Citation: Zhen Guang LIN, Hua Yang CHEN, Yu Juan LIN, Feng Hua HUANG. The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE₂B₄［36］ENE-O₆N₈·2THF[J]. Chinese Chemical Letters, ;1996, 7(10): 884-885. shu

The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF:THIONE₂B₄［36］ENE-O₆N₈·2THF

a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Fuzhou 350002;
b Department of Chemistry Fujian Teachers University Fuzhou 350007

Received Date: 3 January 1996

Fund Project: This work was supported by the grants of Natural Science Foundations of China and Fujian Province.

New Schiff base Macrocyclic compound of 2, 3:11, 12:20, 21:29, 30-tetrabenzo-l, 13, 16, 19, 31, 34-hexaoxa-5, 6, 8, 9, 23, 24, 26, 27-octaaza-7, 25-dithione-2, 3:4, 5:9, 10:11, 12:22, 23:27, 28:29, 30-cyclo-[36]ene (thione₂B₄[36]ene-O₆N₈) containing THF has been prepared.It crystallizes in the monoclinic, space group P21/n, with parameters a=9.829(5)Å, b=24.23(1)Å, c=10.181(9)Å, β =92.93(5)°, Z=2, V=2422(3)Å³, D_c=1.25gcm^-3.Data collection:Rigaku AFC-5R diffractometer, (MoK_α, λ =0.71069Å), ω/2θ scans, θ_max=25°, empirical absorption correction, 4658 measured reflections, 4387 independent, 1743 observed reflections [I≥ 3σ(I)].The final R=0.056, R_W=0.069, S=1.54, (△/σ)_max=0.01, △ρ_max=0.36eÅ^-3.
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