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Citation: WANG Hai-yan, SONG Pan-pan, WANG Yu-jia. Influence of hierarchically mesoporous Hβ zeolite on the performance of NiWP/Hβ-Al2O3 catalysts in diesel oil hydro-upgrading[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(4): 470-476. shu

Influence of hierarchically mesoporous Hβ zeolite on the performance of NiWP/Hβ-Al2O3 catalysts in diesel oil hydro-upgrading

  • 1.

    Liaoning Shihua University, Fushun 113001, China

  • 2.

    China University of Petroleum (East China), Qingdao 266555, China

  • Corresponding author: WANG Hai-yan, fswhy@126.com
  • Received Date: 9 November 2015
    Revised Date: 30 January 2016

Figures(9)

  • Hβ-Al2O3 composite supports were prepared through mechanically mixing Al2O3 with hierarchically mesoporous Hβ zeolite obtained by desilication with NaOH solution; bifunctional NiWP/Hβ-Al2O3 catalysts were then obtained by impregnation method. The composite supports and NiWP/Hβ-Al2O3 catalysts were characterized by XRD, BET and NH3-TPD; the effect of Hβ addition on the catalytic performance of NiWP/Hβ-Al2O3 in diesel oil hydro-upgrading was investigated in a fixed bed reactor with fluid catalytic cracking (FCC) diesel as the feed. The results showed that by adding 15% Hβ in the Hβ-Al2O3 composite support, NiWP/Hβ-Al2O3 catalyst performs best in diesel oil hydro-upgrading; under 360 ℃, 8 MPa, volume space velocity of 1.0 h-1 and volumetric hydrogen/oil ratio of 800, the desulfurization degree reaches 99.77%, the density of FCC diesel oil is decreased from 0.927 to 0.837 g/cm3, while the cetane value is increased from 13.78 to 55.39.
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