Citation: SHI Min, FAN Ming-ming, ZHANG Ping-bo, JIANG Ping-ping. Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(8): 921-927. shu

Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel

School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China

Corresponding author: ZHANG Ping-bo, pingbozhang@126.com
Received Date: 24 March 2016
Revised Date: 6 May 2016

Figures(10)

The CaO@SiO₂ alkaline catalyst was prepared by sol-gel method that chooses polystyrene as hard template and P123 as soft template to control the microstructure. Furthermore, the prepared catalyst was applied to the transesterification of soybean and methanol. Also, the nano-solid based catalyst was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), CO₂-TPD and N₂ absorption-desorption (BET). The results show that the catalyst possesses an ordered morphology and core-shell structure. In addition, the effect of the ratio of SiO₂/CaO (mass ratio), reaction temperatures, catalyst dosages and the ratio of oil/methanol (mol ratio) on the yield of biodiesel was examined. Under the best reaction condition, the yield of biodiesel can reach 95.6%.
- CaO,
- transesterification,
- biodiesel,
- nano-catalyst
1. [1]
  LI H, XIA S Q, LUO H J, MA P S. Experimental and computational study on the compatibility of biodiesel/diesel/methanol blended fuel[J]. Fuel, 2016,173:52-59. doi: 10.1016/j.fuel.2016.01.036
2. [2]
  TANMAY B, MANAS K K, SUDIP B. Palladium nanoparticle-graphitic carbon nitride porous synergistic catalyst for hydrogen evolution/oxidation reactions over a broad range of pH and correlation of its catalytic activity with measured hydrogen binding energy[J]. ACS Catal, 2016,6(3):1929-1941. doi: 10.1021/acscatal.5b02485
3. [3]
  ABDERRAHIM B, RODRIGO V, MERCEDES M, JOSE A. Effect of free fatty acids contents on biodiesel quality.Pilot plant studies[J]. Fuel, 2016,174:54-62. doi: 10.1016/j.fuel.2016.01.018
4. [4]
  AHMAD M, ASADOLAH A, SHAHIN R, ELNAZ B K. Energy and cost analyses of biodiesel production from waste cooking oil[J]. Renewable Sustainable Energy Rev, 2014,33:44-49. doi: 10.1016/j.rser.2014.01.067
5. [5]
  LI Xiao-hong, JIN Fu-quan. Preparation of CaO/(Mg-Fe-O) solid base and its catalytic activity in transesterification[J]. China Oils Fats, 2015,40(7):55-59.
6. [6]
  ZHANG Chuan-feng, ZHAO Jing, FANG Wen-jun, GUO Yong-sheng. Application of nanocatalyst in the fields of hydrocarbon fuel and biodiesel[J]. Acta Pet Sin, 2015,31(2):418-425.
7. [7]
  NAVOT K, AMJAD A. Biodiesel production via ethanolysis of jatropha oil using molybdenum impregnated calcium oxide as solid catalyst[J]. RSC Adv, 2015,5(18):13285-13295. doi: 10.1039/C4RA14786C
8. [8]
  ZHENG Hua-yan, LI Xi-qian, CUI Li-ping, LI Zhong. Synthesis of biodiesel from rapeseed oil catalyzed by Ca/Al solid base[J]. J Fuel Chem Technol, 2012,40(3):331-336.
9. [9]
  JOSHI G, RAWAT D S, LAMBA B Y, BISHT K K, KUMAR P, KUMAR N, KUMAR S. Transesterification of Jatropha and Karanja oils by using waste egg shell derived calcium based mixed metal oxides[J]. Energy Convers Manage, 2015,96:258-267. doi: 10.1016/j.enconman.2015.02.061
10. [10]
  SIOW H T, AMINUL I, TALAL Y, YUN H T. Transesterification of nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst[J]. Energy, 2014,78:63-71. doi: 10.1016/j.energy.2014.07.045
11. [11]
  NEZAHAT B, NEBAHAT D, DIHAN M K. Transesterification of canola oil to biodiesel using calcium bentonite functionalized with K compounds[J]. Appl Catal B:Environ, 2013,138-139:236-242. doi: 10.1016/j.apcatb.2013.02.043
12. [12]
  SUN Yan-rong, FAN Tao, LIU Feng, MA Li-guo, WANG Chang-an. influence of templates on morphology of nano-hydroxyapatite synthesized by Co-precipitation method[J]. J Chin Ceram Soc, 2012,40(1):90-94.
13. [13]
  SHEN Shao-chun, YUAN Zhi-qing, YANG Wei-min, LI Ying-cheng. Preparation of nano-sized ZSM-5 zeolite based on the novel template gemini quaternary ammonium hydroxide[J]. Ind Catal, 2015,23(10):763-766.
14. [14]
  WANG Ya-yun, CHEN Yang, ZHAN Xiao-bing, QIN Jia-wei. Effects of the polishing pressure on the polishing performance of nano-sized PS/CeO₂ composite abrasives[J]. Micronanoelectron Technol, 2015,52(2):129-134.
15. [15]
  RASHAD M M, IBRAHIM I A. Improvement of the magnetic properties of barium hexaferrite nanopowders using modified co-precipitation method[J]. J Mang Magn Mater, 2011,323(16):2158-2164. doi: 10.1016/j.jmmm.2011.03.023
16. [16]
  OU Yang-mi, HUANG Sen-biao, HAN Yan-gang, LV Xiao-jing, YANG yuan, DAI Yu-yu, LU Yao-kang, ZHANG Cheng. Enhanced electrochromic performance of ordered porous monolayer PBTB film using amine-modified polystyrene spheres as a template[J]. Acta Phys-Chim Sin, 2015,31(3):476-482.
17. [17]
  XIE W L, YANG X L, FAN M L. Novel solid base catalyst for biodiesel production:Mesoporous SBA-15 silica immobilized with 1, 3-dicyclohexyl-2-octylguanidine[J]. Renewable Energy, 2015,80:230-237. doi: 10.1016/j.renene.2015.02.014
18. [18]
  HOU Qian-fen, ZHANG Qian-qian, GUO Hua-rong, LI Ling. Synthesis and characterization of Ca/SBA-15 solid base catalyst and its application in biodiesel production via waste cooking oil[J]. Chem Bioeng, 2015,32(8):28-34.
19. [19]
  HOU Li-wei, YI Yu-feng, DING Fu-chen. Study on affecting factors of determining glycerol content with periodic acid oxidation[J]. Cereal Oil, 2010(1):36-40.
20. [20]
  GUO Ping-mei, HUANG Qing. Study on analytical method of free glycerin and total glycerin in biodiesel[J]. Cereal Oil, 2003(8):41-42.
21. [21]
  PUNNAMA S, SHIGEO H, ATSUO Y, KYIOSHI O. Preparation and sintering of CaSiO₃ from coprecipitated powder using NaOH as precipitant and its apatite formation in simulated body fluid solution[J]. J Mater Res, 1999,14(2):529-536. doi: 10.1557/JMR.1999.0076
22. [22]
  JIANG W, NIU X Y, YUAN F L, ZHU Y J, FU H G. Preparation of KF-La₂O₂CO₃ solid base catalysts and their excellent catalytic activities for transesterification of tributyrin with methanol[J]. Catal Sci Technol, 2014,4:2957-2968. doi: 10.1039/C4CY00167B
23. [23]
  FAN Ming-ming, LIU Yan-lei, ZHANG Ping-bo, JIANG Ping-ping. Preparation of magnetic core-shell CaO-MgO@CoFe₂O₄ solid base and its catalytic performance in the transesterification of soybean oil to biodiesel[J]. J Fuel Chem Technol, 2016,44(4):422-427.
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Preparation of nano-solid based catalyst CaO@SiO2 for the transesterification of soybean oil to biodiesel

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通讯作者: 陈斌, bchen63@163.com

Preparation of nano-solid based catalyst CaO@SiO₂ for the transesterification of soybean oil to biodiesel