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Citation: ZHANG Lu-lu, ZHAN Jin-you, SUN Yao, SHEN Jian. Preparation of WO3-TiO2/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(6): 754-762. shu

Preparation of WO3-TiO2/SBA-15 catalyst and its photocatalytic performance in oxidative desulfurization

  • College of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China

  • Corresponding author: SHEN Jian, lnshenjian@126.com
  • Received Date: 28 October 2015
    Revised Date: 16 December 2015

Figures(15)

  • WO3-TiO2/SBA-15 catalyst was prepared by inner-pore hydrolysis method; it was characterized by XRD, SEM, EDS, N2 sorption, FT-IR, TG-DTA and UV-vis and used in the photocatalytic oxidative desulfurization of diesel oil. The effects of WO3 and TiO2 loading and calcination temperature and time on the performance of the WO3-TiO2/SBA-15 catalyst in its photocatalytic oxidative desulfurization were investigated. The results indicated that the optimum loadings of WO3 and TiO2 were 1.6% and 15%, respectively, and corresponding calcination temperature and time were 500℃ and 3h, respectively. Over the WO3-TiO2/SBA-15 catalyst prepared under the optimum conditions, in which the hexagonal mesoporous structure was well retained, the desulfurization rate of model diesel oil reached 87.9%. Moreover, the WO3-TiO2/SBA-15 catalyst also exhibited excellent reusability after regeneration.
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