Citation: ZHANG Li, DAI Chao-hua, LIANG Qing-man, YAN Jian-hui, ZHOU Min-jie. Preparation of ZnCr₂O₄-ZnO composite photocatalyst based on the hydrotalcite precursor and its performance in hydrogen production[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(10): 1266-1274. shu

Preparation of ZnCr₂O₄-ZnO composite photocatalyst based on the hydrotalcite precursor and its performance in hydrogen production

College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China

Corresponding author: ZHOU Min-jie, zmj0104@163.com
Received Date: 26 June 2017
Revised Date: 13 August 2017

Fund Project: The project was supported by the National Natural Science Foundation of China 51372080Scientific Research Foundation of Hunan Provincial Education Department of China 15A076the Natural Science Foundation of Hunan Provincial of China 2017JJ2108The project was supported by the National Natural Science Foundation of China (51372080), the Natural Science Foundation of Hunan Provincial of China (2017JJ2108) and Scientific Research Foundation of Hunan Provincial Education Department of China (15A076)

Figures(10)

ZnCr₂O₄-ZnO composite photocatalyst with heterogeneous structure was synthesized by grinding hydrothermal method and characterized by TG-DTA, XRD, SEM, HRTEM, DRS, and N₂ absorption; its photocatalytic activity in H₂ production was evaluated by using oxalic acid as the sacrificial agent under simulated sunlight irradiation and compared with those of the ZnCr₂O₄-ZnO samples prepared by coprecipitation, urea reflux and urea hydrothermal methods. The results indicate that Zn-Cr precursors prepared by four methods show a certain hydrotalcite structure; the catalyst samples prepared at 500℃ are spherical nanoparticles, but different in agglomeration status, specific surface area and pore structure parameters. The ZnCr₂O₄-ZnO nanoparticles prepared by a grinding hydrothermal method exhibits the optimized photocurrent response and photocatalytic activity; the yield of hydrogen production is 0.956 mmol/(h·g_cat), which is 2.3, 1.5 and 3.0 times higher than that of the catalyst samples prepared by coprecipitation, urea reflux and urea hydrothermal methods, respectively. On the basis of these results, a possible mechanism for the hydrogen production over ZnCr₂O₄-ZnO composite photocatalyst with heterogeneous structure was then proposed.
- grinding hydrothermal method,
- ZnCr₂O₄-ZnO,
- heterojunction,
- photocatalytic hydrogen production
1. [1]
  FUJISHIMA K, HONDA K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972,238(7):37-38.
2. [2]
  WANG K, XU J M, WANG X T. The effects of ZnO morphology on photocatalytic efficiency of ZnO/RGO nanocomposites[J]. Appl Surf Sci, 2016,360:270-275. doi: 10.1016/j.apsusc.2015.10.190
3. [3]
  LIU Zong-yuan, WANG Gui-yun, LIU Xian-ping, WANG Yan-ji. Preparation of CuCrO₂ and the photocatalytic properties of its composites[J]. J Fuel Chem Technol, 2013,41(12):1473-148.
4. [4]
  YU X L, AN X Q, GENC A, IBANEZ M, ARBIOL J, ZHANG Y H, and CABOT A. Cu₂ZnSnS₄-PtM (M=Co, Ni) Nanoheterostructures for Photocatalytic Hydrogen Evolution[J]. J Phys Chem C, 2015,119(38):21882-21888. doi: 10.1021/acs.jpcc.5b06199
5. [5]
  WANG Ze-yan, HUANG Bai-biao1, DAI Ying. Design and Synthesis of Highly Reactive Photocatalysts[J]. Mater China, 2017,36(1):7-17.
6. [6]
  NIKITENKO S I, CHAVE T, CAU C, BRAU H-P, FLAUD V. Photothermal Hydrogen Production Using Noble-Metal-Free Ti@TiO₂ Core-Shell Nanoparticles under Visible-NIR Light Irradiation[J]. ACS Catalysis, 2015,5(8):4790-4795. doi: 10.1021/acscatal.5b01401
7. [7]
  KLINGSHIM C. ZnO:material, physics and applications[J]. ChemPhysChem, 2007,8(6):782-803. doi: 10.1002/(ISSN)1439-7641
8. [8]
  WANG Z L. Zinc oxide nanostructures:growth, properties and applications[J]. J Phys:Condens Matter, 2004,16(25):R829-R858. doi: 10.1088/0953-8984/16/25/R01
9. [9]
  WANG Z, TERAMURA K, HOSOKAWA S, TANAKA T. Highly efficient photocatalytic conversion of CO₂ into solid CO using H₂O as a reductant over Ag-modified ZnGa₂O₄[J]. J Mater Chem A, 2015,3(21):11313-11319. doi: 10.1039/C5TA01697E
10. [10]
  ZHANG L, YAN J H, ZHOU M J, YANG Y H, LIU Y N. Fabrication and photocatalytic properties of spheres-in-spheres ZnO/ZnAl₂O₄ composite hollow microspheres[J]. Appl Surf Sci, 2013,268:237-245. doi: 10.1016/j.apsusc.2012.12.069
11. [11]
  YANG H H, YAN J H, LU Z, CHENG X, TANG Y G. Photocatalytic activity evaluation of tetragonal CuFe₂O₄ nanoparticles for the H₂ evolution under visible light irradiation[J]. J Alloys Compd, 2009,476(1):715-719.
12. [12]
  GHOLAMI T, SALAVATI-NIASARI M, VARSHOY S. Investigation of the electrochemical hydrogen storage and photocatalytic properties of CoAl₂O₄ pigment:Green synthesis and characterization[J]. Int J Hydrogen Energy, 2016,41(22):9418-9426. doi: 10.1016/j.ijhydene.2016.03.144
13. [13]
  PENG C, GAO L. Optical and photocatalytic properties of spinel ZnCr₂O₄ nanoparticles synthesized by a hydrothermal route[J]. J Am Ceram Soc, 2008,91(7):2388-2390. doi: 10.1111/jace.2008.91.issue-7
14. [14]
  BOUMAZA S, BOUGUELIAA , BOUARAB R, TRARI M. Physical and photoelectrochemical studies for hydrogen photo-evolution over the spinel ZnCr₂O₄[J]. Int J Hydrogen Energy, 2009,34(11):4963-4967. doi: 10.1016/j.ijhydene.2008.11.059
15. [15]
  KUMAR A, DIXIT T. Phase Transformation and Optical Properties of Annealed Hydrothermally Synthesized ZnO/ZnCr₂O₄ Nanocomposites[J]. Int J Appl Ceram. Technol, DOI:2016,10.1111/ijac.12546.
16. [16]
17. [17]
  PALMER S J, FROST R L, NGUYEN T. Hydrotalcites and their role in coordination of anions in Bayer liquors:anion binding in layered double hydroxides[J]. Coord Chem Rev, 2009,253(1):250-267.
18. [18]
  MOHAPATRA L, PARIDA K M. Zn-Cr layered double hydroxide:Visible light responsive photocatalyst for photocatalytic degradation of organic pollutants[J]. Sep Purif Technol, 2012,91:73-80. doi: 10.1016/j.seppur.2011.10.028
19. [19]
  KIM S H, FAHEL J, DURAND PAndré E, Carteret C. Ternary layered double hydroxides (LDH) based on ZnAl substituted with Co, Cu for efficient photocatalysts designs[J]. Eur J Inorg Chem, DOI:2016,10.1002/ejic.01213.
20. [20]
  POKHREL S, JEYARAJ B, NAGARAJA K S. Humidity-sensing properties of ZnCr₂O₄-ZnO composites[J]. Mater Lett, 2003,57(22):3543-3548.
21. [21]
  JIANG C, LEE K Y, PARLETT C M A, BAYAZIT M K, LAU C C, RUAN Q S, MONIZ S J A, LEE A F, TANG J W. Size-controlled TiO₂ nanoparticles on porous hosts for enhanced photocatalytic hydrogen production[J]. Appl Catal, A, 2016,521:133-139. doi: 10.1016/j.apcata.2015.12.004
22. [22]
  CHENG X, HUANG X R, WANG X Z, SUN D Z. Influence of calcination on the adsorptive removal of phosphate by Zn-Al layered double hydroxides from excess sludge liquor[J]. J Hazard Mater, 2010,177:516-523. doi: 10.1016/j.jhazmat.2009.12.063
23. [23]
  HUO R J, KUANG Y, ZHAO Z P, ZHANG F Z, XU S L. Enhanced photocatalytic performances of hierarchical ZnO/ZnAl₂O₄ microsphere derived from layered double hydroxide precursor spray-dried microsphere[J]. J Colloid Interface Sci, 2013,407:17-21. doi: 10.1016/j.jcis.2013.06.067
24. [24]
  Yu X X, Yu J G, CHENG B, JARONIEC M. Synthesis of hierarchical flower-like AlOOH and TiO₂/AlOOH superstructures and their enhanced photocatalytic properties[J]. J Phys. Chem, 2009,113(40):17527-17535.
25. [25]
  GUO Q, ZHANG Z H, MA X P, JING K, SHEN M L, YU N, TANG J H, DIONYSIOU D D. Preparation of N, F-codoped TiO₂ nanoparticles by three different methods and comparison of visible-light photocatalytic performances[J]. Sep Purif Technol, 2017,v175:305-313.
26. [26]
  SREETHAWONG T, PUANGPETCH T, CHAVADEJ S, YOSHIKAWA S. Quantifying influence of operational parameters on photocatalytic H₂ evolution over Pt-loaded nanocrystalline mesoporous TiO₂ prepared by single-step sol-gel process with surfactant template[J]. J Power Sources, 2007,165(2):861-869. doi: 10.1016/j.jpowsour.2006.12.050
27. [27]
  TAN D Z, FAN W J, XIONG W N, SUN H X, LI A, DENG W Q, MENG C G. Study on adsorption performance of conjugated microporous polymers for hydrogen and organic solvents:The role of pore volume[J]. Eur Polym J, 2012,48(4):705-711. doi: 10.1016/j.eurpolymj.2012.01.012
28. [28]
  ZHANG Y, TANG Z R, FU X, XU Y J. Engineering the unique 2D mat of graphene to achieve graphene-TiO₂ nanocomposite for photocatalytic selective transformation:what advantage does graphene have over its forebear carbon nanotube[J]. ACS Nano, 2011,5:7426-7435. doi: 10.1021/nn202519j
29. [29]
  HAO Rui-peng, YANG Peng-ju, WANG Zhi-jian, ZHU Zhen-ping. Effect of noble metals loaded TiO₂ on the selectivity of photocatalytic CO₂ reduction[J]. J Fuel Chem Technol, 2015,43(1):94-99.
30. [30]
  PARHI P, MANIVANNAN V. Microwave metathetic approach for the synthesis and characterization of ZnCr₂O₄[J]. J Eur Ceram Soc, 2008,28:1665-1670. doi: 10.1016/j.jeurceramsoc.2007.11.005
31. [31]
  ZHANG Li, YAN Jian-hui, ZHOU Min-jie, YANG Ya-hui, LIU You-nian. Preparation and Photocatalytic Property of Hollow Sphere-Like ZnO/ZnAl₂O₄ Composite Photocatalysts with High Specific Surface Area[J]. Chinese J Inorg Chem, 2012,28(9):1827-1834.
32. [32]
  WEI Yang, MA Xin-guo, ZHU Lin, HE Hua, HUANG Chu-yun. Interfacial cohesive interaction and band modulation of two-dimensional MoS₂/graphene heterostructure[J]. Acta Phys Sin, 2017,66(8)087101-1-087101-10.
1. [1]
  Ruiyun Liu , Ping Wang , Xuefei Wang , Feng Chen , Huogen Yu . Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100137-0. doi: 10.1016/j.actphy.2025.100137
2. [2]
  Xiaochun Ke , Wei Zhong , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Heterointerface engineering of Mo₂C MXene to modulate H* adsorption affinity for efficient photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2026, 42(11): 100372-0. doi: 10.1016/j.actphy.2026.100372
3. [3]
  Jinhui Jiang , Jiaqi Sun , Yongyi Chen , Lei Zhang , Pengyu Dong . W₁₈O₄₉/Al-doped SrTiO₃ S-scheme heterojunction aided by the LSPR effect for full-spectrum solar light-driven photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100145-0. doi: 10.1016/j.actphy.2025.100145
4. [4]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
5. [5]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
6. [6]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
7. [7]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-0. doi: 10.1016/j.actphy.2025.100053
8. [8]
  Min WANG , Dehua XIN , Wei ZHANG , Haiying YANG , Yuchun WANG , Zhaorong LIU , Meng SHI , Le SHI . Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C₃N₄/Bi/BiOBr/BiOI heterojunction material. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2283-2298. doi: 10.11862/CJIC.20250109
9. [9]
  Min WANG , Dehua XIN , Guoqiang TAN , Xiaolu WU , Wei ZHANG , Tong CHANG , Lijuan JIA , Yuchun WANG , Zhaorong LIU . Construction and full-spectrum-driven photocatalytic antibiotics degradation performance of Z-scheme nitrogen vacancy g-C₃N₄/Ti₃C₂T_x/W₁₈O₄₉ heterojunction. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1613-1626. doi: 10.11862/CJIC.20260086
10. [10]
  Jingjing Liu , Aoqi Wei , Hao Zhang , Shuwang Duo . SnS₂-based heterostructures: advances in photocatalytic and gas-sensing applications. Acta Physico-Chimica Sinica, 2025, 41(12): 100185-0. doi: 10.1016/j.actphy.2025.100185
11. [11]
  Jiaqi Yang , Xuqiang Hao , Jiejie Jing , Yuqiang Hao , Zhiliang Jin . 3D/2D ReSe₂/ZnCdS S-scheme photocatalyst with efficient interfacial charge separation for optimized hydrogen production. Acta Physico-Chimica Sinica, 2025, 41(10): 100131-0. doi: 10.1016/j.actphy.2025.100131
12. [12]
  Yukai SHEN , Zhaochao YAN , Yangjun ZHOU , Mei HUANG . Nickel foam-supported NiFeP/NiFcDCA heterojunction electrocatalyst for efficient urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 237-246. doi: 10.11862/CJIC.20250257
13. [13]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
14. [14]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016
15. [15]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
16. [16]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
17. [17]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Zhiwen HU , Huiying ZHANG , Jiayan ZHOU , Yulong YANG , Ping LI , Zelong CHEN , Weixia DONG , Qifu BAO . Time evolution of in-situ synthesized Bi₁₂TiO₂₀/BaTiO₃ heterojunctions and catalytic mechanisms. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 65-77. doi: 10.11862/CJIC.20250172
20. [20]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(2850)
HTML views(383)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of ZnCr2O4-ZnO composite photocatalyst based on the hydrotalcite precursor and its performance in hydrogen production

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of ZnCr₂O₄-ZnO composite photocatalyst based on the hydrotalcite precursor and its performance in hydrogen production