Citation: SUN Liang-liang, LIU Li-li, LUO Ling-hong, WU Ye-fan, SHI Ji-jun, CHENG Ling, Xu XU, GUO You-min. Facile synthesis of flower like Pd catalyst for direct ethanol solid oxide fuel cell[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(5): 607-612. shu

Facile synthesis of flower like Pd catalyst for direct ethanol solid oxide fuel cell

SUN Liang-liang ¹ ,
LIU Li-li ¹ ,
LUO Ling-hong ¹ ,
WU Ye-fan ¹ ,
SHI Ji-jun ¹ ,
CHENG Ling ¹ ,
Xu XU ¹ ,
GUO You-min ^2,*,,

1.
School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333001, China
2.
School of Physics and Materials Science, Anhui University, Hefei 230601, China

Corresponding author: GUO You-min, 122193285@qq.com
Received Date: 20 November 2015
Revised Date: 25 February 2016

Fund Project: the National Nature Science Foundation of China 51162014the National Nature Science Foundation of China 51462011Anhui University personnel start-up funding 10117700069the National Nature Science Foundation of China 51302119

Figures(8)

A flower like Pd layer was synthesized through galvanic displacement reaction on Ni-YSZ (yttria stabilized zirconia) anode at room temperature. The morphology of as prepared Pd catalyst was characterized by various techniques. It was shown that three dimensional Pd nanoflowers were formed via nanorods on the Ni-YSZ anode. With Pd nanoflowers as a functional layer of the Ni-YSZ anode, the cell exhibited much higher peak power density and better operation stability in ethanol than that made with conventional Ni-YSZ anode. This study demonstrated that galvanic displacement reaction is a promising way to prepare nanostructured metal catalyst as a result of depressing the carbon deposition in Ni-based anode and improving its output in alcohol fuels.
- SOFC,
- galvanic displacement reaction,
- Pd nanoflowers,
- carbon deposition
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