Citation: LIU Chun-ya, YANG Hao, JING Zhong-yu, XI Ke-zhong, QIAO Cong-zhen. Hydrodeoxygenation of fatty acid methyl esters and isomerization of products over NiP/SAPO-11 catalysts[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(10): 1211-1216. shu

Hydrodeoxygenation of fatty acid methyl esters and isomerization of products over NiP/SAPO-11 catalysts

1.
College of Chemistry and Chemical Engineering, Henan Engineering Research Center of Resource & Energy Recovery from Waste, Henan University, Kaifeng 475004, China
2.
Zhengzhou United Elites Bioenergy Co. Ltd., Zhengzhou 450001, China

Corresponding author: QIAO Cong-zhen, qiaocongzhen@163.com
Received Date: 12 July 2016
Revised Date: 22 August 2016

Figures(7)

NiP/SAPO-11 catalysts with various nickle loading amounts were prepared by the impregnation method, and their properties were determined by means of N₂ adsorption-desorption, DRIFTS of adsorbed pyridine, NH₃-TPD and H₂-TPR. The catalytic hydrodeoxygenation of fatty acid methyl esters (FAME) and isomerization of consecutive paraffin products were carried out in a fixed-bed continuous-flow reactor. Liquid products were qualitatively and quantitatively identified by GC-MS and GC respectively. Under the operation conditions of 340℃, 2.0 MPa, WHSV of 2.5 h^-1, H₂ of 60 mL/min, the catalyst with 3% nickel loading (mass content) attained the high conversion of FAME (97.8%), C_15-18 yield (84.5%) and isomerization rate (14.0%).
- FAME,
- NiP/SAPO-11,
- hydrodeoxygenation,
- isomerization
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沈阳化工大学材料科学与工程学院沈阳 110142