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Citation: ZHAN Hai-juan, SHI Xiao-yan, HUANG Xin, ZHAO Ning. Highly coke-resistant ordered mesoporous Ni/SiC with large surface areas in CO2 reforming of CH4[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(8): 942-948. shu

Highly coke-resistant ordered mesoporous Ni/SiC with large surface areas in CO2 reforming of CH4

  • 1.

    State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

  • 2.

    State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

  • Corresponding author: HUANG Xin, huangxin@sxicc.ac.cn ZHAO Ning, zhaoning@sxicc.ac.cn
  • Received Date: 16 April 2019
    Revised Date: 12 June 2019

    Fund Project: the Scientific Research Foundation of Higher Education Institutions of Ningxia NGY2017008The project was supported by the Scientific Research Foundation of Higher Education Institutions of Ningxia (NGY2017008)

Figures(9)

  • An ordered mesoporous SiC (SiC-OM) material with high specific surface area (345 m2/g) and narrow pore distribution was prepared by a nanocasting method, and a commercial SiC (49 m2/g, SiC-C) was used as a reference carrier. The Ni/SiC-C and Ni/SiC-OM catalysts were prepared by an incipient wetness impregnation method, and tested in the CO2 reforming of CH4(CRM). The textural properties of fresh and used catalysts were characterized by means of ICP, BET, XRD, H2-TPR, XPS, HRTEM, TG, and Raman. The results suggested the average carbon deposition rate over the Ni/SiC-OM decreased one order of magnitude compared with the Ni/SiC-C during 50 h of CRM reaction, due to the strong interaction between Ni species and SiC-OM support and confinement effect of rigid mesoporous skeleton.
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    1. [1]

      DEVENDRA P, JAMES S. A review of dry (CO2) reforming of methane over noble metal catalysts[J]. Chem Soc Rev, 2014,43(22):7813-7837. doi: 10.1039/C3CS60395D

    2. [2]

      SUN N N, WEN X, WANG F, WEI W, SUN Y H. Effect of pore structure on Ni catalyst for CO2 reforming of CH4[J]. Energy Environ Sci, 2010,3(3):366-369. doi: 10.1039/b925503f

    3. [3]

      HUANG X, XUE G X, WANG C Z, ZHAO N, SUN N N, WEI W, SUN Y H. Highly stable mesoporous NiO-Y2O3-Al2O3 catalysts for CO2 reforming of methane:Effect of Ni embedding and Y2O3 promotion[J]. Catal Sci Technol, 2016,6(2):449-459. doi: 10.1039/C5CY01171J

    4. [4]

      LI S R, GONG J L. Strategies for improving the performance and stability of Ni-based catalysts for reforming reactions[J]. Chem Soc Rev, 2014,43(21):7245-7256. doi: 10.1039/C4CS00223G

    5. [5]

      KAWI S, KATHIRASER Y, NI J, OEMAR U, LI Z W, SAW E T. Progress in synthesis of highly active and stable nickel-based catalysts for carbon dioxide reforming of methane[J]. ChemSusChem, 2015,8(21):3556-3575. doi: 10.1002/cssc.201500390

    6. [6]

      ROSTRUP-NIELSEN J R, HANSEN J H B. CO2 reforming of methane over transition metals[J]. J Catal, 1993,144(1):38-49.  

    7. [7]

      HUANG X, JI C C, WANG C Z, XIAO F K, ZHAO N, SUN N N, WEI W, SUN Y H. Ordered mesoporous CoO-NiO-Al2O3 bimetallic catalysts with dual confinement effects for CO2 reforming of CH4[J]. Catal Today, 2017,281:241-249. doi: 10.1016/j.cattod.2016.02.064

    8. [8]

      KIM J, SUH D J, PARK T, KIM K. Effect of metal particle size on coking during CO2 reforming of CH4 over Ni-alumina aerogel catalysts[J]. Appl Catal A:Gen, 2000,197(2):191-200. doi: 10.1016/S0926-860X(99)00487-1

    9. [9]

      TIAN H, LI X Y, ZENG L, GONG J L. Recent advances on the design of group Ⅷ base-metal catalysts with encapsulated structures[J]. ACS Catal, 2015,5(8):4959-4977. doi: 10.1021/acscatal.5b01221

    10. [10]

      LI H T, QIU Y, WANG C Z, HUANG X, XIAO T C, ZHAO Y X. Nickel catalysts supported on ordered mesoporous SiC materials for CO2 reforming of methane[J]. Catal Today, 2018,317:76-85. doi: 10.1016/j.cattod.2018.02.038

    11. [11]

      LIU H T, LI S Q, ZHANG S B, WANG J M, WANG J M, ZHOU G J, CHEM G J, CHEM L, WANG X L. Catalytic performance of novel Ni catalysts supported on SiC monolithic foam in carbon dioxide reforming of methane to synthesis gas[J]. Catal Commun, 2008,9(1):51-54.  

    12. [12]

      LIU H T, LI S Q, ZHANG S B, CHEN L, ZHOU G J, WANG J M, WANG X L. Catalytic performance of monolithic foam Ni/SiC catalyst in carbon dioxide reforming of methane to synthesis gas[J]. Catal Lett, 2008,120(1/2):111-115.  

    13. [13]

      GUO Peng-fei, JIN Guo-qiang, GUO Cong-xiu, WANG Ying-yong, TONG Xi-li, GUO Xiang-yun. Effects of Yb2O3 promoter on the performance of Ni/SiC catalysts in CO2 reforming of CH4[J]. J Fuel Chem Technol, 2014,42(6):719-726.  

    14. [14]

      WANG Bing, GUO Cong-xiu, WANG Ying-yong, JIN Guo-qiang, GUO Xiang-yun. Performance of Ni-Smx/SiC catalysts for CO2 reforming of CH4[J]. J Fuel Chem Technol, 2016,44(5):587-596. doi: 10.3969/j.issn.0253-2409.2016.05.011 

    15. [15]

      SHI Y F, MENG Y, CHEN D H, CHENG S J, CHEN P, YANG T F, WAN Y, ZHAO D Y. Highly ordered mesoporous silicon carbide ceramics with large surface areas and high stability[J]. Adv Funct Mater, 2006,16(4):561-567. doi: 10.1002/(ISSN)1616-3028

    16. [16]

      JIN G Q, GUO X Y. Synthesis and characterization of mesoporous silicon carbide[J]. Microporous Mesoporous Mater, 2003,60(1/3):207-212.  

    17. [17]

      WANG C Z, SUN N N, ZHAO N, WEI W, ZHANG J, ZHAO T J, SUN Y H, SUN C G, LIU H, SNAPE C. The properties of individual carbon residuals and their influence on the deactivation of Ni-CaO-ZrO2 catalysts in CH4 dry reforming[J]. ChemCatChem, 2014,6(2):640-648. doi: 10.1002/cctc.v6.2

    18. [18]

      HOFFMANN C, PLATE P, STEINBRUCK A, KASKEL S. Nanoporous silicon carbide as nickel support for the carbon dioxide reforming of methane[J]. Catal Sci Technol, 2015,5(8):4174-4183. doi: 10.1039/C4CY01234H

    19. [19]

      SING K S, EVERETT D H, HAUL R A W, MOSCOU L, PIEROTTI R A, ROUQUÉROL J, SIEMIENIEWSKA T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity[J]. Pure Appl Chem, 1985,57(4):603-619. doi: 10.1351/pac198557040603

    20. [20]

      XU L L, SONG H L, CHOU L J. One-pot synthesis of ordered mesoporous NiO-CaO-Al2O3 composite oxides for catalyzing CO2 reforming of CH4[J]. ACS Catal, 2012,2(7):1331-1342. doi: 10.1021/cs3001072

    21. [21]

      WANG C Z, SUN N N, ZHAO N, WEI W, SUN Y H, SUN C G, LIU H, SNAPE C. Coking and deactivation of a mesoporous Ni-CaO-ZrO2 catalyst in dry reforming of methane:A study under different feeding compositions[J]. Fuel, 2015,143:527-535. doi: 10.1016/j.fuel.2014.11.097

    22. [22]

      HUANG X, JIAO X, LIN M G, WANG K, JIA L T, HOU B, LI D B. Coke distribution determines the lifespan of a hollow Mo/HZSM-5 capsule catalyst in CH4 dehydroaromatization[J]. Catal Sci Technol, 2018,8(22):5740-5749. doi: 10.1039/C8CY01391H

    23. [23]

      HUANG Xin, JIAO Xi, LIN Ming-gui, JIA Li-tao, HOU Bo, LI De-bo. Research progress in the direct nonoxidative dehydroaromatization of methane to aromatics[J]. J Fuel Chem Technol, 2018,46(9):1087-1100. doi: 10.3969/j.issn.0253-2409.2018.09.008 

    24. [24]

      GUO J J, LUO H, ZHENG X M. The deposition of coke from methane on a Ni/MgAl2O4 catalyst[J]. Carbon, 2007,45(6):1314-1321. doi: 10.1016/j.carbon.2007.01.011

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