Citation: KUANG Zhi-qi, LI Feng, LUO Jing, WANG Yan-xia, YUAN Dan-ping, WANG Qin, ZHAO Hai-hong, WANG Shi-wei, ZHAO Ning, XIAO Fu-kui. LaCuZnX (X=Al, Zr, Al+Zr) perovskite-like catalysts treated by NaBH₄ and their catalytic performance for CO₂ hydrogenation to methanol[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(3): 293-301. shu

LaCuZnX (X=Al, Zr, Al+Zr) perovskite-like catalysts treated by NaBH₄ and their catalytic performance for CO₂ hydrogenation to methanol

KUANG Zhi-qi ^1,2 ,
LI Feng ^1,, ,
LUO Jing ^1,2 ,
WANG Yan-xia ^1,2 ,
YUAN Dan-ping ^1,2 ,
WANG Qin ^1,2 ,
ZHAO Hai-hong ^1,2 ,
WANG Shi-wei ^1,2 ,
ZHAO Ning ¹ ,
XIAO Fu-kui ^1,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LI Feng, lifeng2729@sxicc.ac.cn XIAO Fu-kui, xiaofk@sxicc.ac.cn
Received Date: 6 December 2019
Revised Date: 9 January 2020

Fund Project: Natural Science Foundation of Shanxi Province 201801D121070the National Natural Science Foundation of China 21776294The project was supported by the National Youth Science Foundation of China(21802158), the National Natural Science Foundation of China (21776294), Natural Science Foundation of Shanxi Province (201801D121070) and Youth Science Foundation of Shanxi Province(201701D221052)The project was supported by the National Youth Science Foundation of China 21802158Youth Science Foundation of Shanxi Province 201701D221052

Figures(8)

La:Cu:Zn:X (X=Zr, Al, Al+Zr) perovskite-like catalysts were prepared by coprecipitation method followed by liquid phase reduction by NaBH₄. The physicochemical properties of the catalysts were tested by a series of characterization methods, and the catalysts were tested for methanol synthesis from CO₂ hydrogenation in a fixed-bed reactor. The results showed that the as-prepared catalysts were mainly composed of La₂CuO₄ perovskite-like crystal structure and doping of elements led to the spatial distortion of the perovskite-like structure. After reduction by NaBH₄, metal copper species and some high-valence copper species were found, which could be further reduced during the reaction. The CO₂ conversion was positively correlated with the Cu surface area, the dispersion of Cu, and the (Cu^α++Cu⁰)/Cu_total of the catalyst. The higher methanol selectivity was obtained when Cu^α+ binding energy was farther away from Cu⁺ binding energy. LCZA had the highest CO₂ conversion, LCZ catalyst possessed the highest methanol selectivity, and LCZZA catalyst presented the optimal methanol space time yield.
- CO₂ hydrogenation,
- methanol,
- perovskite-like,
- liquid reduction method
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LaCuZnX (X=Al, Zr, Al+Zr) perovskite-like catalysts treated by NaBH4 and their catalytic performance for CO2 hydrogenation to methanol

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通讯作者: 陈斌, bchen63@163.com

LaCuZnX (X=Al, Zr, Al+Zr) perovskite-like catalysts treated by NaBH₄ and their catalytic performance for CO₂ hydrogenation to methanol