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Citation: YU SHIH-CHENG, HSU TSUNG-TE. VISCOSITY AND LIGHT SCATTERING OF POLYDIMETHYL-SILOXANE IN MIXED SOLVENTS[J]. Acta Polymerica Sinica, ;1964, 6(6): 467-473. shu

VISCOSITY AND LIGHT SCATTERING OF POLYDIMETHYL-SILOXANE IN MIXED SOLVENTS

Received Date: 4 June 1964

The θ-compositions at 25℃ of polydimethylsiloxane for the binary solvent systems：ethyl benzene-diethyl phthalate and heptane-dioxane were determined by the precipitation threshold method of Elias．They were further confirmed by light scattering measurements to give A2=O and by the intrinsic viscosity-molecular weight relationships to give a=1／2．Weight average molecular weights of eight fractions of polydimethylsiloxane were deter-mined by light scattering in toluene and intrinsic viscosities of these fractions were mea-sured in the above mentioned θ-solvents at 25℃．The data fit the following equations.
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