Citation: WU Bao-qiang, MA Xiao-xun, LIANG Bin, HAN Yun-da. Preparation of HZSM-5 zeolite assisted by glycerin and its catalytic performance for methane aromatization[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 821-832. shu

Preparation of HZSM-5 zeolite assisted by glycerin and its catalytic performance for methane aromatization

School of Chemical Engineering, Northwest University; International Scientific and Technological Cooperation Base for Clean Utilization of Hydrocarbon Resources; Chemical Engineering Research Center of the Ministry of Education for Advance Use Technology of Shaanbei Energy; Shaanxi Research Center of Engineering Technology for Clean Coal Conversion; Collaboration Innovation Center for Development of Energy and Chemical Industry in Northern Shanxi, Xi'an 710069, China

Corresponding author: MA Xiao-xun, 13772424852@163.com
Received Date: 21 April 2020
Revised Date: 14 June 2020

Fund Project: the National Natural Science Foundation of China 21536009the Joint Funds of National Key R & D Program of China 2018YFB0604603The project was supported by the Joint Funds of National Key R & D Program of China (2018YFB0604603), the National Natural Science Foundation of China (21536009) and the Science and Technology Plan Projects of Shaanxi Province, China (2017ZDCXL-GY-10-03, 2018ZDXM-GY-167)the Science and Technology Plan Projects of Shaanxi Province, China 2018ZDXM-GY-167the Science and Technology Plan Projects of Shaanxi Province, China 2017ZDCXL-GY-10-03

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HZSM-5 zeolite was synthesized under hydrothermal condition with TEOS as silicon source and glycerin as auxiliary agent. The effects of glycerol addition and crystallization time on the grain size, relative crystallinity and acidity of HZSM-5 molecular sieves and their catalytic performance for anaerobic aromatization of methane were investigated. XRD, SEM, NH₃-TPD and other analytical methods were used to characterize the HZSM-5 molecular sieve samples synthesized under different conditions. The results show that the relative crystallinity of HZSM-5 molecular sieve can be increased through adding certain amount of glycerol adjuvant and adjusting the crystallization time, meanwhile, the formation of amorphous SiO₂ can be suppressed and the acid content can be increased. The HZSM-5 prepared with glycerol assistance shows excellent catalytic performance in methane anaerobic aromatization. Compared with the HZSM-5 catalyst synthesized without the addition of glycerin, the methane conversion rate, benzene selectivity and aromatic selectivity are all greatly improved, and it has better stability and resistance to carbon deposition.
- glycerin,
- HZSM-5,
- methane,
- anaerobic aromatization,
- aromatics
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