Citation: SHANG Shuang, GUO Chao-qiang, LAN Kui, LI Ze-shan, QIN Zhen-hua, HE Wei-tao, LI Jian-fen. Preparation of Ni/Zr-MOF catalyst and its application in pyrolysis of biomass[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(9): 1067-1074. shu

Preparation of Ni/Zr-MOF catalyst and its application in pyrolysis of biomass

School of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China

Corresponding author: LI Jian-fen, lijfen@163.com
Received Date: 14 June 2019
Revised Date: 5 July 2019

Fund Project: The project was supported by the Technology Innovation Major Project of Hubei Province (2017ABA155) and the Central Committee Guide Local Science and Technology Development Special project of Hubei Province (2018ZYYD062)the Central Committee Guide Local Science and Technology Development Special project of Hubei Province 2018ZYYD062the Technology Innovation Major Project of Hubei Province 2017ABA155

Figures(8)

The catalytic co-pyrolysis of wet sewage sludge and wheat straw for hydrogen-rich gas production was experimentally investigated in a fixed bed reactor with Ni/Zr-MOF catalyst. The Ni/Zr-MOF catalyst was characterized by ultimate analysis, XRF, TG, XRD, SEM and BET. The effects of reactor temperature, straw content and Ni loading on the composition and yield of gasification gases were explored. The experimental results indicate that the mesoporous Zr-MOF support particles are octahedral with a specific surface area of 805.93 m²/g and an average pore diameter of 20.14 nm. The Ni/Zr-MOF catalyst has high thermal stability and catalytic activity. Compared with the pyrolysis without catalyst, the H₂ yield increases significantly from 0.39 mol/kg to 12.65 mol/kg using Ni/Zr-MOF catalyst at 500 ℃. After reuse, the carbon deposits are formed on the surface of catalyst. With the increase in reactor temperature, the catalytic activity decreases gradually due to the agglomeration of the catalyst. Therefore, the Ni/Zr-MOF catalyst is suitable for catalytic pyrolysis of biomass at lower temperature.
- biomass,
- Zr-MOF,
- catalyst,
- pyrolysis
1. [1]
  SAXENA R C, ADHIKARI D K, GOYAL H B. Biomass-based energy fuel through biochemical routes:A review[J]. Renewable Sustainable Energy Rev, 2009,13(1):167-178. doi: 10.1016/j.rser.2007.07.011
2. [2]
  ZHAO Z Y, YAN H. Assessment of the biomass power generation industry in China[J]. Renew Energy, 2012,37(1):53-60.
3. [3]
  ISMAIL T M, EL-SALAM M A. Parametric studies on biomass gasification process on updraft gasifier high temperature air gasification[J]. Appl Therm Eng, 2017,112:1460-1473. doi: 10.1016/j.applthermaleng.2016.10.026
4. [4]
  XU X, ZHAO B, SUN M, CHEN X, ZHANG M, LI H, XU S. Co-pyrolysis characteristics of municipal sewage sludge and hazelnut shell by TG-DTG-MS and residue analysis[J]. Waste Management, 2017,62:91-100. doi: 10.1016/j.wasman.2017.02.012
5. [5]
  HAN J, KIM H. The reduction and control technology of tar during biomass gasification/pyrolysis:An overview[J]. Renewable Sustainable Energy Rev, 2008,12(2):397-416. doi: 10.1016/j.rser.2006.07.015
6. [6]
  ZHOU Y, WANG W, SUN J, FU L, SONG Z, ZHAO X, MAO Y. Microwave-induced electrical discharge of metal strips for the degradation of biomass tar[J]. Energy, 2017,126:42-52. doi: 10.1016/j.energy.2017.03.008
7. [7]
  YANG Ze, LI Ting, WANG Mei-jun, CHANG Li-ping, REN Xiu-rong. Research progress on Ni-based catalyst for tar reforming in biomass gasification[J]. Chem Ind Eng Prog, 2016,35(10):3155-3163.
8. [8]
  LI J, LIU J, LIAO S, YAN R. Hydrogen-rich gas production by air-steam gasification of rice husk using supported nano-NiO/γ-Al₂O₃ catalyst[J]. Int J Hydrog Energy, 2010,35(14):7399-7404. doi: 10.1016/j.ijhydene.2010.04.108
9. [9]
  JI Ting-ting, YANG Xiao-xuan, WANG Ya-jing, WANG Yu-he. Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods[J]. J Fuel Chem Technol, 2016,44(9):1131-1137. doi: 10.3969/j.issn.0253-2409.2016.09.015
10. [10]
  SHI X W, XIN X, LIU Z, YAO L U, HONG-XIA L I, JIAN-FEN L I, CHEN Q P. Preparation and characterization of Ni/TPC catalyst and applied in straw pyrolysis gas reforming[J]. J Fuel Chem Technol, 2018,46(6):659-665. doi: 10.1016/S1872-5813(18)30028-8
11. [11]
  SHI Xun-wang, LI Jian-fen, XIN Xin, LI Hong-xia, LU Yao, LIU Zhao, CHENG Qun-peng. Preparation of NiO-Fe₂O₃/PG-γ-Al₂O₃ catalysts and its application in pyrolysis of biomass straw[J]. J Fuel Chem Technol, 2017,45(12):1434-1440. doi: 10.3969/j.issn.0253-2409.2017.12.004
12. [12]
  REN J, LANGMI H W, NORTH B C, MATHE M, BESSARABOV D. Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications[J]. Int J Hydrog Energy, 2014,39(2):890-895. doi: 10.1016/j.ijhydene.2013.10.087
13. [13]
  LV P M, XIONG Z H, CHANG J, WU C Z, CHEN Y, ZHU J X. An experimental study on biomass air-steam gasification in a fluidized bed[J]. Bioresour Technol, 2004,95(1):95-101. doi: 10.1016/j.biortech.2004.02.003
14. [14]
  QIAN K, KUMAR A. Catalytic reforming of toluene and naphthalene (model tar) by char supported nickel catalyst[J]. Fuel, 2017,187:128-136. doi: 10.1016/j.fuel.2016.09.043
15. [15]
  HU M, LAGHARI M, CUI B, XIAO B, ZHANG B, GUO D. Catalytic cracking of biomass tar over char supported nickel catalyst[J]. Energy, 2018,145:228-237. doi: 10.1016/j.energy.2017.12.096
16. [16]
  XIAO X, CAO J, MENG X, LE D D, LI L, OGAWA Y, SATO K, TAKARADA T. Synthesis gas production from catalytic gasification of waste biomass using nickel-loaded brown coal char[J]. Fuel, 2013,103:135-140. doi: 10.1016/j.fuel.2011.06.077
17. [17]
  SHEN W, MOMOI H, KOMATSUBARA K, SAITO T, YOSHIDA A, NAITO S. Marked role of mesopores for the prevention of sintering and carbon deposition in dry reforming of methane over ordered mesoporous Ni-Mg-Al oxides[J]. Catal Today, 2011,171(1):150-155. doi: 10.1016/j.cattod.2011.04.003
18. [18]
  YANG Y, ZHU J, ZHU G, YANG L, ZHU Y. The effect of high temperature on syngas production by immediate pyrolysis of wet sewage sludge with sawdust[J]. J Therm Anal Calorim, 2018,132(3):1783-1794. doi: 10.1007/s10973-018-7143-9
19. [19]
  HU M, GAO L, CHEN Z, MA C, ZHOU Y, CHEN J, MA S, LAGHARI M, XIAO B, ZHANG B, GUO D. Syngas production by catalytic in-situ steam co-gasification of wet sewage sludge and pine sawdust[J]. Energy Convers Manage, 2016,111:409-416. doi: 10.1016/j.enconman.2015.12.064
20. [20]
  WANG Chen-guang, WANG Tie-jun, LÜ Peng-mei, CHANG Jie, XU Ying. Reforming of raw biomass fuel gas over monolithic catalyst[J]. J Fuel Chem Technol, 2007,35(3):285-288. doi: 10.3969/j.issn.0253-2409.2007.03.006
21. [21]
  XU L, SONG H, CHOU L. Carbon dioxide reforming of methane over ordered mesoporous NiO-MgO-Al₂O₃ composite oxides[J]. Appl Catal B:Environ, 2011,108/109:177-190. doi: 10.1016/j.apcatb.2011.08.028
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Wenruo NI , Hongpeng LI , Yun ZHANG , Yiran TIAN , Jiehui RUI , Yingcheng TONG , Xiaolin PI , Zhenyan TANG . Research progress of ruthenium alloy catalysts in hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 23-44. doi: 10.11862/CJIC.20250188
3. [3]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
6. [6]
  Chenyang WANG , Yiyan BAI , Wei ZHANG , Zhaorong LIU , Yuchun WANG . Performance of photo-assisted copper oxide catalyzed hydrolysis of ammonia borane to produce hydrogen. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 97-110. doi: 10.11862/CJIC.20250116
7. [7]
  Zhonghan Xu , Yuejia Li , Kin Shing Chan . 碳中和新旅程. University Chemistry, 2025, 40(6): 167-171. doi: 10.12461/PKU.DXHX202407075
8. [8]
  Qianqian ZHU , Lihui XU , Hong PAN , Chengjian YAO , Hong ZHAO , Nan MA , Xiaolin SHI , Zihan SHEN , Weijun ZHANG , Zhongjian WANG . Waste cotton fabric-ased porous carbon materials: Preparation and wave-absorbing properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1555-1564. doi: 10.11862/CJIC.20250040
9. [9]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
10. [10]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
11. [11]
  Mei-Xia Yang , Zhen-Hong He , Long-Rui Wang , You-Xing Yang . Route for Turning Waste CH₄ and CO₂ into Valuable Products: Reforming for Syngas. University Chemistry, 2026, 41(2): 197-207. doi: 10.12461/PKU.DXHX202503012
12. [12]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
13. [13]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
14. [14]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
15. [15]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
16. [16]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
17. [17]
  Aoran LIU , Rui LI , Zongyao WANG , Penghui SHANG , Jiawei WAN , Dan WANG . Hollow multi-shelled structure materials for catalytic applications. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2039-2053. doi: 10.11862/CJIC.20250036
18. [18]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
19. [19]
  Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
20. [20]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(2432)
HTML views(369)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142