Citation: MENG Peng-tong, FAN Chao, LÜ Wen-ting, WU Zhi-wei, JIAO Wei-yong, LI Jun-fen, QIN Zhang-feng, FAN Wei-bin, WANG Jian-guo. Preparation of monolithic cordierite supported Cu-SSZ-13 catalyst and its performance in the selective catalytic reduction of NO_x with NH₃[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(10): 1216-1223. shu

Preparation of monolithic cordierite supported Cu-SSZ-13 catalyst and its performance in the selective catalytic reduction of NO_x with NH₃

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LI Jun-fen, lijunfen@sxicc.ac.cn QIN Zhang-feng, qzhf@sxicc.ac.cn
Received Date: 9 July 2020
Revised Date: 8 August 2020

Fund Project: The Strategic Program of Coal-based Technology of Shanxi Province of China MQ2014-10The project was supported by the Strategic Program of Coal-based Technology of Shanxi Province of China ( MQ2014-11, MQ2014-10) and the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21020500).The Strategic Program of Coal-based Technology of Shanxi Province of China MQ2014-11The Strategic Priority Research Program of the Chinese Academy of Sciences XDA21020500

Figures(6)

A series of monolithic cordierite supported Cu-SSZ-13 catalysts (Cu-SSZ-13/Cordierite) was prepared by coating the Cu-SSZ-13 molecular sieves on the cellular cordierite through ultrasonic dispersion with polyvinyl alcohol (PVA) or pseudo boehmite powder (SB) as assisting agent and used in the selective catalytic reduction of NO_x with NH₃ (NH₃-SCR). With the help of XRD, nitrogen sorption, SEM and H₂-TPR characterization techniques, the influence of coating assistant agent on the firmness of the Cu-SSZ-13 layer, catalytic activity in the NH₃-SCR of NO, hydrothermal stability and resistance against SO₂ poisoning was then investigated. The results indicate that by using PVA as the coating assistant agent, a firm layer of Cu-SSZ-13 can be formed on the surface of monolithic Cu-SSZ-13/Cordierite catalyst. Moreover, the Cu-SSZ-13(PVA)/Cordierite exhibits high catalytic activity in the NH₃-SCR of NO_x (close to that of the pristine Cu-SSZ-13 molecular sieve), high hydrothermal stability and good tolerance to SO₂, displaying great potential as a practicable catalyst for the removal of NO_x from exhausts of both the mobile and the stationary sources.
- Cu-SSZ-13,
- cordierite,
- monolithic catalyst,
- selective catalytic reduction of NO_x with NH₃,
- denitrification
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of monolithic cordierite supported Cu-SSZ-13 catalyst and its performance in the selective catalytic reduction of NOx with NH3

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通讯作者: 陈斌, bchen63@163.com

Preparation of monolithic cordierite supported Cu-SSZ-13 catalyst and its performance in the selective catalytic reduction of NO_x with NH₃