Citation: YANG Qing, HAO Qing-lan, YAN Ning-na, ZHAO Ruo-zhu, ZHAO Chen-chen, ZHANG Qing, DOU Bao-juan, BIN Feng. Preparation of CuCe_0.75Zr_0.25O_x composite by bacterial cellulose promoted sol-gel method and its catalytic performance in the toluene degradation at low temperature[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1401-1408. shu

Preparation of CuCe_0.75Zr_0.25O_x composite by bacterial cellulose promoted sol-gel method and its catalytic performance in the toluene degradation at low temperature

1.
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China
2.
Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: DOU Bao-juan, bjdou@tust.edu.cn
Received Date: 23 June 2017
Revised Date: 23 August 2017

Fund Project: the National Natural Science Foundation of China 21307088The project was supported by the National Natural Science Foundation of China (21307088)

Figures(10)

Mesoporous CuCe_0.75Zr_0.25O_x composite was prepared by a simple sol-gel method with environmentally benign bacterial cellulose (BC) as a pore former and characterized by TG/DTG, N₂ adsorption-desorption, XRD, H₂-TPR, O₂-TPD and Raman; its catalytic activity in the degradation of toluene at low temperature was investigated in a fixed-reactor. The results indicated that BC with ultra fine three-dimensional networks and excellent compatibility is beneficial to the formation of gel with nitrate solution, to prepare the mesoporous catalyst. The catalyst performance of CuCe_0.75Zr_0.25O_x composite is significantly affected by the gel-form and gelling temperature during the preparation process. Over the ACCZ-70 catalyst prepared by alcohol gelling at 70 ℃, the temperature for a complete degradation of toluene (T₁₀₀) reaches 205 ℃, much lower than those reported in open literature; the excellent activity of ACCZ-70 is ascribed to its high reducibility at low temperature and high concentration of oxygen vacancies (0.81). In addition, adsorption phenomenon was observed in the range of 120-140 ℃ during the toluene degradation over WCCZ catalysts prepared by water gelling.
- bacterial cellulose,
- sol-gel,
- multiple oxide catalysts,
- VOCs
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of CuCe0.75Zr0.25Ox composite by bacterial cellulose promoted sol-gel method and its catalytic performance in the toluene degradation at low temperature

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通讯作者: 陈斌, bchen63@163.com

Preparation of CuCe_0.75Zr_0.25O_x composite by bacterial cellulose promoted sol-gel method and its catalytic performance in the toluene degradation at low temperature