Citation: De Liang LONG, Xin Quan XIN, Xiao Ying HUANG, Jing Hua CAI, Bei Sheng KANG. SYNTHESIS AND CRYSTAL STRUCTURE OF THE CLUSTER COMPOUND MoS₄CuS₂Ag(PhS₃P)3Br·HS₂O[J]. Chinese Chemical Letters, ;1995, 6(3): 263-264. shu

SYNTHESIS AND CRYSTAL STRUCTURE OF THE CLUSTER COMPOUND MoS₄CuS₂Ag(PhS₃P)3Br·HS₂O

a Stale Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093;
b State Key Laboratory of Structural Chemistry, Fujian Institute of Resarch on Structue of Matter, Chin

Received Date: 18 October 1994

MoS₄Cu₂Ag(Ph₃P)₃Br·H₂O,fw=1344,triclinic,space group P1:a=13.246(4),b=20.314(6),c=11.995(4)Å,α=93.25(3)°,β=115.99(2)°,γ=74.44(3)°,V=2788.(2)Å³,Z=2,Dc=1.60g cm^-3,F(000)=1340,μc=22.87cm^-1,R=0.060,R_W=0.067.This is the first example of tetranuclear M-Mo-S cluster containing Cu and Ag together and the structure is a completed cubane that the Br atom bonds to Cu and Ag.
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