Citation: ZHAO Qing-ning, SONG Qing-wen, LIU Ping, ZHANG Kan, HAO Jian. Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO₂ into β-oxopropylcarbamates[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(8): 1009-1017. shu

Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO₂ into β-oxopropylcarbamates

ZHAO Qing-ning ¹ ,
SONG Qing-wen ^2,, ,
LIU Ping ² ,
ZHANG Kan ^2,, ,
HAO Jian ^1,3,,

1.
Department of Chemistry, Shanghai University, Shanghai 200444, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
Basic Research Institute of Cultural Heritage Protection, Shanghai University, Shanghai 200444, China

Corresponding author: SONG Qing-wen, songqingwen@sxicc.ac.cn ZHANG Kan, zhangkan@sxicc.ac.cn HAO Jian, jhao@shu.edu.cn
Received Date: 25 April 2018
Revised Date: 20 June 2018

Fund Project: the National Natural Science Foundation of China 21672139the Natural Science Foundation of Shanxi Province 201701D221057the National Natural Science Foundation of China 21602232The project was supported by the National Natural Science Foundation of China (21602232, 21672139) and the Natural Science Foundation of Shanxi Province (201701D221057)

Figures(5)

A simple dual-component catalytic system, i.e., Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr was applied for the synthesis of various β-oxopropylcarbamates via dual-component coupling of ammonium carbamates and propargylic alcohols under atmospheric pressure.This simple method was proved to be a highly efficient system without the use of ligand, and capable of converting various propargylic alcohols and secondary amines into corresponding organic carbamates.Notably, quantitative conversion of CO₂ was achieved, thus improved the efficiency of CO₂ utilization.
- CO₂ conversion,
- ammonium carbamates,
- silver catalysis,
- β-oxopropylcarbamates,
- synthetic method
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Ag(Ⅰ)/(nC7H15)4NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO2 into β-oxopropylcarbamates

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通讯作者: 陈斌, bchen63@163.com

Ag(Ⅰ)/(ⁿC₇H₁₅)₄NBr-catalyzed reaction of ammonium carbamates and propargylic alcohols:Quantitative conversion of CO₂ into β-oxopropylcarbamates