Citation: Li Qiang, Liu Jiajia, Li Fangni, Bing Liancheng, Ji Shengfu, Wang Guangjian. Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins[J]. Chemistry, ;2019, 82(7): 585-589. shu

Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins

1.
Chemical Engineering Institute, Qingdao University of Science and Technology, Qingdao 266042
2.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029

Corresponding author: Wang Guangjian, wgjnet@126.com
Received Date: 29 January 2019
Accepted Date: 4 April 2019

SAPO-34 molecular sieve is widely used in the reaction of methanol to olefin (MTO). Traditional SAPO-34 molecular sieve is prone to carbon deposition and coking in the catalytic process, which lead to molecular sieve deactivation and short service life. Nano-scale SAPO-34 molecular sieves have smaller crystal size, higher specific surface area, less diffusion limitation, stronger catalyst activity center and anti-carbon deposition ability. In this paper, the preparation methods of nano-scale SAPO-34 were introduced from the perspectives of seed assist, additive addition, double template agent and optimization of crystallization conditions, and the effects of different conditions on the size of nano crystals were further studied and analyzed. Meanwhile, the catalytic performance of different nano-sized SAPO-34 in MTO was discussed. The current research problems and future development directions are put forward.
- Molecular sieve,
- SAPO-34,
- Hierarchical pore structure,
- Methanol to olefin,
- Nanocrystallites
1. [1]
  B M Lok, C A Messina, R L Patton et al. J. Am. Chem. Soc., 1984, 106(20): 6092~6093.
2. [2]
  D Chen, K Moljord, A Holmen. Micropor. Mesopor. Mater., 2012, 164(164): 239~250.
3. [3]
  Y Kawabuchi, H Oka, S Kawano et al. Carbon, 1998, 36(4): 377~382.
4. [4]
5. [5]
6. [6]
7. [7]
  None. Appl. Catal., 1984, 10(1): 80.
8. [8]
  T M Nenoff, S G Thoma, M Kartin. USP: 7041616, 2006.
9. [9]
  N Najafi, S Askari, R Halladj et al. Powder Technol., 2014, 254(2): 324~330.
10. [10]
11. [11]
  G Y Liu, P Tian, J Z Li et al. Micropor. Mesopor. Mater., 2008, 111(1~3): 143~149.
12. [12]
  T Z Wang, X C Lu, Y Yan. Micropor. Mesopor. Mater., 2013, 168: 155~163.
13. [13]
14. [14]
  Q M Sun, N Wang, G Q Guo et al. Chem. Commun., 2015, 51(91): 16397~16400.
15. [15]
  Q M Sun, N Wang, R S Bai et al. J. Mater. Chem. A, 2016, 4(39): 14978~14982.
16. [16]
  G R Chen, Q M Sun, J H Yu. Chem. Commun., 2017, 53(100): 13328~13331.
17. [17]
  P F Wang, D X Yang, J Hu et al. Catal. Today, 2013, 212: 62.e1~62.e8.
18. [18]
  C Wang, M Yang, P Tian et al. J. Mater. Chem. A, 2015, 3(10): 5608~5616.
19. [19]
  B Yang, P B Zhao, J H Ma et al. Chem. Phys. Lett., 2016, 665: 59~63.
20. [20]
  J W Zheng, J J Ding, D L Jin et al. Chem. Commun., 2017, 53(45): 6132~6135.
21. [21]
  P F Wu, M Yang, W N Zhang et al. Chem. Commun., 2017, 53(36): 4985~4988.
22. [22]
  P F Wu, M Yang, L J Sun et al. Chem. Commun., 2018, 54(79): 11160~11163.
23. [23]
  C Wang, M Yang, W N Zhang et al. RSC Adv., 2016, 6(53): 47864~47872.
24. [24]
  H Yang, X H Liu, G Z Lu et al. Micropor. Mesopor. Mater., 2016, 225: 144~153.
25. [25]
  S T Yang, J Y Kim, H J Chae et al. Mater. Res. Bull., 2012, 47(11): 3888~3892.
26. [26]
  N Najafi, S Askari, R Halladj. Powder Technol., 2014, 254: 324~330.
27. [27]
  H S Pajaie, M Taghizadeh. J. Ind. Eng. Chem., 2015, 24: 59~70.
28. [28]
  H S Pajaie, M Taghizadeh. Synth. React. Inorg. Mater., 2016, 46(5): 701~712.
29. [29]
  M Li, Y H Wang, L Bai et al. Appl. Catal. A, 2017, 531: 203~211.
30. [30]
  D Chen, K Moljord, T Fuglerud et al. Micropor. Mesopor. Mater., 1999, 29(1-2): 191~203.
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2. [2]
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1.
沈阳化工大学材料科学与工程学院沈阳 110142