Citation: Huiquan Yang, Fan Yang, Mingyang Wei, Lichun Liu, Liqiu Zhang. Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode[J]. Chemistry, ;2021, 84(2): 172-177. shu

Atomic Platinum Cluster Electrodeposition on Micro-Nano-Scale Carbon Electrode

College of Biological and Chemical Science and Engineering, Jiaxing University, Jiaxing, 314001

Corresponding author: Liqiu Zhang, liqiu0524@zjxu.edu.cn
Received Date: 18 August 2020
Accepted Date: 2 September 2020

Figures(4)

In this work, micro-nano-scale carbon electrodes were successfully prepared by flame etching and glass capillary tubes encapsulation. Pt clusters of different sizes, such as single atom, 3 atoms, 5 atoms, were obtained on as-prepared carbon electrodes by electrochemical deposition through regulating the parameters, such as electrolyte concentration, deposition strategy and deposition time. The size of Pt clusters was calculated using limiting current of the catalytic hydrogen reduction on as-prepared electrodes in an acidic solution. Meanwhile, the hydrogen evolution characteristics of Pt clusters were compared using linear scanning voltammetry, and the stability of Pt single atom was evaluated by consulting cyclic voltammetry. This study can provide an important reference for the study of the electrodeposition and properties of single-atom and few-atom metal clusters.
- Carbon electrode,
- Catalyst,
- Single atom,
- Pt,
- Electrochemical deposition
1. [1]
  Zhang L, Doyle-Davis K, Sun X. Energy Environ. Sci., 2019, 12(2): 492~517.
2. [2]
  Martins M, Mourato C, Sanches S, et al. Water Res., 2017, 108: 160~168.
3. [3]
  Zhao X, Chen S, Fang Z, et al. J. Am. Chem. Soc., 2015, 137(8): 2804~2807.
4. [4]
  Zhang L, Yu S, Zhang J, et al. Chem. Sci., 2016, 7(6): 3500~3505.
5. [5]
  Zhou Z, Tian N, Li J, et al. Chem. Soc. Rev., 2011, 40(7): 4167~4185.
6. [6]
  Luo Z, Tan C, Lai Z, et al. Sci. Chin. Mater., 2018, 62(1): 115~121.
7. [7]
  Zhang Z, Liu G, Cui X, et al. Adv. Mater., 2018, 30(30): e1801741.
8. [8]
  Han B, Carlton C, Kongkanand A, et al. Energy Environ. Sci., 2015, 8(1): 258~266.
9. [9]
  Tian N, Zhou Z Y, Sun S, et al. Science, 2007, 316: 732~735.
10. [10]
  Qiao B, Wang A, Yang X, et al. Nat. Chem., 2011, 3(8): 634~641.
11. [11]
12. [12]
13. [13]
  Kistler J, Chotigkrai N, Xu P, et al. Angew. Chem. Int. Ed., 2014, 53(34): 8904~8907.
14. [14]
  Xing J, Chen J, Li Y, et al. Chem. Eur. J., 2014, 20(8): 2088~2088.
15. [15]
  Wei S, Li A, Liu J, et al. Nat. Nanotech., 2018, 13(9): 856~861.
16. [16]
  Zhou M, Dick J, Bard A. J. Am. Chem. Soc., 2017, 139(48): 17677~17682.
17. [17]
  Zhou M, Bao S, Bard A. J. Am. Chem. Soc., 2019, 141(18): 7327~7332.
18. [18]
  Ma W, Hu K, Chen Q, et al. Nano Lett., 2017, 17(7): 4354~4358.
1. [1]
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2. [2]
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3. [3]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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