Citation: YANG Gang-sheng, ZENG Gan-ning, ZHAO Qiang, CHEN Xu, CHEN Sheng-ji, AI Ning. Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(1): 106-112. shu

Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide

YANG Gang-sheng ^1,2 ,
ZENG Gan-ning ³ ,
ZHAO Qiang ¹ ,
CHEN Xu ³ ,
CHEN Sheng-ji ¹ ,
AI Ning ^1,2,*,,

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
2.
Zhejiang Province Key Laboratory of Biofuel, Hangzhou 310014, China
3.
Ocean College, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: AI Ning, aining@zjut.edu.cn
Received Date: 24 July 2015
Revised Date: 29 September 2015

Fund Project: The project was supported by the Public Welfare Project of Science and Technology Department of Zhejiang Province 2013C33005

Figures(6)

Two amino acid ionic liquids (AAILs), viz., tetramethyl ammonium glycinate ([N₁₁₁₁][Gly]) and tetramethyl ammonium lysine ([N₁₁₁₁][Lys]) were supported on porous silica gel through impregnation evaporation method and used as the adsorbents for carbon dioxide. They were characterized by elemental analysis (EA), thermogravimetric analysis (TGA), nitrogen physisorption and Fourier transform infrared (FT-IR) spectroscopy; the effects of AAIL type, loading and temperature on their adsorption capacity towards carbon dioxide were investigated. The results illustrate that AAILs are successfully immobilized into the porous silica gel and the supported sorbents exhibit excellent performance towards carbon dioxide, i.e. fast adsorption rate and high capacity. At 303.15-323.15 K, the adsorption capacity reduces with the increase of temperature, whereas there is a optimal loading of ionic liquids to get highest adsorption capacity towards carbon dioxide. Under 30 ℃ and 0.1 MPa, the [N₁₁₁₁][Gly]/SG adsorbent with a [N₁₁₁₁][Gly] loading of 22.4% exhibits the highest CO₂ capture capacity, i.e. 41 mg/g, equivalent to 0.62 mol CO₂ per mol AAILs; moreover, 90% of the equilibrium adsorption amount can be achieved in 20 min. Furthermore, no obvious decrease in the adsorption capacity is observed after recycling for six times.
- amino acid ionic liquids,
- CO₂ capture,
- support,
- impregnation evaporation method
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