Citation: Shi Yufang, Wang Yingjin, Sun Jinyu, Zhao Minggen. Syntheses and Ultrafast Third-Order Nonlinear Optical Response of Ferrocene-Based Chalcone Derivatives[J]. Chemistry, ;2018, 81(8): 739-744. shu

Syntheses and Ultrafast Third-Order Nonlinear Optical Response of Ferrocene-Based Chalcone Derivatives

Key Laboratory of Materials and Computational Chemistry, Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000

Corresponding author: Zhao Minggen, zhao_minggen@aliyun.com
Received Date: 10 March 2018
Accepted Date: 28 April 2018

Figures(7)

Two novel chalcone derivatives with ferrocenyl, 1-ferrocenyl-3-(4-tert-butylphenyl) acrylic ketone (a) and 1-ferrocenyl-3-biphenylyl acrylic ketone (b) were synthesized and characterized by ¹H NMR, ¹³C NMR and HR-MS. The thermodynamic properties of compounds a and b were measured. Their molecular orbital energies and polarizabilities were calculated by quantum chemical method, and then the electronic cloud figures of these orbitals were obtained. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra and Z-scan technique, respectively. The results indicated that the absorption of compounds a and b increases significantly, and the absorption wavelength of compound b is longer. Both compounds a and b have intramolecular charge transfer phenomena, exhibiting ultrafast third-order nonlinear optical response.
- Ferrocene derivatives,
- Chalcone,
- Synthesis,
- Ultrafast third-order nonlinear optical response
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