Citation: FU Chang-liang, WANG Li-ping, WANG Shao-peng, WANG Dong-jiao, ZHAO Ya-wen, MEI Meng-di. Preparation and properties of Ni/KIT-6 catalysts modified with different metals for methanation of CO₂[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 476-482. shu

Preparation and properties of Ni/KIT-6 catalysts modified with different metals for methanation of CO₂

1.
School of Chemical Engineering and Food Science, Zhengzhou Institute of Technology, Zhengzhou 450044, China
2.
Zhengzhou Key Laboratory of Applied Chemical Industry, Zhengzhou 450044, China

Corresponding author: FU Chang-liang, fuchangliang@163.com
Received Date: 7 January 2020
Revised Date: 27 February 2020

Fund Project: The project was supported by the Henan Science and Technology Open Cooperation Project (172106000067) and the Funding Scheme for Young Key Teachers in Colleges and Universities of Henan Province (2013GGJS-297)the Funding Scheme for Young Key Teachers in Colleges and Universities of Henan Province 2013GGJS-297the Henan Science and Technology Open Cooperation Project 172106000067

Figures(5)

Ni/KIT-6 catalysts modified by Mg, Ce, V and La for CO₂ methanation were prepared by co-impregnation method.The catalysts were characterized by N₂ absorption-desorption, XRD, H₂-TPD and TEM.The effects of different promoters on structure and properties of Ni/KIT-6 catalysts were investigated. The results show that the dispersity of Ni and promoters are very high. The dispersion of Ni particles depends primarily on the confinement effect of the well-ordered mesoporous structure of KIT-6, and is not affected by the addition of metal promoters. The addition of promoters does not affect the surface morphology of Ni/KIT-6 catalyst, but has effects on the difficulty and reduction degree of Ni reduction. Among the metal promoters studied, V addition makes the reduction of NiO in the catalyst easily and results in a high reduction degree. The oxide of V can change the reaction mechanism of CO₂ methanation, resulting in the best methanation performance. Compared with the unmodified catalyst, the catalyst modified by V makes the conversion of CO₂ and the selectivity of CH₄ increase by 3.7% and 11.6% respectively. The selectivity of CH₄ is 100%.
- Ni catalyst,
- KIT-6 carrier,
- carbon dioxide,
- methanation
1. [1]
  QIU M, T AO, H L, LI Y, ZHANG Y F. Insight into the mechanism of CO₂ and CO methanation over Cu(100) and Co-modified Cu(100) surfaces:A DFT study[J]. Appl Surf Sci, 2019,495143457. doi: 10.1016/j.apsusc.2019.07.199
2. [2]
  FALBO L, VISCONTI C G, LIETTI L, SZANYI J. The effect of CO on CO₂ methanation over Ru/Al₂O₃ catalysts:A combined steady-state reactivity and transient DRIFT spectroscopy study[J]. Appl Catal B:Environ, 2019,256.
3. [3]
  CABRERO-ANTONINO M, REMIRO-BUENAMAÑANA S, SOUTO M, VALDIVIA A G, CHOQUESILLO-LAZARTE D, NAVALÓN S, RODRIGUEZ-DIÉGUEZ A, MINGUEZ ESPALLARGAS G, GARCÍA H. Design of cost-efficient and photocatalytically active Zn-based MOFs decorated with Cu₂O nanoparticles for CO₂ methanation[J]. Catal Commun, 2019,55(73):10932-10935.
4. [4]
  HUANG J, LI X, WANG X, FANG X ZH, WANG H M, XU X L. New insights into CO₂ methanation mechanisms on Ni/MgO catalysts by DFT calculations:Elucidating Ni and MgO roles and support effects[J]. J CO₂ Util, 2019,33:55-63. doi: 10.1016/j.jcou.2019.04.022
5. [5]
  ZHANG Zhi-lei. Preparation and catalytic performance of nickel-based zirconia catalysts for carbon dioxide methanation[D]. Taiyuan: Taiyuan University of Technology, 2019.
6. [6]
  SUN Yi-qing, JIN Bao-sheng, DONG Xin-xin, ZHANG Wen-jie, WANG Jin-de. Co_x methanation over nickel-based catalysts supported on ZrO₂-Al₂O₃ composite[J]. Chem Ind Eng Prog, 2019,38(7):3176-3184.
7. [7]
  HAN Yang. Study on Ni-based catalyst for methanation of syngas[D]. Shihezi: Shihezi University, 2017.
8. [8]
  LU Huai-liang. Preparation of catalysts of Ni-Mn(La, Ce, Fe, Co)/ZrO₂-montmorillonite nanocomposites and study on their methanation performance[D]. Hohhot: Inner Mongolia University, 2014.
9. [9]
  ZHI G J, GUO X N, WANG Y Y, JIN G Q. Effect of La₂O₃ modification on the catalytic performance of Ni/SiC for methanation of carbon dioxide[J]. Catal Commun, 2011,16(1):56-59. doi: 10.1016/j.catcom.2011.08.037
10. [10]
  WANG W, CHU W, WANG N, YANG W, JIANG C F. Mesoporous nickel catalyst supported on multi-walled carbon nanotubes for carbon dioxide methanation[J]. Int J Hydrogen Energy, 2016,41(2):967-975.
11. [11]
  GUO M, LU G X. The effect of impregnation strategy on structural characters and CO₂ methanation properties over MgO modified Ni/SiO₂catalysts[J]. Catal Commun, 2014,54:55-60. doi: 10.1016/j.catcom.2014.05.022
12. [12]
  LU X P, GU F N, LIU Q, GAO J J, LIU Y J, LI H F, JIA L H, ZHONG Z Y, SU F B. VO_x promoted Ni catalysts supported on the modified bentonite for CO and CO₂ methanation[J]. Fuel Process Technol, 2015,135:34-46. doi: 10.1016/j.fuproc.2014.10.009
13. [13]
  CHENG Kai, BAI Long-lu, PIAO Wen-xiang. Research progress of mesoporous material KIT-6[J]. Chin Polym Bull, 2018(7):58-68.
14. [14]
  MEI De-jun. Preparation, modification and CO₂ adsorption of Beta/KIT-6 micro/mesoporous composite molecular sieves[D]. Guilin: Guilin University of Technology, 2019.
15. [15]
  LI Bai-tao, LUO Xin, HUANG Jing, WANG Xiu-jun, LIANG Zhen-xing. One-pot synthesis of ordered mesoporous Cu-KIT-6 and its improved catalytic behavior for the epoxidation of styrene:Effects of the pH value of the initial gel[J]. Chin J Catal, 2017,38(3):518-528.
16. [16]
  CAO Hong-xia. Study on preparation, Characterization and performance of catalyst for CO/CO₂ methanation[D]. Xuzhou: China University of Mining and Technology, 2018.
17. [17]
  HUANG jin. CO₂ methanation mechanismon cubic-ZrO₂ and MgO supported Ni catalysts: A combined theoretical and experimental study[D]. Nanchang: Nanchang University, 2019.
18. [18]
  LU B W, KAWAMOTO K. Direct synthesis of highly loaded and well-dispersed NiO/SBA-15 for producer gas conversion[J]. RSC Adv, 2012,2(17):6800-6805. doi: 10.1039/c2ra20344h
19. [19]
  QIU S B, ZHANG X, LIU Q Y, WANG T J, ZHANG Q, MA L L. A simple method to prepare highly active and dispersed Ni/MCM-41 catalysts by co-impregnation[J]. Catal Commun, 2013,42(23):73-78.
20. [20]
  ZHANG Q, WANG T J, LI B, JIANG T, MA L L, ZHANG X H, LIU Q Y. Aqueous phase reforming of sorbitol to bio-gasoline over Ni/HZSM-5 catalysts[J]. Appl Energy, 2012,97(3):509-513.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and properties of Ni/KIT-6 catalysts modified with different metals for methanation of CO2

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通讯作者: 陈斌, bchen63@163.com

Preparation and properties of Ni/KIT-6 catalysts modified with different metals for methanation of CO₂