Citation: Cao Sijia, Chen Fan, Chen Yifa, Wang Bo. Fabrication of Metal-Organic Frameworks into Membranes#[J]. Chemistry, ;2017, 80(1): 3-9. shu

Fabrication of Metal-Organic Frameworks into Membranes#

Cao Sijia ^† ,
Chen Fan ^† ,
Chen Yifa ,
Wang Bo ^*,,

Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, Beijing, 100081

Corresponding author: Wang Bo, bowang@bit.edu.cn
Received Date: 30 July 2016
Accepted Date: 1 September 2016

Figures(8)

Metal-organic frameworks (MOFs), with well-defined porosity, rich structural diversity and tailable functionality, have drawn a great deal of attention from across the scientific community due to their potential applications in the fields of gas storage, separation, catalysis and chemical sensing, etc. However, MOF crystals are often fragile, insoluble and poor in processability. Commonly processing method is to fabricate MOFs into pellet. Yet the obtained samples can easily break down into tiny particles or fine powders, which might hamper their industrial applications. Herein, we developed four methods (in-situ interweaving, photo-induced postsynthetic polymerization, hot-pressing and electrospinning) to process MOFs into membranes, films and fibers. We further set out to explore their applications in the areas of electrochemistry, separation, detection, safety protection and even the possibility in industrial production.
- Metal-organic-frameworks,
- Processibility,
- Membrane
1. [1]
  H Li, M Eddaoudi, M O'Keeffe et al. Nature, 1999, 402:276-279.
2. [2]
  R Kitaura, S Kitagawa, Y Kubota et al. Science, 2002, 298:2358-2361.
3. [3]
  G Ferey, C Mellot-Draznieks, C Serre et al. Science, 2005, 309:2040-2042.
4. [4]
  S S Y Chui, S M F Lo, J P H Charmant et al. Science, 1999, 283:1148-1150.
5. [5]
  S L Qiu, M Xue, G S Zhu. Chem. Soc. Rev., 2014, 43:6116-6140.
6. [6]
  J R Li, R J Kuppler, H C Zhou. Chem. Soc. Rev., 2009, 38:1477-1504.
7. [7]
  H L Zhou, R B Lin, C T He et al. Nat. Commun., 2013, 4:2534-2541.
8. [8]
  D Y Du, J S Qin, S Li et al. Chem. Soc. Rev., 2014,43:4615-4632.
9. [9]
  G Huang, Q Yang, Q Xu et al. Angew. Chem. Int. Ed., 2016, 55:7379-7383.
10. [10]
  D Tian, Q Chen, Y Li et al. Angew. Chem. Int. Ed., 2014, 53:837-841.
11. [11]
  A U Czaja, N Trukhan, U Müller. Chem. Soc. Rev., 2009, 38:1284-1293.
12. [12]
  K M Choi, H M Jeong, J H Park et al. ACS Nano, 2014, 8:7451-7457.
13. [13]
  L Wang, X Feng, L Ren et al. J. Am. Chem. Soc., 2015, 137:4920-4923.
14. [14]
  Z Weng, Y Su, D W Wang et al. Adv. Energy Mater., 2011, 1:917-922.
15. [15]
  Y Xu, Z Lin, X Huang et al. ACS Nano, 2013, 7:4042-4049.
16. [16]
  X Dong, L Wang, D Wang et al. Langmuir, 2012, 28:293-298.
17. [17]
  X Xiao, X Peng, H Jin et al. Adv. Mater., 2013, 25:5091-5097.
18. [18]
  Y Y Zhang, X Feng, H W Li et al. Angew. Chem. Int. Ed., 2015, 54:4259-4263.
19. [19]
  M Rose, B B hringer, M Jolly et al. Adv. Eng. Mater., 2011, 13:356-360.
20. [20]
  Y Y Zhang, S Yuan, X Feng et al. J. Am. Chem. Soc., 2016, 138:5785-5788.
21. [21]
  Y F Chen, S Q Li, X K Pei. Angew. Chem. Int. Ed., 2016, 55:3419-3423.
1. [1]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
2. [2]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
3. [3]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
4. [4]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
5. [5]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
6. [6]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
7. [7]
  Bin XU , Shufeng ZHANG , Feifan LANG , Chunyan NI , Bing WU , Jianping LANG . Photoreactive pyrene-based Zn?? metal-organic frameworks: Solid-state [2+2] cycloaddition and tunable luminescence. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2119-2126. doi: 10.11862/CJIC.20260140
8. [8]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
9. [9]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
10. [10]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
11. [11]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
12. [12]
  . Synthesis and properties of metal‐organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 1-2.
13. [13]
  Zhenhuan Wang , Weifei Wei , Ruijie Ma , Dou Luo , Zhanxiang Chen , Jun Zhang , Liyang Yu , Gang Li , Zhenghui Luo . 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能电池. Acta Physico-Chimica Sinica, 2026, 42(2): 100182-0. doi: 10.1016/j.actphy.2025.100182
14. [14]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
15. [15]
  Yijing GU , Huan PANG , Rongmei ZHU . Applications of nickel-based metal-organic framework compounds in supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2029-2038. doi: 10.11862/CJIC.20250186
16. [16]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
17. [17]
  Qiuxiang FANG , Xinyue CHEN , Yuyang GUO , Penghui XIE , Pengbiao GENG . Application of metal-organic framework derived materials in lithium-sulfur battery separators. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 1910-1932. doi: 10.11862/CJIC.20260188
18. [18]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
19. [19]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(47)
Abstract views(4055)
HTML views(925)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142