Citation: Guo Bin RONG, Xing Ming LI, Yong ZHANG. The Preparation and Application of two New Types of Oxazaborolidines[J]. Chinese Chemical Letters, ;2000, 11(5): 381-382. shu

The Preparation and Application of two New Types of Oxazaborolidines

Department of Chemistry East China University of Science and Technology, Shanghai 200237

Received Date: 1 December 1999

Fund Project: This work was supported by the NNSFC (29972012).

Two new type of 1,3,2-oxazaborolidines were prepared from (1s,2s)-2-amino-1-(4-nitrophenyl)-propane-1,3-diol and were used as catalyst in the asymmetric reduction of acetophenone. The influence of the reaction temperature as well as the effect of the structure of catalyst on the enantioselectivity was investigated. The origin of the products' configuration was discussed.
- Oxazaborolidine,
- asymmetric catalytic reduction,
- prochiral ketone
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