Citation: CHEN Ling-peng, TIAN Zhi-peng, LÜ Wei, SI Zhan, LIU Qi-ying, DING Ming-yue, CHEN Lun-gang, MA Long-long, ZHANG Qi, WANG Tie-jun, WANG Chen-guang. Preparation of Pt-Sn_E/Mg (Al) O catalyst by anion exchange method and its performance in alkane dehydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(5): 597-606. shu

Preparation of Pt-Sn_E/Mg (Al) O catalyst by anion exchange method and its performance in alkane dehydrogenation

1.
Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Bio Energy Engineering and Low Carbon Technology Laboratory, China Agricultural University, Beijing 100083, China

Corresponding author: WANG Chen-guang, wangcg@ms.giec.ac.cn
Received Date: 16 December 2015
Revised Date: 1 March 2016

Fund Project: the National Natural Science Foundation of China 51476175the Hundred Talents Program of the Chinese Academy of Sciences y507y51001

Figures(11)

Pt-Sn_E/Mg (Al) O catalyst was prepared by anion exchange method with hydrotalcite as the support. The Pt-Sn_E/Mg (Al) O catalyst was characterized by XRD, nitrogen sorption, CO-TPD and TEM; its catalytic performance in the dehydrogenation of ethane and propane was compared with that the Pt-Sn_I/Mg (Al) O catalyst obtained by impregnation method. The results indicate that under the same reaction conditions, the conversions of ethane over the Pt-Sn_E/Mg (Al) O and Pt-Sn_I/Mg (Al) O catalysts are 12.2% and 3.1%, respectively, whist the conversions of propane over these two catalysts are 38.7% and 26.4%, respectively. Such results illustrate that the Pt-Sn_E/Mg (Al) O catalyst prepared by the anion exchange method is obviously superior to the Pt-Sn_I/Mg (Al) O catalyst prepared by the impregnation method in terms of catalytic activity and stability for alkane dehydrogenation.
- platinum,
- hydrotalcite,
- Mg (Al) O,
- anion exchange,
- ethane dehydrogenation,
- propane dehydrogenation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Pt-SnE/Mg (Al) O catalyst by anion exchange method and its performance in alkane dehydrogenation

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通讯作者: 陈斌, bchen63@163.com

Preparation of Pt-Sn_E/Mg (Al) O catalyst by anion exchange method and its performance in alkane dehydrogenation