Citation: ZHANG Huan-ling, WANG Guo-wei, SHAN Hong-hong, LI Chun-yi. Propane dehydrogenation over NiSn-based catalysts[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(12): 1529-1536. shu

Propane dehydrogenation over NiSn-based catalysts

State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: WANG Guo-wei, wangguowei@upc.edu.cn
Received Date: 7 July 2017
Revised Date: 30 September 2017

Fund Project: The project was supported by the National Natural Science Foundation of China(21606257, U1362201)the National Natural Science Foundation of China 21606257the National Natural Science Foundation of China U1362201

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In this paper, we studied the effects of supports, such as SiO₂, MgO, Al₂O₃ and MgAl₂O₄, on the performance of supported NiSn catalyst for propane dehydrogenation. NH₃ temperature-programmed desorption, H₂ temperature-programmed reduction were applied for the characterization of the catalysts. The results show that SiO₂ with large specific surface area and large pore size can achieve good contact between catalyst and reactants, leading to a high content of Ni_2.67Sn₂ alloy and a reduced diffusion resistance, In addition, their weak acid improve dehydrogenation activity and propene selectivity.
- propane dehydrogenation,
- NiSn-based catalysts,
- support
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