Citation: Wei Xiaolong, Qian Yaxuan, Zhang Yafang, Wang Zhihua. Development of Methyl Parathim Molecularly Imprinted Electrochemical Sensors Based on Multi-Walled Carbon Nanotubes Supported Gold Nanoparticles[J]. Chemistry, ;2018, 81(3): 223-230. shu

Development of Methyl Parathim Molecularly Imprinted Electrochemical Sensors Based on Multi-Walled Carbon Nanotubes Supported Gold Nanoparticles

College of Chemistry and Chemical Engineering, Northwest Normal University Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu Province, Lanzhou 730070

Corresponding author: Wang Zhihua, zhwang@nwnu.edu.cn
Received Date: 2 October 2017
Accepted Date: 5 December 2017

Figures(10)

The methyl parathion molecularly imprinted electrochemical sensor was constructed based on WMCNTs and AuNPs, with tetramethylthiophenol (p-ATP) as functional monomer and methyl parathion (MP) as template molecule by electrochemical polymerization method. The electrochemical performance, selectivity, reproducibility and stability of the sensor were studied by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse method (DPV). The prepared sensor was used to measure MP in the Yellow River sample with satisfactory results. This method has the advantages of easy preparation, good selectivity, high sensitivity and good reproducibility. It provides a very effective method for analysis of methyl parathion (MP).
- Molecular imprinting,
- Carbon nanotubes,
- Au nanoparticles,
- Electrochemical sensor
1. [1]
  A Y Kolosova, J H Park, S A Eremin et al. J. Agr. Food Chem., 2003, 51(5):1107~1114.
2. [2]
  D Silva, C M Cortez, J Cunha-Bastos et al. Toxicol. Lett., 2004, 147:53~61.
3. [3]
  T H Kim, K Kuca, D Jun et al. Bioorg. Med. Chem. Lett., 2005, 15:2914~2917.
4. [4]
  E L Ang, H Zhao, J P Obbard. Enzyme Microb. Tech., 2005, 37:487~496.
5. [5]
  R A Videira, M C Medeira, V I Lopes et al. Biochim. Biophys. Acta, 2001, 1511:360~368.
6. [6]
  M Martinez Galera, M D Gil Garcia, R Santiago Valverde. Talanta, 2008, 76:815~823.
7. [7]
  G Gervais, S Brosillona, A Laplanche et al. J. Chromatogr. A, 2008, 1202:163~172.
8. [8]
  H Guan, W E Brewer, S L Morgan. J. Agr. Food Chem., 2009, 57(22):10531~10538.
9. [9]
  J W Wong, M G Webster, C A Halverson et al. J. Agr. Food Chem., 2003, 51(5):1148~1161.
10. [10]
  J W Wong, M G Webster, D Z Bezabeh et al. J. Agr. Food Chem., 2004, 52(21):6361~6372.
11. [11]
  N S Tulve, P A Jones, M G Nishioka et al. Environ. Sci. Technol., 2006, 40:6269~6274.
12. [12]
  E Borrás, P Sánchez, A Muñoz et al. Anal. Chim. Acta, 2011, 699:53~65.
13. [13]
  M R Khalili-Zanjani, Y Yamini, N Yazdanfar et al. Anal. Chim. Acta, 2008, 606:202~208.
14. [14]
  A Garrido Frenich, J L Martínez Vidal, A D Cruz Sicilia et al. Anal. Chim. Acta, 2006, 558:42~52.
15. [15]
  J Kumar, S F D'Souza. Biosens. Bioelectron., 2010, 26(4):1292~1296.
16. [16]
  C Liu, Z Song, J Pan et al. J. Phys. Chem. C, 2013, 117:10445~10453.
17. [17]
  M K P Leung, C F Chow, M H W Lam. J. Mater. Chem., 2001, 11(12):2985~2991.
18. [18]
  H A Panahi, A Feizbakhsh, S Khaledi et al. Int. J. Pharm., 2013, 441:776~780.
19. [19]
  T Selvaraju, R Ramaraj. Electrochem. Commun., 2003, 5:667~672.
20. [20]
  S A Piletsky, T L Panasyuk, E V Piletskaya et al. J. Membrane Sci., 1999, 157:263~278.
21. [21]
  Z Wang, S Xiao, Y Chen. J. Electroanal. Chem., 2006, 589:237~242.
22. [22]
  B Li, J Luo, H Luo et al. Sens. Actuat. B, 2013, 186:96~102.
23. [23]
  K Haupt. Analyst, 2001, 126(6):747~756.
24. [24]
  L Ye, K Mosbach. Chem. Mater., 2008, 20(3):859~868.
25. [25]
  M C Blanco-Lopez, M J Lobo-Castanon, A J Miranda-Ordieres et al. TrAC-Trend. Anal. Chem., 2004, 23:36~48.
26. [26]
  D Zhang, D Yu, W Zhao et al. Analyst, 2012, 137(11):2629~2636.
27. [27]
  Y Fuchs, O Soppera, K Haupt. Anal. Chim. Acta, 2012, 717:7~20.
28. [28]
  C Alexander, H S Andersson, L I Andersson et al. J. Mol.r Recognit., 2006, 19(2):106~180.
29. [29]
  C Xie, H Li, S Li et al. Anal. Chem., 2009, 82(1):241~249.
30. [30]
  J Li, F Jiang, X Wei.. Anal. Chem., 2010, 82(14):6074~6078.
31. [31]
  C Fang, C Yi, Y Wang et al. Biosens. Bioelectron., 2009, 24(10):3164~3169.
32. [32]
  K El Kirat, M Bartkowski, K Haupt. Biosens. Bioelectron., 2009, 24(8):2618~2624.
33. [33]
  J Li, J Zhao, X Wei. Sens. Actuat. B, 2009, 140(2):663~669.
34. [34]
  X Xu, G Zhou, H Li et al. Talanta, 2009, 78(1):26~32.
35. [35]
  M Govindasamy, S Sakthinathan, S M Chen et al. Electroanalysis, 2017, 29(8):1950~1960.
36. [36]
  Y Dai, G D Zhu, X H Shang et al. Electrochem. Commun., 2017, 81:14~17.
37. [37]
  S Sakthinathan, S Kubendhiran, S M Chen et al. J. Phys. Chem. C, 2017, 121(26):14096~14107.
38. [38]
  T Jeyapragasam, R Saraswathi, S M Chenet al. Int. J. Electrochem. Sci., 2017, 12(6):4768~4781.
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