Citation: HUO Hai-hui, GAO Wen-gui, MAO Wen-shuo, NA Wei, YAN Xiao-feng, YE Hai-chuan. Effect of composition of Cu-ZnO-CeO₂ catalyst on its performance for methanol synthesis from CO₂ hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(5): 523-531. shu

Effect of composition of Cu-ZnO-CeO₂ catalyst on its performance for methanol synthesis from CO₂ hydrogenation

HUO Hai-hui ¹ ,
GAO Wen-gui ^1,2,, ,
MAO Wen-shuo ^1,3 ,
NA Wei ^1,2 ,
YAN Xiao-feng ^1,2 ,
YE Hai-chuan ^1,2

1.
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
2.
Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
3.
Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650093, China

Corresponding author: GAO Wen-gui, gao_wengui@126.com
Received Date: 11 December 2018
Revised Date: 26 February 2019

Fund Project: the National Natural Science Foundation of China 51304099The project was supported by the National Natural Science Foundation of China (51304099) and the National Key Technologies R & D Program of China (2011BAC01B03)the National Key Technologies R & D Program of China 2011BAC01B03

Figures(8)

Three catalysts, CuO-CeO₂ (5:1 molar ratio), CuO-ZnO (5:4 molar ratio) and CuO-ZnO-CeO₂ (5:4:1 molar ratio), were prepared by coprecipitation method.The physicochemical properties of the catalysts were characterized by X-ray diffraction (XRD), hydrogen temperature reduction (H₂-TPR), CO₂ temperature programmed desorption (CO₂-TPD), nitrogen adsorption desorption, X-ray photoelectron spectroscopy (XPS), N₂O titration.The activity of the catalyst was evaluated in a catalytic microreactor.The results show that, the physicochemical properties and catalytic activity of the ternary CuO-ZnO-CeO₂ catalyst are different from that of the binary catalyst, specifically, the strength of surface alkaline sites are increased, the thermal stability is enhanced, the particle size of CuO particles is reduced, the dispersion of copper and the concentration of oxygen vacancies are increased, and the catalytic activity is finally improved. In the CuO-ZnO-CeO₂ catalyst, the CuO particle size is 8.2nm, the specific surface area of copper is 68.4m²/g, the copper dispersion is 7.19%, the selectivity and the yield of methanol are 48.6% and 0.057mmol/(g·min), respectively.
- CO₂ hydrogenation,
- CuO-ZnO-CeO₂,
- catalyst,
- methanol
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Effect of composition of Cu-ZnO-CeO2 catalyst on its performance for methanol synthesis from CO2 hydrogenation

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Effect of composition of Cu-ZnO-CeO₂ catalyst on its performance for methanol synthesis from CO₂ hydrogenation