Citation: WANG Hai-yan, GUAN Zong-chi, KANG Lei, HAO Ming-yang. Study on adsorption desulfurization performance of porous microsphere nickel zinc composite adsorbent[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(10): 1236-1243. shu

Study on adsorption desulfurization performance of porous microsphere nickel zinc composite adsorbent

Liaoning Shihua University, Fushun 113001, China

Corresponding author: WANG Hai-yan, fswhy@126.com
Received Date: 10 May 2017
Revised Date: 3 August 2017

Figures(8)

The effects of glucose on the morphology of the microspheres of zinc oxide were first studied, and then 5% NiO/ZnO microspheric adsorbents were prepared by impregnation method and hydrothermal synthesis. The morphology and structure of NiO/ZnO microspheres were analyzed by N₂ adsorption, scanning electron microscopy (SEM), X-ray diffraction (XRD) methods, and the effects of the preparation method of NiO/ZnO microspheric adsorbents on the physicochemical properties were examined. Furthermore, Ni/ZnO microsphere adsorbent was prepared by reduction with H₂, over which the performance of adsorption desulfurization was tested in a fixed bed reactor by using thiophene as the sulfur compounds in model gasoline.The results show that the specific surface area and pore volume of the NiO-ZnO microspheric adsorbents prepared by hydrothermal method are as high as 40.45 m²/g and 0.096 cm³/g, respectively, in contrast to the ones prepared by the impregnation method, and the composite Ni-ZnO microspheric adsorbents exhibit a favorable desulfurization activity. Under the conditions including a temperature of 350℃, a pressure of 1.0 MPa, a volume space velocity of 6 h^-1, and a hydrogen to simulated oil volume ratio of 60, the sulphur contents in simulated oil decrease from 1.5×10^-4 to less than 10^-5. Also, the adsorbents boast a good regeneration capacity and a potential application value in industry.
- composites,
- microsphere,
- adsorbent,
- adsorption desulfurization,
- zincoxide,
- mesoporous structure
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