Citation: Fadhil Mustafa H., Ammar Saad H., Abdul Jabbar Marwa F.. Microwave-assisted catalytic oxidative desulfurization of gasoil fuel using synthesized CuO-ZnO nanocomposites[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(9): 1075-1082. shu

Microwave-assisted catalytic oxidative desulfurization of gasoil fuel using synthesized CuO-ZnO nanocomposites

Chemical Engineering Department, Al-Nahrain University, Baghdad, Iraq

Corresponding author: Ammar Saad H., drsaadchemwork@eng.nahrainuniv.edu.iq
Received Date: 21 May 2019
Revised Date: 20 July 2019

Figures(8)

Recently, organosulfur removal from liquid petroleum fuels is very significant aspect of environment protecting and fuel cell requests. Therefore, improved approaches to remove sulfur are still essential. In the present work, a simple catalytic oxidative desulfurization (CODS) system for Iraqi gasoil fraction has been successfully developed using CuO-ZnO nanocomposites as catalysts, and H₂O₂ as oxidant under microwave irradiation. The main reaction parameters influencing sulfur conversion including microwave power, irradiation time, catalyst dosage and H₂O₂ to gasoil volume ratio have been investigated. The CuO-ZnO nanocomposites was synthesized with different weight ratios and characterized by XRD, FE-SEM, AFM and BET surface area methods. The results reveal that, high sulfur conversion (93%) has been achieved under suitable conditions of microwave CODS as follows:microwave power of 540 W, irradiation time of 15 min, catalyst dosage of 8 g/L (0.4 g), and H₂O₂:gasoil volume ratio of 0.3. The catalyst reusability shows that the synthesized catalyst can be reused five times without an important loss in its activity.
- microwave,
- oxidative desulfurization,
- nanocomposites,
- catalyst,
- gasoil
1. [1]
  ZHU W, LI H, JIANG X, YAN Y, LU J, HE L, XIA J. Commercially available molybdic compound-catalyzed ultra-deep desulfurization of fuels in ionic liquids[J]. Green Chem, 2008,10(6):641-646. doi: 10.1039/b801185k
2. [2]
  CHEN X, SONG D, ASUMANA C, YU G. Deep oxidative desulfurization of diesel fuels by Lewis acidic ionic liquids based on 1-n-butyl-3-methylimidazolium metal chloride[J]. J Mol Catal A:Chem, 2012,359:8-13. doi: 10.1016/j.molcata.2012.03.014
3. [3]
  SEEBERGER A, JESS A. Desulfurization of diesel oil by selective oxidation and extraction of sulfur compounds by ionic liquids-a contribution to a competitive process design[J]. Green Chem, 2010,12:602-608. doi: 10.1039/b918724c
4. [4]
  EβER J, WASSERSCHEID P, JESS A. Deep desulfurization of oil by extraction with ionic liquids[J]. Green Chem, 2004,6:316-322. doi: 10.1039/B407028C
5. [5]
  AGARWAL P, SHARMA D K. Comparative studies on the bio-desulfurization of crude oil with other desulfurization techniques and deep desulfurization through integrated processes[J]. Energy Fuels, 2010,24(1):518-524. doi: 10.1021/ef900876j
6. [6]
  LIU S, WANG B, CUI B, SUN L. Deep desulfurization of diesel oil oxidized by Fe (Ⅵ) systems[J]. Fuel, 2008,87(3):422-428.
7. [7]
  ZHANG J, WANG A, LI X, MA X. Oxidative desulfurization of dibenzothiophene and diesel over[Bmim]₃PMo₁₂O₄₀[J]. J Catal, 2011,279(2):269-275.
8. [8]
  SUN B, YU X, WANG L, FENG L J, LI C H. Enhanced visible light photocatalytic oxidative desulfurization by BiOBr-graphene composite[J]. J Fuel Chem Technol, 2016,44(9):1074-1081. doi: 10.1016/S1872-5813(16)30049-4
9. [9]
  ZENG A X, XIAO X, LI Y, CHEN J, WANG H. Deep desulfurization of liquid fuels with molecular oxygen through graphene photocatalytic oxidation[J]. Appl Catal B:Environ, 2017,209:98-109. doi: 10.1016/j.apcatb.2017.02.077
10. [10]
  CHICA A, CORMA A, DÓMINE M E. Catalytic oxidative desulfurization (ODS) of diesel fuel on a continuous fixed-bed reactor[J]. J Catal, 2006,242(2):299-308.
11. [11]
  GAO Y, GAO R, ZHANG G, ZHENG Y, ZHAO J. Oxidative desulfurization of model fuel in the presence of molecular oxygen over polyoxometalate based catalysts supported on carbon nanotubes[J]. Fuel, 2018,224:261-270. doi: 10.1016/j.fuel.2018.03.034
12. [12]
  SARAVANAN R, KARTHIKEYAN S, GUPTA V K, SEKARAN G, NARAYANAN V, STEPHEN A. Enhanced photocatalytic activity of ZnO/CuO nanocomposite for the degradation of textile dye on visible light illumination[J]. Mater Sci Eng C, 2013,33(1):91-98.
13. [13]
  ZHU L, LI H, LIU Z, XIA P, XIE Y, XIONG D. Synthesis of 0D/3D CuO/ZnO heterojunction with enhanced photocatalytic activity synthesis of 0D/3D CuO/ZnO heterojunction with enhanced photocatalytic activity[J]. J Phys Chem, 2018,122(17):9513-9539.
14. [14]
  CHEN C, LIU P, LU C. Synthesis and characterization of nano-sized ZnO powders by direct precipitation method[J]. Chem Eng J, 2008,144(3):509-513.
15. [15]
  PHIWDANG K, SUPHANKIJ S, MEKPRASART W. Synthesis of CuO nanoparticles by precipitation method using different precursors[J]. Energy Procedia, 2013,34:740-745. doi: 10.1016/j.egypro.2013.06.808
16. [16]
  LI B, WANG Y. Superlattices and microstructures facile synthesis and photocatalytic activity of ZnO-CuO nanocomposite[J]. Superlattices Microstruct, 2010,47(5):615-623. doi: 10.1016/j.spmi.2010.02.005
17. [17]
  KHAN M F, ANSARI A H, HAMMEEDULLAH M, AHMAD E, HUSAIN F M, ZIA Q, BAIG U, ZAHEER M R, ALAM M M, KHAN A H, ALOTHMAN Z A, AHMAD I, ASHRAF G N, ALIEV G. Sol-gel synthesis of thorn-like ZnO nanoparticles endorsing mechanical stirring effect and their antimicrobial activities:Potential role as nano-antibiotics[J]. Sci Rep, 2016,27689.
18. [18]
  KUMARI R, SAHAI A, GOSWAMI N. Effect of nitrogen doping on structural and optical properties of ZnO nanoparticles[J]. Prog Nat Sci Mater Int, 2015,25(4):300-309. doi: 10.1016/j.pnsc.2015.08.003
19. [19]
  MOEZZI A, MCDONAGH A M, CORTIE M B. Zinc oxide particles:Synthesis, properties and applications[J]. Chem Eng J, 2012,185.
20. [20]
  SATHISHKUMAR P, SWEENA R, WU J J, ANANDAN S. Synthesis of CuO-ZnO nanophotocatalyst for visible light assisted degradation of a textile dye in aqueous solution[J]. Chem Eng J, 2011,171(1):136-140.
21. [21]
  MUTYALA S, FAIRBRIDGE C, PARÉ J R J, BÉLANGER J M R, NG S, HAWKINS R. Microwave applications to oil sands and petroleum:A review[J]. Fuel Process Technol, 2010,91(2):127-135. doi: 10.1016/j.fuproc.2009.09.009
22. [22]
  MIADONYE A, SNOW S, IRWIN D J G, KHAN M R, BRITTEN A J. Desulfurization of heavy crude oil by microwave irradiation[J]. 2009, 63: 455-465.
23. [23]
  MESDOUR S, LEKBIR C, DOUMANDJI L, HAMADA B. Microwave-assisted extractive catalytic-oxidative desulfurization of diesel fuel via a VO (acac)₂/ionic liquid system with H₂O₂ and H₂SO₄ as oxidizing agents[J]. J Sulfur Chem, 2017,38(4):421-439. doi: 10.1080/17415993.2017.1304550
24. [24]
  SHANG H, ZHANG H, DU W, LIU Z. Development of microwave assisted oxidative desulfurization of petroleum oils:A review[J]. J Ind Eng Chem, 2013,19(5):1426-1432. doi: 10.1016/j.jiec.2013.01.015
1. [1]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Qijun Tang , Wenguang Tu , Yong Zhou , Zhigang Zou . High efficiency and selectivity catalyst for photocatalytic oxidative coupling of methane. Chinese Journal of Structural Chemistry, 2023, 42(12): 100170-100170. doi: 10.1016/j.cjsc.2023.100170
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
6. [6]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
7. [7]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
8. [8]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
9. [9]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
10. [10]
  Hongwei Ding , Jingjing Yang , Yongchen Shuai , Di Wei , Xueliang Liu , Guiying Li , Lin Jin , Jianliang Shen . In situ preparation of tannin-mediated CeO₂@CuS nanocomposites for multimodal wound therapy. Chinese Chemical Letters, 2025, 36(6): 110286-. doi: 10.1016/j.cclet.2024.110286
11. [11]
  Hong Yin , Zhipeng Yu . Hexavalent iridium catalyst enhances efficiency of hydrogen production. Chinese Journal of Structural Chemistry, 2025, 44(1): 100382-100382. doi: 10.1016/j.cjsc.2024.100382
12. [12]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
13. [13]
  Jian Wang , Baohui Wang , Pin Ma , Yifei Zhang , Honghong Gong , Biyun Peng , Sen Liang , Yunchuan Xie , Hailong Wang . Regulation of uniformity and electric field distribution achieved highly energy storage performance in PVDF-based nanocomposites via continuous gradient structure. Chinese Chemical Letters, 2025, 36(4): 109714-. doi: 10.1016/j.cclet.2024.109714
14. [14]
  Zimo Peng , Quan Zhang , Gaocan Qi , Hao Zhang , Qian Liu , Guangzhi Hu , Jun Luo , Xijun Liu . Nanostructured Pt@RuOx catalyst for boosting overall acidic seawater splitting. Chinese Journal of Structural Chemistry, 2024, 43(1): 100191-100191. doi: 10.1016/j.cjsc.2023.100191
15. [15]
  Yizhe Chen , Yuzhou Jiao , Liangyu Sun , Cheng Yuan , Qian Shen , Peng Li , Shiming Zhang , Jiujun Zhang . Nonmetallic phosphorus alloying to regulate the oxygen reduction mechanisms of platinum catalyst. Chinese Chemical Letters, 2025, 36(4): 110789-. doi: 10.1016/j.cclet.2024.110789
16. [16]
  Shuang Li , Jiayu Sun , Guocheng Liu , Shuo Zhang , Zhong Zhang , Xiuli Wang . A new Keggin-type polyoxometallate-based bifunctional catalyst for trace detection and pH-universal photodegradation of phenol. Chinese Chemical Letters, 2024, 35(8): 109148-. doi: 10.1016/j.cclet.2023.109148
17. [17]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
18. [18]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
19. [19]
  Yanling Yang , Zhenfa Ding , Huimin Wang , Jianhui Li , Yanping Zheng , Hongquan Guo , Li Zhang , Bing Yang , Qingqing Gu , Haifeng Xiong , Yifei Sun . Dynamic tracking of exsolved PdPt alloy/perovskite catalyst for efficient lean methane oxidation. Chinese Chemical Letters, 2024, 35(4): 108585-. doi: 10.1016/j.cclet.2023.108585
20. [20]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(636)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142