: 24 November 1997

Seven compounds containing tin-copper bonds, namely [Ph₂P(CH₂)_nPPh₂](CuSnPh₃)₂(n=1-4) and (Ph₂PR)CuSnPh₃ (R=Ph, Bu, Am), have been synthesized. Tin-119 Moessbauer spectra for these compounds were determined. The results have shown that the QS values for these compounds are all zero, the IS values are between 1.32 and 1.38mm/s, and the oxidation state of tin is +4.
- Moessbauer spectrum,
- oxidation state,
- electron density
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