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Citation: VOONG SING-TUH, CHANG HUNG-TsE, CHAO VE-HSIAO, SHEN BUN, SHI FU, HANG JEN-TSE, CHI HSU-CHAO. STUDIES ON CYCLOPOLYMERIZATION OF 4-SUBSTITUTED1,6-DIENE MONOMERS[J]. Acta Polymerica Sinica, ;1963, 5(1): 19-26. shu

STUDIES ON CYCLOPOLYMERIZATION OF 4-SUBSTITUTED1,6-DIENE MONOMERS

Six monomers of 4-substituted 1，6-dienes：diethyl 1，1-diallyl—malonate (I)，dimethyl 1，1-diallyl—malonate (II)，ethyl 1，1-diallyl—cyano—acetate (III)，ethyl 1，1-diallyl-acetate (Ⅳ)，1，1-α，α’dichloro-diallyl-diethylmalonate (V) and diallyl-disec-butylsilane (VI) (in whjch (II)，(V)and(vI)were unknown in literature)have been synthesized and cyclo-polymerized successfully with benzoyl peroxide as initiator．The efficiency of cyclo-polymerization，average molecular weight and intrinsic viscosity of these organic—solvent soluble polymers were determined． It was also found that monoallyl monomer of such structure as diethyl 1-allyl-malonate could be polymerized without serious “degradation transfer”as usually expected．
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3. [3]
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STUDIES ON CYCLOPOLYMERIZATION OF 4-SUBSTITUTED1,6-DIENE MONOMERS

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com