Citation: Li Qiang, Liu Jiajia, Li Fangni, Bing Liancheng, Ji Shengfu, Wang Guangjian. Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins[J]. Chemistry, ;2019, 82(7): 585-589. shu

Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins

1.
Chemical Engineering Institute, Qingdao University of Science and Technology, Qingdao 266042
2.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029

Corresponding author: Wang Guangjian, wgjnet@126.com
Received Date: 29 January 2019
Accepted Date: 4 April 2019

SAPO-34 molecular sieve is widely used in the reaction of methanol to olefin (MTO). Traditional SAPO-34 molecular sieve is prone to carbon deposition and coking in the catalytic process, which lead to molecular sieve deactivation and short service life. Nano-scale SAPO-34 molecular sieves have smaller crystal size, higher specific surface area, less diffusion limitation, stronger catalyst activity center and anti-carbon deposition ability. In this paper, the preparation methods of nano-scale SAPO-34 were introduced from the perspectives of seed assist, additive addition, double template agent and optimization of crystallization conditions, and the effects of different conditions on the size of nano crystals were further studied and analyzed. Meanwhile, the catalytic performance of different nano-sized SAPO-34 in MTO was discussed. The current research problems and future development directions are put forward.
- Molecular sieve,
- SAPO-34,
- Hierarchical pore structure,
- Methanol to olefin,
- Nanocrystallites
1. [1]
  B M Lok, C A Messina, R L Patton et al. J. Am. Chem. Soc., 1984, 106(20): 6092~6093.
2. [2]
  D Chen, K Moljord, A Holmen. Micropor. Mesopor. Mater., 2012, 164(164): 239~250.
3. [3]
  Y Kawabuchi, H Oka, S Kawano et al. Carbon, 1998, 36(4): 377~382.
4. [4]
5. [5]
6. [6]
7. [7]
  None. Appl. Catal., 1984, 10(1): 80.
8. [8]
  T M Nenoff, S G Thoma, M Kartin. USP: 7041616, 2006.
9. [9]
  N Najafi, S Askari, R Halladj et al. Powder Technol., 2014, 254(2): 324~330.
10. [10]
11. [11]
  G Y Liu, P Tian, J Z Li et al. Micropor. Mesopor. Mater., 2008, 111(1~3): 143~149.
12. [12]
  T Z Wang, X C Lu, Y Yan. Micropor. Mesopor. Mater., 2013, 168: 155~163.
13. [13]
14. [14]
  Q M Sun, N Wang, G Q Guo et al. Chem. Commun., 2015, 51(91): 16397~16400.
15. [15]
  Q M Sun, N Wang, R S Bai et al. J. Mater. Chem. A, 2016, 4(39): 14978~14982.
16. [16]
  G R Chen, Q M Sun, J H Yu. Chem. Commun., 2017, 53(100): 13328~13331.
17. [17]
  P F Wang, D X Yang, J Hu et al. Catal. Today, 2013, 212: 62.e1~62.e8.
18. [18]
  C Wang, M Yang, P Tian et al. J. Mater. Chem. A, 2015, 3(10): 5608~5616.
19. [19]
  B Yang, P B Zhao, J H Ma et al. Chem. Phys. Lett., 2016, 665: 59~63.
20. [20]
  J W Zheng, J J Ding, D L Jin et al. Chem. Commun., 2017, 53(45): 6132~6135.
21. [21]
  P F Wu, M Yang, W N Zhang et al. Chem. Commun., 2017, 53(36): 4985~4988.
22. [22]
  P F Wu, M Yang, L J Sun et al. Chem. Commun., 2018, 54(79): 11160~11163.
23. [23]
  C Wang, M Yang, W N Zhang et al. RSC Adv., 2016, 6(53): 47864~47872.
24. [24]
  H Yang, X H Liu, G Z Lu et al. Micropor. Mesopor. Mater., 2016, 225: 144~153.
25. [25]
  S T Yang, J Y Kim, H J Chae et al. Mater. Res. Bull., 2012, 47(11): 3888~3892.
26. [26]
  N Najafi, S Askari, R Halladj. Powder Technol., 2014, 254: 324~330.
27. [27]
  H S Pajaie, M Taghizadeh. J. Ind. Eng. Chem., 2015, 24: 59~70.
28. [28]
  H S Pajaie, M Taghizadeh. Synth. React. Inorg. Mater., 2016, 46(5): 701~712.
29. [29]
  M Li, Y H Wang, L Bai et al. Appl. Catal. A, 2017, 531: 203~211.
30. [30]
  D Chen, K Moljord, T Fuglerud et al. Micropor. Mesopor. Mater., 1999, 29(1-2): 191~203.
1. [1]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
2. [2]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
3. [3]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
4. [4]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
5. [5]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
6. [6]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
7. [7]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
8. [8]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
9. [9]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
10. [10]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
11. [11]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
12. [12]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
13. [13]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
14. [14]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
15. [15]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
16. [16]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
17. [17]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
18. [18]
  Lilong Gao , Yuhao Zhai , Dongdong Zhang , Linjun Huang , Kunyan Sui . Exploration of Thiol-Ene Click Polymerization in Polymer Chemistry Experiment Teaching. University Chemistry, 2025, 40(4): 87-93. doi: 10.12461/PKU.DXHX202405143
19. [19]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
20. [20]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . Double S-Scheme ZnS/ZnO/CdS Heterostructure Photocatalyst for Efficient Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-0. doi: 10.3866/PKU.WHXB202406020

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(715)
HTML views(223)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142